Specific interaction between fluorine atoms and thiol groups accounting for higher domain purity and photostability in narrowband BHJ systems

In order to explore the role of fluorine atoms on photostability as well as morphology control of active layer in the presence of 1,4‐butanedithiol (BT), the four polymers with or without fluorine atoms in the backbones including polythieno[3,4‐b]thiophene/benzodithiophene, poly[(4,8‐bis‐(2‐ethylhexyloxy)‐benzo(1,2‐b:4,5‐b9)dithiophene)‐2,6‐diyl‐alt‐(4‐(2‐ethylhexanoyl)‐thieno[3,4‐b]thiophene‐)‐2‐6‐diyl)], poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b;4,5‐b′]dithiophene‐2,6‐diyl‐alt‐(4‐(2‐ethylhexyl)‐3‐fluorothieno[3,4‐b]thiophene‐)‐2‐carboxylate‐2‐6‐diyl)], and poly[4,8‐bis‐(2‐ethyl‐hexyl‐thiophene‐5‐yl)‐benzo[1,2‐b:4,5‐b0]dithiophene‐2,6‐diyl]‐alt‐[2‐(20‐ethyl‐hexanoyl)‐thieno [3,4‐b]thiophen‐4,6‐diyl] were selected for comparison. It is found that the specimens containing fluorine atoms in polymer backbones showed of higher stability after illumination for 1 h in the presence of BT additive, contributing to the higher domain purity. The specific interaction between fluorine atoms and thiol groups was demonstrated by the appearance of novel absorption peak at 2663.1 cm^?1, in addition to the broadening of peak at 2556.2 cm^?1 ascribing to S? H stretching vibration as confirmed by Fourier transform infrared (FTIR) spectroscopy. The finding may guide the accurate use of thiols as effective solvent additive in morphology and stability optimization. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 941–951     

NIFTy 3 – Numerical Information Field Theory: A Python Framework for Multicomponent Signal Inference on HPC Clusters

NIFTy , “Numerical Information Field Theory,” is a software framework designed to ease the development and implementation of field inference algorithms. Field equations are formulated independently of the underlying spatial geometry allowing the user to focus on the algorithmic design. Under the hood, NIFTy ensures that the discretization of the implemented equations is consistent. This enables the user to prototype an algorithm rapidly in 1D and then apply it to high‐dimensional real‐world problems. This paper introduces NIFTy  3, a major upgrade to the original NIFTy  framework. NIFTy  3 allows the user to run inference algorithms on massively parallel high performance computing clusters without changing the implementation of the field equations. It supports n‐dimensional Cartesian spaces, spherical spaces, power spaces, and product spaces as well as transforms to their harmonic counterparts. Furthermore, NIFTy  3 is able to handle non‐scalar fields, such as vector or tensor fields. The functionality and performance of the software package is demonstrated with example code, which implements a mock inference inspired by a real‐world algorithm from the realm of information field theory. NIFTy  3 is open‐source software available under the GNU General Public License v3 (GPL‐3) at https://gitlab.mpcdf.mpg.de/ift/NIFTy/tree/NIFTy_3 .     

Efficient syntheses of zoledronic acid as an active ingredient of a drug against osteoporosis

The reaction of 1H-imidazol-1-ylacetic acid and two equivalents of phosphorus trichloride/phosphorous acid at 75?°C in sulfolane, or in the presence of catalytic amounts of [bmim][BF₄] afforded zoledronic acid in yields up to 75%. The joint use of the ionic liquid additive and sulfolane as the solvent was synergetic affording highly valuable zoledronic acid in a record yield of 93%.     

反导火力单元空间杀伤区内拦截概率研究

拦截概率是评价反导作战效能的重要指标,对交战前任务规划至关重要。选取某一拦截弹建立其在空间的可达集区域,针对中段反导逆轨拦截情况,确立其在空间中的杀伤区。针对杀伤区内任一点可能为拦截点的情况,对某一来袭导弹的弹道轨迹,选取可拦截弧段上的理论拦截点,通过在选取不同高度上的理论拦截点上,调整拦截弹的发射位置,从而得到拦截点在杀伤区内不同高度,不同距离以及在不同的交汇角时对拦截概率的影响。为反导作战的阵地部署研究和交战策略提供了一定的参考。     

On the phase space approach to complexity

We elaborate in some detail on a new phase space approach to complexity, due to Y.-C. Zhang. We show in particular that the connection between maximal complexity and power law noise or correlations can be derived from a simple variational principle. For a 1D signal we find 1/f noise, in accordance with Zhang.     

一种考虑速度随机慢化概率动态演化的交通流元胞自动机模型

在NS模型的基础上,利用司机的记忆效应和当前交通环境动态地调整随机慢化概率,从而得到一个改进的交通流元胞自动机模型.数值实验表明,该模型可以很好地刻画司机记忆效应对交通流的影响,记忆效应的引入可以提高平均速度和流量. 关键词： 交通流 元胞自动机模型 记忆效应 随机慢化概率     

On the limiting behavior of the maximum partial sums for arrays of rowwise NA random variables

Let {Xni, 1 ≤ n,i ＜∞} be an array of rowwise NA random variables and {an, n ≥ 1} a sequence of constants with 0 ＜ an ↑∞. The limiting behavior of maximum partial sums 1/an max 1≤k≤n| kΣi=1 Xni| is investigated and some new results are obtained. The results extend and improve the corresponding theorems of rowwise independent random variable arrays by Hu and Taylor [1] and Hu and Chang [2].     

On the Lower Tail Probabilities of Some Random Sequences in <Emphasis Type="Italic">l</Emphasis><Subscript><Emphasis Type="Italic">p</Emphasis></Subscript>

We investigate the behaviour of the logarithmic small deviation probability of a sequence (σ _n θ _n ) in l _p , 0<p≤∞, where (θ _n ) are i.i.d. random variables and (σ _n ) is a decreasing sequence of positive numbers. In particular, the example σ _n ∼n ^−μ (1+log n)^−ν is studied thoroughly. Contrary to the existing results in the literature, the rate function and the small deviation constant are expressed expli- citly in the present treatment. The restrictions on the distribution of θ ₁ are kept to an absolute minimum. In particular, the usual variance assumption is removed. As an example, the results are applied to stable and Gamma-distributed random variables.     

基于复合泊松过程战略石油储备天数的概率模型及其应用

为了明确国家或地区战略石油储备天数,在分析世界发生石油生产中断的历史数据的基础上,建立了战略石油储备天数的复合泊松过程的概率模型。把模型计算结果与国际能源机构确定的经合组织石油储备天数的标准及其实际石油储备数据进行对比分析,发现该模型具有相当的合理性,可以作为指导国家或地区进行战略石油储备的理论依据。