全文获取类型
收费全文 | 500篇 |
免费 | 123篇 |
国内免费 | 62篇 |
专业分类
化学 | 126篇 |
晶体学 | 2篇 |
力学 | 291篇 |
综合类 | 5篇 |
数学 | 30篇 |
物理学 | 231篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 5篇 |
2020年 | 13篇 |
2019年 | 20篇 |
2018年 | 6篇 |
2017年 | 20篇 |
2016年 | 35篇 |
2015年 | 21篇 |
2014年 | 24篇 |
2013年 | 42篇 |
2012年 | 28篇 |
2011年 | 31篇 |
2010年 | 30篇 |
2009年 | 34篇 |
2008年 | 34篇 |
2007年 | 34篇 |
2006年 | 21篇 |
2005年 | 23篇 |
2004年 | 41篇 |
2003年 | 29篇 |
2002年 | 21篇 |
2001年 | 15篇 |
2000年 | 16篇 |
1999年 | 16篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 10篇 |
1994年 | 12篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有685条查询结果,搜索用时 250 毫秒
71.
以RDX为基的含铝炸药中铝粉粒度和氧化剂形态对加速金属能力的影响 总被引:3,自引:0,他引:3
利用激光速度干涉仪研究了含微米铝粉和纳米铝粉复合炸药加速金属平板的能力,结果表明纳米铝粉的引入能够获得更大的金属平板自由面速度,其反应时间比微米复合含铝炸药缩短35.1%。研究了氧化剂的形态对含铝炸药性能的影响,用物理化学手段获得的RDX/AP复合粒子复合粒子制作的含铝炸药加速金属平板的能力优于机械混合RDX/AP的含铝炸药,前者的反应时间也比后者短。此外,还研究了以富氧炸药取代RDX获得的含铝炸药的性能,结果表明其加速金属平板的速度比RDX/Al复合炸药提高10%。 相似文献
72.
In this paper, instead of energy methods, we apply the supersolution and subsolution methods to investigate the critical extinction exponents for a polytropic filtration equation with absorption and source, and improve the results of Mu et al. (J. Math. Anal. Appl. 2012; 391 :429–440). Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
73.
74.
Kepa Castro Silvia Fdez‐Ortiz de Vallejuelo Izaskun Astondoa Flix M. Goi Juan Manuel Madariaga 《Journal of Raman spectroscopy : JRS》2011,42(11):2000-2005
A forensic analysis of several samples of pyrotechnic artefacts was performed by Raman spectroscopy assisted by scanning electron microscopy/energy‐dispersive X‐ray spectroscopy (SEM‐EDS) and Fourier transform infrared (FTIR) analysis. Among the components, several nitrates, ammonium perchlorate, nitrocellulose, metallic titanium particles and shellac were detected. The combination of Raman spectroscopy and SEM‐EDS showed very useful performance. All components were detected by Raman spectroscopy except for shellac, kaolinite and titanium particles, which were not conclusive enough and had to be determined by FTIR and EDS. In contrast, many compounds were not detected by FTIR. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
75.
Explosive synchronization in a mobile network in the presence of a positive feedback mechanism
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Synchronization is a process that describes the coherent dynamics of a large ensemble of interacting units.The study of explosive synchronization transition attracts considerable attention.Here,I report the explosive transition within the framework of a mobile network,while each oscillator is controlled by global-order parameters of the system.Using numerical simulation,I find that the explosive synchronization(ES)transition behavior can be controlled by simply adjusting the fraction of controlled oscillators.The influences of some parameters on explosive synchronization are studied.Moreover,due to the presence of the positive feedback mechanism,I prevent the occurrence of the synchronization of continuous-phase transition and make phase transition of the system a first-order phase transition accompanied by a hysteresis loop. 相似文献
76.
Matthew L. Gettings Michael T. Thoenen Dr. Edward F. C. Byrd Dr. Jesse J. Sabatini Dr. Matthias Zeller Prof. Dr. Davin G. Piercey 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(64):14530-14535
This work reports the first compound containing both a tetrazole and an azasydnone ring, a unique energetic material. Several energetic salts of the tetrazole azasydnone were synthesized and characterized, leading to the creation of new secondary and primary explosives. Molecular structures are confirmed by 1H and 13C NMR, IR spectroscopy, and X-ray crystallographic analysis. The high heats of formation, fast detonation velocities, and straight-forward synthesis of energetic azasydnones should capture the attention of future energetics research. 相似文献
77.
富碳炸药在爆轰过程中可产生团簇分子,而现有的实验手段不能直接观测团簇分子的形成过程.本文采用ReaxFF/lg力场对梯恩梯(TNT)在不同温度下的热分解过程进行了模拟.研究发现:团簇分子在反应初始阶段形成缓慢,大约一次增加一个TNT相对分子质量.随着反应进行,团簇分子迅速增大,最大团簇分子相对分子质量可达8000~10000,约占体系质量的18%.分析团簇分子的结构发现,团簇分子中一部分苯环被破坏,形成五元环和夹杂N、O原子的六元环,在3500 K条件下还形成了更为复杂的七元环等结构.通过体积膨胀和直接降温的方法,研究了团簇分子的稳定性:体积膨胀使得团簇分子迅速分解;而直接降温,团簇分子又聚合成更大的团簇.分析类石墨结构的产生过程,发现先膨胀然后降温是必不可少的步骤.比较团簇分子和TNT分子中各原子质量所占比,团簇分子中C原子质量比始终在增加. 相似文献
78.
Joseph P. Hutchinson Cameron Johns Michael C. Breadmore Emily F. Hilder Rosanne M. Guijt Chris Lennard Greg Dicinoski Paul R. Haddad 《Electrophoresis》2008,29(22):4593-4602
Novel CE methods have been developed on portable instrumentation adapted to accommodate a capacitively coupled contactless conductivity detector for the separation and sensitive detection of inorganic anions and cations in post‐blast explosive residues from homemade inorganic explosive devices. The methods presented combine sensitivity and speed of analysis for the wide range of inorganic ions used in this study. Separate methods were employed for the separation of anions and cations. The anion separation method utilised a low conductivity 70 mM Tris/70 mM CHES aqueous electrolyte (pH 8.6) with a 90 cm capillary coated with hexadimethrine bromide to reverse the EOF. Fifteen anions could be baseline separated in 7 min with detection limits in the range 27–240 μg/L. A selection of ten anions deemed most important in this application could be separated in 45 s on a shorter capillary (30.6 cm) using the same electrolyte. The cation separation method was performed on a 73 cm length of fused‐silica capillary using an electrolyte system composed of 10 mM histidine and 50 mM acetic acid, at pH 4.2. The addition of the complexants, 1 mM hydroxyisobutyric acid and 0.7 mM 18‐crown‐6 ether, enhanced selectivity and allowed the separation of eleven inorganic cations in under 7 min with detection limits in the range 31–240 μg/L. The developed methods were successfully field tested on post‐blast residues obtained from the controlled detonation of homemade explosive devices. Results were verified using ion chromatographic analyses of the same samples. 相似文献
79.
A New Method for Assessment of Performing Mechanical Works of Energetic Compounds by the Cylinder Test
下载免费PDF全文
![点击此处可从《无机化学与普通化学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Farshad Fotouhi‐Far Hadis Bashiri Masood Hamadanian Mohammad Hossein Keshavarz 《无机化学与普通化学杂志》2016,642(19):1086-1090
A new method is introduced for assessment of performing mechanical works of energetic compounds by cylinder wall velocities of CHNOFCl energetic compounds on the basis of the cylinder test. Four suitable decomposition paths are used to evaluate the number of moles of gaseous detonation products per gram of explosive, the average molecular weight of these gases, and the heat of detonation in calories per gram by considering different decomposition products HF, HCl, CO, N2, H2O, H2, and CO2. For CHNO and fluoro energetic compounds, the predicted cylinder wall velocities of these compounds give more reliable results than one of the best available empirical methods. The predicted root mean square (rms) deviations of cylinder wall velocities of the new model for some chloro explosives at actual radial expansions 0.6 and 1.9 mm are 0.010 and 0.062 km · s–1, which show high reliability of the new method. 相似文献
80.