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131.
Jilly James Chidambaram Ramalechume Asit Baran Mandal 《Journal of Polymer Science.Polymer Physics》2007,45(17):2410-2420
The shape, size, aggregation, hydration, and correlation times of water insoluble PEO‐PPO‐PEO triblock copolymer micelles with sodium dodecylsulfate (SDS) micelles were investigated using transport studies and dynamic light scattering technique. From the conductance of micellar solutions of the polymer in 25 mM SDS and 5 mM NaCl, the hydration of polymer micelles were determined using the principle of obstruction of electrolyte migration by the polymer. The asymmetry of the micellar particles of polymer and polymer‐SDS mixed micellar systems in 5 mM NaCl and their average axial ratios were calculated using intrinsic viscosity and hydration data obeying Simha–Einstein equation. Hydration number and micellar sizes were variable with temperature. The shape of the polymer micelles has been ellipsoidal rather than spherical. The micellar volume, hydrodynamic radius, radius of gyration, diffusional coefficients as well as translational, rotational and effective correlation times have been calculated from the absolute values of the axes. The partial molal volume of polymer micelles has also been determined and its comparison with the molar volume of pure polymer suggested a volume contraction due to immobilization of the water phase by the hydrophilic head groups of the polymer. The thermodynamic activation parameters for viscous flow favor a more ordered water structure around polymer micelles at higher temperatures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2410–2420, 2007 相似文献
132.
133.
B. Sun Yu. A. Litvinov P. M. Walker K. Beckert P. Beller F. Bosch D. Boutin C. Brandau L. Chen C. Dimopoulou H. Geissel R. Knöbel C. Kozhuharov J. Kurcewicz S. A. Litvinov M. Mazzocco J. Meng C. Nociforo F. Nolden W. R. Plass C. Scheidenberger M. Steck H. Weick M. Winkler 《The European Physical Journal A - Hadrons and Nuclei》2007,31(3):393-394
A new long-lived isomeric state in the near proton dripline nucleus 125Ce has been identified with Schottky mass spectrometry at GSI. The excitation energy E
* = 103(12)keV and the decay time of 193(1)s have been obtained from a single stored fully ionized 125m
Ce58+ ion. The data implies an E3 transition and a 1/2+ assignment for the spin of the isomer. 相似文献
134.
Protein Conformation of a Lattice Model Using Tabu Search 总被引:1,自引:0,他引:1
We apply tabu search techniques to the problem of determining the optimal configuration of a chain of protein sequences on a cubic lattice. The problem under study is difficult to solve because of the large number of possible conformations and enormous amount of computations required. Tabu search is an iterative heuristic procedure which has been shown to be a remarkably effective method for solving combinatorial optimization problems. In this paper, an algorithm is designed for the cubic lattice model using tabu search. The algorithm has been tested on a chain of 27 monomers. Computational results show that our method outperforms previously reported approaches for the same model. 相似文献
135.
This study provides a stability theory for the nonlinear least-squares formulation of estimating the diffusion coefficient in a two-point boundary-value problem from an error-corrupted observation of the state variable. It is based on analysing the projection of the observation on the nonconvex attainable set.This research was started while G. Chavent visited the Technical University of Graz. Support through the Steiermaerkische Landesregierung is gratefully acknowledged. 相似文献
136.
137.
为解决高等师范院校物理专业学生的知识结构和实际能力与社会需要明显不相适应的矛盾,我们对四年制物理专业的课程结构进行了全面改革。改革后,毕业生不仅能胜任普通中学或职业中学(职业中专)的教学,而且有能力参与厂矿企业的技术工作,具有更广泛的适应性和更强的竞争力。 相似文献
138.
聚醚醚酮链结构与反应的模型化合物的量子化学研究 总被引:1,自引:1,他引:0
利用AM1方法对聚醚醚酮模型化合物全优化,结果为:芳环平均相互扭转角为33.0度,桥键角117.0-118.0度,其分子结构拓扑图形表明:所有苯环(核)为平面构型,但其内角扭曲;其氢原子对苯环构型无实质性贡献,在更长链的计算中,冻结苯核与氢原子也得出满意结果,根据Mulliken键序与电荷讨论了醚交换与磺化反应。 相似文献
139.
B. M. Dzhagarov N. N. Kruk N. V. Konovalova A. A. Solodunov I. I. Stepuro 《Journal of Applied Spectroscopy》1995,62(2):285-289
Presented at the XV IUPAC Symposium on Photochemistry, Prague, July 17–22, 1994. 相似文献
140.
D. Kast A. Jungclaus K.P. Lieb M. Górska G. de Angelis P.G. Bizzeti A. Dewald C. Fahlander H. Grawe R. Peusquens M. De Poli H. Tiesler 《The European Physical Journal A - Hadrons and Nuclei》1998,3(2):115-128
In the neutron deficient isotopes 104,105In lifetimes of high spin states in the range from 0.5 ps to 600 ps have been measured in a coincidence recoil distance Doppler
shift (RDDS) experiment. By combining the Doppler shift attenuation (DSA) and RDDS methods at few μm flight distances, the
problem of delayed feeding has been avoided and very short lifetimes in the range 0.5–0.8 ps have been determined. Shell model
calculations with strong restrictions for the neutron orbitals reveal good agreement with experimental level energies and
still fair agreement for most measured B(M1) and B(E2) values.
Received: 30 June 1998 相似文献