Highly efficient heterogeneous procedure for the synthesis of fructone fragrancy

A novel heterogeneous strong acid catalyst was synthesized through the copolymerization of p-toluenesulfonic acid and paraformaldehyde and utilized for the synthesis of fructone. The results showed that the catalyst was very efficient for the reaction with the yield over 95%. The advantages of extremely high density of acidity, high thermal and chemical stability, low cost for the simple synthetic procedure, and reusability made the catalyst one of the best choices for the reaction.     

A comparison of the effect of nanotube chirality and electronic properties on the π–π interaction of single‐wall carbon nanotubes with pyrazinamide antitubercular drug

Theoretical investigation on local electronic structure and stability of the π–π stacking interaction of pyrazinamide (PZA) with armchair (5,5) and zigzag (9,0) single‐walled carbon nanotubes (SWCNTs) is performed using density functional theory (DFT). PZA is physisorbed onto nanotube sidewall through interaction of π orbitals of PZA and SWCNT and the enhanced structural stability of PZA/SWCNT systems is due to weak side‐on rather than the head‐on π‐interactions. The physisorption of PZA onto SWCNT sidewall is thermodynamically favored; as a consequence, it modulates the electronic properties of pristine nanotube in the vicinity of Fermi region and π–π stacked interactions is stronger in (9,0) SWCNT compared to (5,5) SWCNT. The density of states (DOS) analysis show that PZA contributes toward the enhancement of electronic states. Projected DOS and frontier orbital analysis in the vicinity of Fermi level region suggest the electronic states to be contributed from SWCNT rather than PZA. In addition, hybrid DFT calculation which includes the dispersion correction is employed to explain the non‐covalent π–π stacking interaction between PZA and SWCNT. The local density approximation and GGA results are compared with DFT‐D to explain near about accurately the weak nonbonded van der Waals interactions between PZA and SWCNTs. © 2012 Wiley Periodicals, Inc.     

高效大面积有机白光照明研究及其展望

白光有机发光二极管(OLED)是新一代健康节能照明光源,光效性能已超过荧光灯水平。自从OLED技术问世以来,研究人员陆续开展了关于OLED照明的研究工作。本文介绍了OLED照明的特点,以及国内外OLED照明发展现状,讨论了发展OLED照明技术和装备国产化所亟待解决的重大难题和面临的挑战,重点论述了发展高效大面积OLED照明器件制备技术及推动OLED照明产业化的重要意义。     

Continuity of the efficient solution mapping for vector optimization problems

This paper aims at investigating the continuity of the efficient solution mapping of perturbed vector optimization problems. First, we introduce the concept of the level mapping. We give sufficient conditions for the upper semicontinuity and the lower semicontinuity of the level mapping. The upper semicontinuity and the lower semicontinuity of the efficient solution mapping are established by using the continuity properties of the level mapping. We establish a corollary about the lower semicontinuity of the minimal point set-valued mapping. Meanwhile, we give some examples to illustrate that the corollary is different from the ones in the literature.     

Unbounded Components in the Solution Sets of Strictly Quasiconcave Vector Maximization Problems

Let (P) denote the vector maximization problem

复形上一类混合约束的多目标规划问题

探讨了ｎ维复形上一类具有混合约束的多目标规划问题,并运用代数拓扑方法得出这类规划问题的有效解。     

基于条件VaR(CVaR)的投资组合优化模型及比较研究

在总结投资组合优化模型的基础上 ,详细分析了 Va R和 CVa R的概念及重要性质 ,分析了将 Va R和 CVa R应用于决策问题的处理技巧 .针对传统均值—方差模型 ,提出不考虑各种限定条件的基于条件Va R( CVa R)的投资组合优化模型以及考虑限定条件的一般模型 .针对模型的适用性 ,详细比较了 CVa R模型和均值—方差模型的应用复杂性 ,并利用实际数据进行了对比 .