Optimization of thin-film design for multi-layer dielectric grating

Thin-film design used to fabricate multi-layer dielectric (MLD) gratings should provide high transmittance during holography exposure, high reflectance at use wavelength and sufficient manufacturing latitude of the grating design making the MLD grating achieve both high diffraction efficiency and low electric field enhancement. Based on a (HLL)⁹H design comprising of quarter-waves of high-index material and half-waves of low-index material, we obtain an optimum MLD coating meeting these requirements by inserting a matching layer being half a quarter-wave of Al₂O₃ between the initial design and an optimized HfO₂ top layer. The optimized MLD coatings exhibits a low reflectance of 0.017% under photoresist at the exposure angle of 17.8° for 413 nm light and a high reflectance of 99.61% under air at the use angle of 51.2° for 1053 nm light. Numerical calculation of intensity distribution in the photoresist coated on the MLD film during exposure shows that standing-wave patterns are greatly minimized and thus simulation profile of photoresist gratings after development demonstrates smoother shapes with lower roughness. Furthermore, a MLD gratings with grooves etched into the top layer of this MLD coating provides a high diffraction efficiency of 99.5% and a low electric field enhancement ratio of 1.53. This thin-film design shows perfect performances and can be easily fabricated by e-beam evaporation.     

New far infrared laser lines obtained by optically pumping13CD3OD

We have obtained laser action on 34 far infrared lines for the first time in fully deuterated methyl alcohol with the¹³C isotope (¹³CD₃OD), and we have measured the frequency of 13 lines. The molecule was pumped by a cw CO₂ laser. We have measured the wavelength, the relative polarization, the relative intensity of most lines, the frequency, and the CO₂ pump frequency offset of the strongest lines. The new lines are distributed in the wavelength region from 75.27 m to 464.7 m.Supported in part by a joint grant with the U.S. National Science Foundation grant # INT 80-19014 and the Brazilian Conselho Nacional de Pesquisas (CNPq).     

The deterministic grey dynamic model with convolution integral DGDMC(1, n)

Although the grey forecasting models have been successfully utilized in many fields and demonstrated promising results, literatures show their performance still could be improved. The grey prediction theory is methodology and it is necessary to constantly present new models or algorithm based on the theory to improve its performance, prediction accuracy especially. For this purpose, this paper proposes a new prediction model called the deterministic grey dynamic model with convolution integral, abbreviated as DGDMC(1, n). Improvements upon the existing grey prediction model GM(1, n) are made to a large extent and the messages for a system can be inserted sufficiently. The major improvements include determining the unbiased estimates of the system parameters by the deterministic convergence scheme, introducing the first derivative of the 1-AGO data of each associated series into the DGDMC(1, n) model to strengthen the indicative significance and evaluating the modelling 1-AGO data of the predicted series by the convolution integral. The indirect measurement of the tensile strength of a material for a higher temperature is adpoted for demonstration. The results show that the accuracy of indirect measurement is higher by the DGDMC(1, n) model than by the existing GM(1, n) model.     

Y掺杂对氢氧化镍电极高温性能的影响

合成了内掺稀土元素Y的β-Ni(OH)2和α-Ni(OH)2材料, 并通过XRD、TEM、CV 和充放电测试等方法研究了Y元素对这两种晶型活性材料的结构、形貌以及高温电化学性能方面的影响, 发现Y元素可显著提高β-Ni(OH)2和α-Ni(OH)2材料的高温性能, 且作用机理相同, 均是通过提高析氧过电位来改善镍电极的高温充电效率. 但是α-Ni(OH)2在高温下的相稳定性仍有待提高.     

Studies on photoinduced effects in pulse-electrodeposited Ag/Hg-1212/CdSe hetero-nanostructures

Metal/superconductor/semiconductor (Ag/Hg-1212/CdSe) hetero-nanostructures have been fabricated using pulse-electrodeposition technique and are characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy (SEM) studies. The junction capacitance of Ag/Hg-1212, Hg-1212/CdSe and Ag/Hg-1212/CdSe heterojunctions is measured in dark and under laser irradiation at room temperature. The nature of the junction formed and built-in-junction potentials were determined. The increase in carrier concentration across the junction due to photo-irradiation has been observed.     

基于Talbot-Moiré法测量透镜焦距的CCD亚像素标定技术

利用Ronchi光栅的Talbot效应和Moiré条纹测量长焦透镜焦距,根据焦距与莫尔条纹斜率之间的定量关系可求得透镜焦距.分别采用Canny算子和形态学方法对光栅的栅线中心进行像素级定位,再用高斯曲线拟合对其进行亚像素定位.经过对标准条纹的标定,验证了该方法的条纹中心定位误差小于0.1个像素.采用光栅作为系统的自基准对CCD像素当量进行了亚像素标定,为条纹斜率和宽度的计算提供了可靠的测量基准,经过计算,采用这些数据计算的焦距误差为0.10%.     

双轴应力状态下正交异性动态光弹性应力——光性定律研究

基于静态下Ｈｙｅｒ和Ｌｉｕ表述的正交异性应力－光性定律，在前文中，提出了正交异性光弹性复合材料的动态应力－光性定律并证明了其在单轴应力状态下的正确性。本文旨在进一步考察在双轴应力状态下正交异性动态应力－光性定律的适用性，采用的方法是对纤维增强光弹性复合材料制作的平板模型施加冲击荷载，加载方向与材料纤维方向分别成０°、９０°及４５°角，同时进行正交异性动态光弹性实验和动态应变测量，另外，对该模型进行相应的各向异性介质时域边界元计算。把动态应变测量推算出的应力分量以及时域边界元计算出的应力分量分别代入正交异性动态应力－光性定律，得到随时间变化的双折射条纹级数历程，将其与正交异性动态光弹性实验的结果进行比较。实验及计算结果表明，在三个加载方向下，由这三种方法得到的双折射条纹级数历程均吻合良好，从而证明了前文提出的正交异性动态应力－光性定律在双轴应力状态下的正确性。     

X射线硬化对面密度测量灵敏度的影响

利用蒙特卡罗方法分别研究了3种能量X光机的光子穿透不同厚度铝的硬化情况及3种能量光机作为光源测量面密度的过程,并开展了相关实验研究,根据模拟结果对比分析了不同能量光机X射线硬化对面密度测量灵敏度的影响,结果表明:对同种能量光机的光子而言,随着面密度变大,射线硬化程度越严重,导致测量灵敏度下降;光子能量越低,测量灵敏度随面密度变大下降越快,反之亦然;对于某一范围面密度被测物,调整X光机电压使X光子刚好穿透并形成有效图像,可获得最理想的测量灵敏度。     

空间激光与单模光纤和光子晶体光纤的耦合效率

为了设计最优光纤耦合系统,利用高斯模场近似单模阶跃光纤的模场和大模面积光子晶体光纤的模场,推导出了理想情况下空间激光与这两种光纤的耦合效率解析表达式以及光纤端面相对于耦合系统存在横向偏移和端面倾斜时的耦合效率解析表达式。基于上述理论表达式计算了空间激光与光纤的耦合效率,并通过实验验证了此理论表达式的有效性。理论计算和实验均证实了单模阶跃光纤对于横向偏移更敏感,当横向偏移量等于单模光纤的纤芯半径时所对应的耦合效率只有20.25%,为理论最大值的1/4;而大模面积光子晶体光纤对于端面倾斜更加敏感,当端面倾斜2°时对应的耦合效率只有40.5%,为理论最大值的1/2。所提出理论表达式和实验方法完全可以为设计光纤耦合系统提供准确的参数。     

水质监测中总磷无损的近红外光谱分析研究

本文对天然水样的近红外光谱与水样总磷（TP）含量进行了相关性研究,并建立了水质总磷的近红外光谱（NIRS）分析方法。结果表明：NIRS方法建立的定量分析模型所得TP含量与国标法得到结果的相关性达到0.908,并且在显著性水平大于0.05的条件下对NIRS方法与国标法的测定结果进行t检验,二者无显著性差异,说明了NIRS方法定量分析地表水中低含量总磷的可行性。