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81.
Takao Masuda 《Catalysis Surveys from Asia》2003,7(2-3):133-144
The diffusion mechanisms within zeolite catalysts, such as resistance to diffusion at pore mouths, configurational diffusion, adsorption-controlled diffusion, influence of co-existing molecules and pore blocking, were overviewed. Two kinds of diffusivities, the intracrystalline diffusivity and the effective diffusivity, were discussed separately to clarify the diffusion mechanism. 相似文献
82.
We propose a physical interpretation of the so-called van der Waals equation of state for rubbers, which gives a relation between the force and the deformation. On a phenomenological basis this equation takes the finite extensibility and a non-defined interaction into account. Here the fininte extensibility is discussed for the dilute case (no entanglements) and the highly entangled limit. The intramolecular interactions are described by orientational effects. The resulting equation of state for the force shows the same features as the van der Waals equation.Dedicated to Prof. H.-G. Kilian on the occasion of his 60th birthday. 相似文献
83.
A. V. Sinitsky M. B. Darhovskii A. L. Tchougreff I. A. Misurkin 《International journal of quantum chemistry》2002,88(4):370-379
In the present work the semiempirical effective crystal field (ECF) method previously designed for electronic structure calculations of transition metal complexes and utilizing non‐Hartree–Fock trial wave function and parameterized for complexes of doubly charged Cr2+, V2+, Mn2+, Fe2+, Co2+, and Ni2+ cations is extended to complexes of triply charged cations of 3d‐elements. With the parameters adjusted the ECF method is applied to calculations of ground states and low‐energy spectra of the d‐shells of fluoro‐, chloro‐, aqua‐, amino‐, and cyano‐complexes of the triply charged cations. Obtained total spin and symmetry of the ground states match the experimentally observed ones. Satisfactory agreement between the calculated and experimental d‐shell electronic transition energies is achieved as well. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002 相似文献
84.
STUDY ON 1-HEXENE POLYMERIZATION BASED ON ZIEGLER-NATTA CATALYSTS WITH DOPED SUPPORT 总被引:1,自引:0,他引:1
XueJiang Zhi-qiangFan 《高分子科学》2004,(4):305-308
A series of Ti/Mg supported catalysts are prepared by using ball-milled mixtures of MgCl2-ethanol adducts and NaCl as supports, and 1-hexene polymerizations catalyzed by the novel catalysts are studied. It is found that the molecular weight distribution of poly(1-hexene) becomes apparently narrower when catalysts with doped supports are used, indicating that changing the structure of the support is an effective way to regulate the active center distribution of heterogeneous Ziegler-Natta catalyst. 相似文献
85.
Elastic Analysis of Anisotropic Functionally Graded Rotating Disks With Non-Uniform Thicknesses北大核心CSCD 下载免费PDF全文
研究了任意梯度变化的变厚度各向异性转动圆盘的弹性问题.假设圆盘绕刚性轴匀速转动,其材料性能和厚度沿径向任意梯度变化.考虑圆盘在中心转轴处受位移约束,外侧自由,根据各向异性转动圆盘的平衡微分方程,得到关于径向应力的Fredholm积分方程,继而通过对Fredholm积分方程进行数值求解,得到结构的位移场和应力场.对具体梯度变化情况仅需代入相应梯度变化进行求解即可.数值算例部分,通过假设厚度、弹性模量等参数为特殊的幂函数形式,将由Fredholm积分方程求出的数值解与对应的精确解进行对比,以及针对常见的Voigt模型,将由该方法算得的数值解和ANSYS有限元计算结果进行对比,验证了该方法的准确性和精度.其次,针对Voigt模型,重点分析了厚度变化、材料性能梯度参数、各向异性度等对应力场和位移场的影响.提出了针对材料性能和厚度沿径向呈任意梯度变化的圆盘结构弹性分析方法,将为优化功能梯度圆盘的结构和材料参数、有效调整构件应力分布、提高结构安全性,提供强有力的工具;算例分析结果对功能梯度圆盘在复杂条件下的结构安全设计有重要的理论指导意义. 相似文献
86.
87.
The main purpose of the present paper is to compare two different kinds of approaches in modeling the deck of a suspension bridge: in the first approach we look at the deck as a rectangular plate and in the second one we look at the deck as a beam for vertical deflections and as a rod for torsional deformations. Throughout this paper we will refer to the model corresponding to the second approach as the beam-rod model. In our discussion, we observe that the beam-rod model contains a larger number of elastic parameters if compared with the isotropic plate model. For this reason the beam-rod model is supposed to be more appropriate to describe the behavior of the deck of a real suspension bridge. A possible strategy to make the plate model more efficient could be to relax the isotropy condition with a more general condition of orthotropy, which is expected to increase the number of elastic parameters. In this new setting, a comparison between the two approaches becomes now possible.Basic results are proved for the suggested problem, from existence and uniqueness of solutions to spectral properties. We suggest realistic values for the elastic parameters thus obtaining with both approaches similar responses in the static and dynamic behavior of the deck. This can be considered as a preliminary article since many work has still to be done with the perspective of formulating models for a complete suspension bridge which take into account not only the deck but also the action on it of cables and hangers. With this perspective, a section is devoted to possible future developments. 相似文献
88.
Consider the variational integral
where Ω⊂ℝ
n
andp≥n≥2. H: (0, ∞)→[0, ∞) is a smooth convex function such that
. We approximateJ by a sequence of regularized functionalsJ
δ whose minimizers converge strongly to anJ-minimizing function and prove partial regularity results forJ
δ-minimizers. 相似文献
89.
J. A. Yan 《Applied Mathematics and Optimization》1995,31(2):137-153
Some sharp results about Weiner and Wick products of whitenoise functionals are obtained. Using the inequality of Wick products we show to what extent scaling transformations, translations, and Sobolev differentiations can be performed on white-noise functionals.This work was supported by the National Natural Science Foundation of China. This paper is an enlargement and revised version of the paper entitled Products and Transforms of White-Noise Functionals (preprint, 1990). 相似文献
90.
We prove that certain two-point Padé approximants occupying the diagonal of the Padé table form monotone sequences of lower and upper bounds uniformly converging to a Stieltjes function. The results can be applied to the theory of inhomogeneous media for the calculation of the bounds on the effective transport coefficients of heterogeneous materials. 相似文献