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11.
本文运用信息保存法对低速二维的流动现象进行模拟,考察了低速条件下的有限平板绕流以及微槽道气体流动问题。研究表明:在对低速流动的模拟过程中,运用IP法在能够获得较好的结果的同时,具有比DSMC方法更高的计算效率。 相似文献
12.
Analytical solutions of the diffusion equations to obtain the diffusant concentrations in the macro- and micropores which constitute the pore system of a zeolite bed are presented. The parameter which determines the influence of each pore type on the evolution of the adsorbate/adsorbant system towards the equilibrium state is described. Examples are given to illustrate a qualitative and quantitative study based on the curves obtained from these equations. 相似文献
13.
Benoit B. Mandelbrot 《Journal of statistical physics》1984,34(5-6):895-930
The three topics discussed in this paper are largely independent. Part 1: Fractal squig clusters are introduced, and it is shown that their properties can match to a remarkable extent those of percolation clusters at criticality. Physics on these new geometric shapes should prove tractable. As background, the author's theories of squig intervals and squig trees are reviewed, and restated in more versatile form. Part 2: The notion of latent fractal dimensionality is introduced and motivated by the desire to simplify the algebra of dimensionality. Scaling noises are touched upon. A common formalism is presented for three forms of anomalous diffusion: the ant in the fractal labyrinth, fractional Brownian motion, and Lévy stable motion. The fractal dimensionalities common to diverse shapes generated by diffusion are given, in Table I, as functions of the latent dimensionalities of the support of the motion and of the diffusion itself. Part 3: It is argued that every fractal point set has a unique fractal dimensionality, but it is pointed out that many fractals involve diverse combinations of many fractal point sets. Such is, in particular, the case for fractal measures and for fractal graphs, often called hierarchical lattices. The fractal measures that the author had introduced in the early 1970s are described, including new developments. 相似文献
14.
Summary A global LSER model that relates HPLC retention to mobile phase composition and pH is tested for a varied group of solutes,
both neutral and ionizable, in a polymeric column and methanol-water mobile phases. It is compared to the local LSER model
developed only for a given mobile phase, i.e., a fixed organic modifier content, and to the global LSER model set only for
neutral solutes. The global LSER model for neutral and ionizable solutes requires a few supplementary parameters over the
other models tested, but it accounts for retention under any experimental conditions for a given column and methanol-water
mobile phases, describing properly the interactions established in the HPLC system (hydrophobicity, hydrogen-bond acidity
and basicity, dipolarity/polarizability…).
This paper is number 13 of a series with the same general title: “Retention of Ionizable Compounds on HPLC” published in various
journals. 相似文献
15.
Summary Retention models for ionic compounds in reversed-phase ion-pair chromatographic systems have been developed on the basis of
the capacity ratios of solutes and ionic mobile phase components using indirect detection. The binding to the adsorbent, μBondapak
Phenyl, has been expressed by ion-pair distribution constants and tested in the retention models by non-linear regression.
All the ionic compounds followed adsorption models of the Langmuir type comprising two kinds of binding sites with widely
different adsorption capacities and binding constants. The results indicate certain differences between the two sites regarding
the binding of cationic and anionic components, respectively. 相似文献
16.
Giuseppe Caruso 《Molecules (Basel, Switzerland)》2022,27(10)
Carnosine (β-alanyl-L-histidine) is a naturally occurring endogenous dipeptide and an over-the-counter food supplement with a well-demonstrated multimodal mechanism of action that includes the detoxification of reactive oxygen and nitrogen species, the down-regulation of the production of pro-inflammatory mediators, the inhibition of aberrant protein formation, and the modulation of cells in the peripheral (macrophages) and brain (microglia) immune systems. Since its discovery more than 100 years ago, a plethora of in vivo preclinical studies have been carried out; however, there is still substantial heterogeneity regarding the route of administration, the dosage, the duration of the treatment, and the animal model selected, underlining the urgent need for “coordinated/aligned” preclinical studies laying the foundations for well-defined future clinical trials. The main aim of the present position paper is to critically and concisely consider these key points and open a discussion on the possible “alignment” for future studies, with the goal of validating the full therapeutic potential of this intriguing molecule. 相似文献
17.
Oblique perforation of thick metallic plates by rigid projectiles with various nose shapes is studied in this paper. Two perforation mechanisms, i.e., the hole enlargement for a sharp projectile nose and the plugging formation for a blunt projectile nose, are considered in the proposed analytical model. It is shown that the perforation of a thick plate is dominated by several non-dimensional numbers, i.e., the impact function, the geometry function of projectile, the non-dimensional thickness of target and the impact obliquity. Explicit formulae are obtained to predict the ballistic limit, residual velocity and directional change for the oblique perforation of thick metallic plates. The proposed model is able to predict the critical condition for the occurrence of ricochet. The proposed model is validated by comparing the predictions with other existing models and independent experimental data.The English text was polished by Keren Wang 相似文献
18.
Active control of a flexible cantilever plate with multiple time delays is investigated using the discrete optimal control method. A controller with multiple time delays is presented. In this controller, time delay effect is incorporated in the mathematical model of the dynamic system throughout the control design and no approximations and assumptions are made in the controller derivation, so the system stability is easily guaranteed. Furthermore, this controller is available for both small time delays and large time delays. The feasibility and efficiency of the proposed controller are verified through numerical simulations in the end of this paper. 相似文献
19.
对实腹式波形顶板-UHPC(超高性能混凝土)组合桥面板进行了改进, 采用空腹式结构建立波形钢板-UHPC组合桥面板有限元模型, 研究UHPC层厚度、波形钢板厚度、波形长度、下缘板宽度和波形高度等截面参数变化对组合桥面板受力特性的影响, 并确定其合理取值范围. 在此基础上, 通过理想点法对参数组合进行优化, 得到合理的参数匹配. 研究结果表明 相较于实腹式组合桥面板, 优化后的组合桥面板自重减小35%, 钢板弯折处应力减小16%; 相较于正交异性钢桥面板, 桥面板用钢量减小7%, 顶板与U肋连接位置应力减小47%. 相似文献
20.