Oxygen‐barrier properties of copolymers based on ethylene terephthalate

The oxygen‐barrier properties of amorphous polyethylene terephthalate‐based copolymers with various acid comonomers were examined. The incorporation of increasing amounts of isophthalate, phthalate, or naphthalate gradually reduced the permeability P toward the low values obtained for the corresponding homopolymers. The permeability of poly(ethylene 3,4′‐bibenzoate) homopolymer was only slightly lower than that of polyethylene terephthalate, and the copolymers correspondingly exhibited a very gradual decrease in P as the amount of 3,4′‐bibenzoate (3,4′BB) increased. In contrast, copolymerization with the linear isomer, 4,4′BB, produced a substantial increase in P. Generally, comonomer affected the solubility S less than the diffusivity D, and therefore changes in P reflected primarily changes in D for the polymers studied. The diffusivity and solubility depended on the copolymer composition in accordance with static and dynamic free‐volume concepts of gas permeability in glassy polymers. The solubility S correlated with the amount of free volume as determined by the glass‐transition temperature. Correlation of the diffusivity D with the magnitude of the subambient γ relaxation identified dynamic free volume with thermally activated conformational changes and segmental motions. Correspondence in the activation energy confirmed the relationship. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1889–1899, 2001     

PKI域间互操作性研究

Internet作为电子商务和数字通信的基础平台面临着很多安全威胁.PKI技术为安全电子交易提供了保障.电子商务中.在不同的PKI域之间需要实现互操作.本文提出了一种不使用交叉证书的情况下连接多个独立的PKI域的新方法.该方法是将多个PKl域整合成一个PKI域来实现PKl域之间的互操作.本文采用形式化的方法来描述合并过程.     

Two splitting schemes for nonstationary convection-diffusion problems on tetrahedral meshes

Two splitting schemes are proposed for the numerical solution of three-dimensional nonstationary convection-diffusion problems on unstructured meshes in the case of a full diffusion tensor. An advantage of the first scheme is that splitting is generated by the properties of the approximation spaces and does not reduce the order of accuracy. An advantage of the second scheme is that the resulting numerical solutions are nonnegative. A numerical study is conducted to compare the splitting schemes with classical methods, such as finite elements and mixed finite elements. The numerical results show that the splitting schemes are characterized by low dissipation, high-order accuracy, and versatility.     

最优多期比例再保险策略的必要条件

研究最小化保险公司破产概率的最优多期比例再保险策略,给出了保险公司最小破产概率的一个递归表达式,证明了可用动态规划方法求解此类问题.在此基础上,我们推导出最优多期比例再保险策略的几个必要条件.     

Mortar element methods for parabolic problems

In this article a standard mortar finite element method and a mortar element method with Lagrange multiplier are used for spatial discretization of a class of parabolic initial‐boundary value problems. Optimal error estimates in L^∞(L²) and L^∞(H¹)‐norms for semidiscrete methods for both the cases are established. The key feature that we have adopted here is to introduce a modified elliptic projection. In the standard mortar element method, a completely discrete scheme using backward Euler scheme is discussed and optimal error estimates are derived. The results of numerical experiments support the theoretical results obtained in this article. © 2008 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2008     

Connection between an Exactly Solvable Stochastic Optimal Control Problem and a Nonlinear Reaction-Diffusion Equation

We present an exactly soluble optimal stochastic control problem involving a diffusive two-states random evolution process and connect it to a nonlinear reaction-diffusion type of equation by using the technique of logarithmic transformations. The work generalizes the recently established connection between the non-linear Boltzmann-like equations introduced by Ruijgrok and Wu and the optimal control of a two-states random evolution process. In the sense of this generalization, the nonlinear reaction-diffusion equation is identified as the natural diffusive generalization of the Ruijgrok–Wu and Boltzmann model.     

A new difference scheme with high accuracy and absolute stability for solving convection–diffusion equations

In this paper, we use a semi-discrete and a padé approximation method to propose a new difference scheme for solving convection–diffusion problems. The truncation error of the difference scheme is O(h⁴+τ⁵). It is shown through analysis that the scheme is unconditionally stable. Numerical experiments are conducted to test its high accuracy and to compare it with Crank–Nicolson method.     

An efficient ghost fluid method for compressible multifluids in Lagrangian coordinate

In this paper, we present an extended ghost fluid method (GFM) for computations of inviscid compressible multifluids in Lagrangian coordinate. That is, we capture the appropriate interface conditions by defining a fluid that has the velocity and the pressure of the real fluid at each point, but the entropy or the internal energy of some other fluid. Meanwhile, a single-fluid solver, CWENO-type central-upwind scheme, is developed in Lagrangian coordinate. The high resolution and the non-oscillatory quality of the scheme can be verified by solving several numerical experiments.     

On the reservoir technique convergence for nonlinear hyperbolic conservation laws - Part I

This paper is devoted to the analysis of flux schemes coupled with the reservoir technique for approximating hyperbolic equations and linear hyperbolic systems of conservation laws [F. Alouges, F. De Vuyst, G. Le Coq, E. Lorin, The reservoir scheme for systems of conservation laws, in: Finite Volumes for Complex Applications, III, Porquerolles, 2002, Lab. Anal. Topol. Probab. CNRS, Marseille, 2002, pp. 247-254 (electronic); F. Alouges, F. De Vuyst, G. Le Coq, E. Lorin, Un procédé de réduction de la diffusion numérique des schémas à différence de flux d'ordre un pour les systèmes hyperboliques non linéaires, C. R. Math. Acad. Sci. Paris 335 (7) (2002) 627-632; F. Alouges, F. De Vuyst, G. Le Coq, E. Lorin, The reservoir technique: A way to make Godunov-type schemes zero or very low diffusive. Application to Colella-Glaz, Eur. J. Mech. B Fluids 27 (6) (2008)]. We prove the long time convergence of the reservoir technique and its TVD property for some specific but still general configurations. Proofs are based on a precise study of the treatment by the reservoir technique of shock and rarefaction waves.     

单片机在设计性物理实验中的应用

在设计性物理实验中引入单片机技术 ,使学生了解怎样实现测量数字化与自动化 ,初步掌握信号放大、数据采集、编程等基本方法