Effects of two benzenedicarboxylic acids on the construction of CdII coordination polymers incorporating a flexible N‐donor ligand

Compared with the monomorphic type of ligand, combining mixed ligands in one coordination polymer offers greater tunability of the structural framework. Employment of N‐heterocyclic ligands and aromatic polycarboxylates is an effective approach for the construction of metal–organic frameworks (MOFs). Two new coordination polymers incorporating both 2‐[(1H‐imidazol‐1‐yl)methyl]‐1H‐benzimidazole (imb) and benzenedicarboxylic acid isomers, namely, catena‐poly[[[di‐μ‐chlorido‐bis[(2‐carboxybenzoato‐κ²O¹,O^1′)cadmium(II)]]‐bis{μ‐2‐[(1H‐imidazol‐1‐yl)methyl]‐1H‐benzimidazole‐κ²N:N′}] dihydrate], {[Cd(C₈H₅O₄)Cl(C₁₁H₁₀N₄)]·H₂O}_n, (I), and poly[[aqua(μ₂‐benzene‐1,3‐dicarboxylato‐κ³O¹,O^1′:O³){μ₂‐2‐[(1H‐imidazol‐1‐yl)methyl]‐1H‐benzimidazole‐κ²N:N′}cadmium(II)] dihydrate], {[Cd(C₈H₄O₄)(C₁₁H₁₀N₄)(H₂O)]·2H₂O}_n, (II), have been prepared and structurally characterized by single‐crystal X‐ray diffraction. In polymer (I), imb ligands bridge Cd^II ions, forming a one‐dimensional chain, and 2‐carboxybenzoate anions coordinate to the Cd^II ions in a terminal fashion. Polymer (II) exhibits a two‐dimensional network structure in which imb ligands and the benzene‐1,3‐dicarboxylate anions join Cd^II ions co‐operatively. This indicates that changing of the aromatic dicarboxylic acids can result in polymers with different compositions and architectures. Moreover, their IR spectra, PXRD (powder X‐ray diffraction) patterns, thermogravimetric analyses and fluorescence properties were also investigated.     

基于GIS的工程移民安置区选择模糊评价模型

基于GIS和模糊数学理论,提出了工程移民安置区选择评价模型,为移民安置区选择提供了一种新的决策方法.该模型通过采用熵信息论建立了综合考虑主客观影响的复合均权法得到指标的权重,减少了指标权重确定的片面性;并采用GIS空间分析功能生成安置区的备选集,从根本上保证了模糊评价的数据源质量,使得评价结果更加科学准确.最后结合应用示例,对模型进行实例分析,结果表明该模型是有效的.     

Application of the ultrasonic technique and high-speed filming for the study of the structure of air–water bubbly flows

Multiphase flows are very common in industry, oftentimes involving very harsh environments and fluids. Accordingly, there is a need to determine the dispersed phase holdup using noninvasive fast responding techniques; besides, knowledge of the flow structure is essential for the assessment of the transport processes involved. The ultrasonic technique fulfills these requirements and could have the capability to provide the information required. In this paper, the potential of the ultrasonic technique for application to two-phase flows was investigated by checking acoustic attenuation data against experimental data on the void fraction and flow topology of vertical, upward, air–water bubbly flows in the zero to 15% void fraction range. The ultrasonic apparatus consisted of one emitter/receiver transducer and three other receivers at different positions along the pipe circumference; simultaneous high-speed motion pictures of the flow patterns were made at 250 and 1000 fps. The attenuation data for all sensors exhibited a systematic interrelated behavior with void fraction, thereby testifying to the capability of the ultrasonic technique to measure the dispersed phase holdup. From the motion pictures, basic gas phase structures and different flows patterns were identified that corroborated several features of the acoustic attenuation data. Finally, the acoustic wave transit time was also investigated as a function of void fraction.     

NON-LOCAL MODELING ON MACROSCOPIC DOMAIN PATTERNS IN PHASE TRANSFORMATION OF NiTi TUBES

Recent experiments revealed many new phenomena of the macroscopic domain patterns in the stress-induced phase transformation of a superelastic polycrystalline NiTi tube during tensile loading. The new phenomena include deformation instability with the formation of a helical domain, domain topology transition from helix to cylinder, domain-front branching and loading-path dependence of domain patterns. In this paper, we model the polycrystal as an elastic continuum with nonconvex strain energy and adopt the non-local strain gradient energy to account for the energy of the diffusive domain front. We simulate the equilibrium domain patterns and their evolution in the tubes under tensile loading by a non-local Finite Element Method （FEM）. It is revealed that the observed loading-path dependence and topology transition of do- main patterns are due to the thermodynamic metastability of the tube system. The computation also shows that the tube-wall thickness has a significant effect on the domain patterns： with fixed material properties and interfacial energy density, a large tube-wall thickness leads to a long and slim helical domain and a severe branching of the cylindrical-domain front.     

An application of the wavelet analysis technique for the objective discrimination of two-phase flow patterns

This paper presents an application of the wavelet analysis technique for two-phase flow pattern identification by using the void fraction signals obtained from a multi-channel Impedance Void Meter (IVM) in a vertical-upward air–water flow. A new method for the objective discrimination of the two-phase flow pattern has been developed to provide information regarding the local energy of void fraction signals at a given scale on the joint time–frequency diagram. The void signals are processed with Continuous Wavelet Transform (CWT) to get the local wavelet energy coefficients map on the time–frequency diagram. The effective local wavelet energy and the effective scale are then calculated. Then the criteria for flow pattern identification are, finally, obtained. A series of void fraction measurements were conducted over a wide range of air–water vertical-upward flow condition to provide an extensive database to cover several types of flow patterns. The results show that the proposed method has a high precision for characterizing different flow regimes in two-phase flow, and is considerably more promising for the online recognition of two-phase flow patterns due to the short time of data processing.     

The stress concentration near a rigid line inclusion in a prestressed, elastic material. Part I.: Full-field solution and asymptotics

A lamellar (zero-thickness) rigid inclusion, so-called ‘stiffener’, is considered embedded in a uniformly prestressed (or prestrained), incompressible and orthotropic elastic sheet, subject to a homogeneous far-field deformation increment. This problem is solved under the assumption of plane strain deformation, with prestress principal directions and orthotropy axes aligned with the stiffener. A full-field solution is obtained solving the Riemann-Hilbert problem for symmetric incremental loading at infinity (while for shear deformation the stiffener leaves the ambient field unperturbed). In addition to the full-field solution, the asymptotic Mode I near-tip representation involving the corresponding incremental stress intensity factor are derived and these results are complemented with the Mode II asymptotic solution. For null prestress, the full-field stress state is shown to match correctly with photoelastic experiments performed by us (on two-part epoxy resin samples containing an aluminum lamina). Our experiments also confirm the fracture patterns for a brittle material containing a stiffener, which do not obey a hoop-stress criterion and result completely different from those found for cracks. Issues related to shear band formation and evaluation of energy release rate for a stiffener growth (or reduction) are deferred to Part II of this article.     

浙江省玄武岩台地地貌及地质灾害

浙江省玄武岩台地地质灾害十分发育．从古沉积环境和微地貌分析入手,根据台地形成的古地理环境,划分了5种基本的台地类型,提出了玄武岩台地的微地貌划分方法,并探讨了玄武岩台地区地质灾害发育的特殊地貌条件．研究表明河谷型台地地质灾害最为发育,台地前缘斜坡亚区是地质灾害的多发微地貌区,地质灾害的规模与地形切割深度具有较好的正相关性,从而为基于地貌分区的地质灾害易发程度评价提供了可能．     

水平管内油气水三相流分流型阻力特性实验研究

对水平管内油气水三相流的摩擦阻力压降特性进行了实验研究,水平管实验段由有机玻璃管制成,内径为40mm,所用的实验工质为:46#机械油,自来水和空气。油、气、水三相的折算速度范围分别为:0.05-0.51m／s、0.05-1.51m／s、0.02-50.6 m／s。按照气液界面总体特征将水平管内油气水三相流的流型分为泡状流、间歇流(段塞流和弹状流)、分层流及环状流。对各种典型流型下的摩擦阻力压降应用改进的Chisholm关系式及油水两相压降关系式进行分析,对Chisholm关系式中的参数C进行了重新定义。发现改进的Chisholm关系式能够较好地对管内油气水三相摩阻压降进行预测,因此改进Chisholm关系式可以作为摩擦压降计算的通用关系式。     

基于J2EE的数字校园系统架构研究

数字化校园建设已经成为目前高等院校发展信息化建设的一个重要目标,针对构建一个稳定、灵活、安全的数字校园系统提出了一个基于J2EE的数字校园系统架构解决方案.     

Plastic deformation modelled as a self-excited wave process at the meso- and macro-level

A self-excited wave model is developed to describe plastic flow phenomena in crystalline solids. Experimental observations suggest that by plastic flow in single crystals and polycrystalline materials, different underlying mechanisms are responsible for key features of strain localisation corresponding to different stages of the deformation curve. The major autowave (self-excited wave) types manifest themselves in plastically deforming materials. The self-excited wave model could explain plastic flow pattern behaviour corresponding to different physical mechanisms.