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31.
We study reflection diffuse optical tomography using two-dimensional (2D) continuous-wave source-detector arrays on the surface
of semi-infinite medium, aiming at imaging the perfusion and the hemoglobin oxygen saturation variation of human cerebral
cortex with brain activation. We had previously formulated the inverse problem with Moore-Penrose inversion. When we use simple
regularization in this inverse problem, the reconstruction sensitivity decreases markedly with the depth so that the signal
in the deep range may be masked by an unwanted signal in the shallow range. In this paper, we propose a depth-adaptive regularized
reconstruction, in which we assign a smaller regularization parameter with the depth. We demonstrate improvement of the three-dimensional
(3D) reconstruction uniformity using the proposed scheme. 相似文献
32.
33.
The introduction of UV-Vis absorption spectrophotometry to the study of radiation chemistry of polymers has opened the possibility to investigate even very opaque samples. The virgin powder polypropylene, as obtained from the industrial production line, shows after irradiation unstable products of radiolysis. Until now they were investigated mainly by EPR method. Optical absorption spectra (by diffuse reflection spectrophotometry) contribute to better identification and study of changes in time, temperature and diffusion of reactive gases. Studying the formation of stable compounds, which do not produce EPR signal, we are able to examine these species on the basis of their electronic spectra. The most important results concern the peroxides in irradiated polypropylene. 相似文献
34.
M. Yu. Doladov V. S. Kazakevich I. G. Kalashnikov V. V. Kupaeva V. A. Shcherbakov 《Journal of Applied Spectroscopy》2001,68(4):708-710
The results of an investigation of the reflection spectrum of the human tympanic membrane in the visible and near IR ranges ( = 400–900 nm) are reported. 相似文献
35.
This paper describes measurements of a vibrating object with rough surface by the time-averaged method of holography using a newly designed optically addressed liquid crystal spatial light modulator with a resolution of 102 lp/mm and a diffraction efficiency of 16%. An object vibrating faster than several tens of Hz could be visualized. The pattern obtained by the method provides the locus of vibrating nodes. The advantage of this method is that a high contrast pattern of a vibrating object can be imaged in near-real-time, although the sensitivity of vibration is decreased. 相似文献
36.
以Ag/Al2O3为催化剂,采用原位漫反射傅里叶变换红外光谱法研究了SO2对C3H6选择性还原NOx反应的影响. 结果表明, SO2在催化剂表面转化为硫酸盐,并且随着硫酸盐累积量的增加,其主要红外特征吸收峰由低波数向高波数漂移. 高浓度表面硫酸盐的存在不仅抑制了催化剂表面硝酸盐的生成,而且抑制了硝酸盐与表面烯醇式物种(RCH=CH-O-)或乙酸盐物种进一步反应,生成活泼的反应中间体异氰酸酯(-NCO), 这是导致Ag/Al2O3催化剂上C3H6选择性还原NOx活性降低的主要原因. 相似文献
37.
A new methodology for the determination of the fluorescence quantum yield of dyes adsorbed onto microcrystalline cellulose is presented and applied to rhodamine 101, cresyl violet and auramine O. It is based on a previously reported method by Ruetten and Thomas (J. Phys. Chem., 1998, 102, 598-606), which is not applicable to the dyes used in the present study. It uses ground-state diffuse reflectance spectra obtained with and without filters, which prevents the luminescence of the dye from reaching the integrating sphere and the photodetector. New equations are presented here, correcting for the fluorescence emission of the dye, which depends on the detector sensitivity. Cut-on filters, which have a transmittance close to unity in the absorption region, and close to zero in the emission region, of the dye are used to obtain corrected reflectance spectra. The influence of the substrate was also taken into account. This methodology may be applied to other probes and surfaces or emissions of a different nature (i.e., phosphorescence or delayed fluorescence), and constitutes a very simple and general procedure to solve the important problem of luminescence quantum yield determination of probes adsorbed onto solid powdered surfaces. 相似文献
38.
A. P. Prishivalko 《Journal of Applied Spectroscopy》1997,64(1):94-100
A method for finding the optimum sizes of pigment particles, their volume concentration, and the paint coating thickness that
provide the covering power and the required coloristic characteristics of reflected light for the minimum flow rate of pigments
is based on using a four-flow approximation of the solution to the equation of radiation transfer in dispersion media and
is extended to coatings of complex composition. The capabilities of the method are demonstrated by examples of coatings of
mixtures of hematite and rutile particles in a binder with n=1.5 for variations of the modal size and the half-width of the
size distribution of the pigment particles.
B. I. Stepanov Institute of Physics, Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 90–96, January–February, 1997. 相似文献
39.
近红外漫反射光谱法对固态样品的无损分析 总被引:1,自引:0,他引:1
本文应用目标因子分析研究了固态样品的近红外漫反射光谱,用目标因子分析成功地确定了固态样品的物种数、物种种类和各物种的含量。 相似文献
40.
芦丁和维生素C的近红外漫反射光谱技术定量分析研究 总被引:17,自引:1,他引:17
首次利用近红外漫反射技术和偏最小二乘法定量分析了复方芦丁片的主组分芦丁和维生素C混合样品的含量,所建立的预测方程对样品的预测值和真实值之间的相关系数为99.75%,芦丁和维生素C定标标准差分别为0.363%和1.078%。该方法快速、准确、不破坏样品。 相似文献