Solubility of 1-Butene in Water and in a Medium for Cultivation of a Bacterial Strain

Solubility measurements of 1-butene in water, from 20 to 50°C and at atmospheric pressure, were carried out using a Ben-Naim/Baer-type apparatus. The experimental results have a precision of about ±0.3%. Using accurate thermodynamic relations, the Ostwald coefficients at the experimental conditions and at infinite dilution, the mole fractions of the dissolved gas at the gas partial pressure of 101.325 kPa and the Henry coefficients at the water vapor pressure were calculated. The mole fraction of dissolved gas were fitted to the Clarke, Glew, and Weiss equation and thermodynamic quantities, standard molar Gibbs energy, entropy, and enthalpy changes, for the process of transferring the 1-butene molecules from the gaseous to the water phase, were computed. Moreover, solubility measurements of 1-butene in an aqueous medium for the cultivation of Xanthobacter Py2 in the same temperature range were also performed at atmospheric pressure. These solubility data are approximately 2.6% lower than those observed in pure water.     

Enthalpies of solution and of crystallization of lithium nitrate and of lithium nitrate trihydrate in water at 25°C

The enthalpies of crystallization of LiNO₃ and LiNO₃–3H₂O from aqueous solutions at 25°C, measured by a calorimetric method and determined from the previously published data on the concentration dependence of the enthalpy of solution, are reported. The results are compared with the values obtained from the concentration dependences of the activity coefficients and from the temperature dependences of the solubilities. The enthalpy of solution at infinite dilution and the enthalpy of hydration are given.     

Interactions of native and modified cyclodextrins with some B-vitamins

Interactions of native and modified α- and β-cyclodextrins with nicotinic acid, pyridoxine and pyridoxal were studied by isothermal titration calorimetry, solution calorimetry, and ¹H NMR spectroscopy at 298.15 K and pH 6.8. Weak 1:1 complex formation was found only between α-cyclodextrin and nicotinic acid. The stability constant and corresponding thermodynamic parameters of complex formation (Δ_c G, Δ_c H and Δ_c S) were calculated using the calorimetric data. The ¹H NMR data indicate the shallow insertion of the carboxylic group of the nicotinic acid molecule into α-CD cavity. For all other compounds the weak interactions, not accompanied by complex formation, were characterized by the enthalpic virial coefficients calculated on the basis of McMillan-Mayer approach. The obtained thermodynamic parameters were analyzed in the terms of influence of the solutes’ structure on the selectivity of intermolecular host-guest interactions.     

Phase-fixed double-group 3-Γ symbols. IV. Real 3-Γ symbols and coupling coefficients for the group hierarchies T* ⊃ C 3 * and T* ⊃ C 2 *

We present sets of real 3- symbols which correspond to explicitly given irreducible matrix representations for the two double group hierarchies T* C ₃ ^* and T* C ₂ ^* . They fit into the formalism exposed in a previous paper [1] on the general theory of 3- symbols and coupling coefficients and illustrate much of the discussion in a subsequent one [2] treating the particular properties of the double groups.     

Liquids and liquid mixtures: Deduction of the BGY equation considering the angular distribution function

The Born→Green→Yvon equation for molecular fluid has been deduced considering the orientational distribution functions. The isotropic and anisotropic parts of the distribution function have been separated. The expressions deduced can be used in the case of mixtures and for the non-central type of intermolecular potential energy.     

Jerk Influence Coefficients,via Screw Theory,of Closed Chains

In this paper a novel method for determining the kinematic influence coefficients up to the jerk analysis of closed chains with multiple degrees of freedom by means of screw theory, also known as motor algebra, is introduced. A closed chain is obtained by rigidly attaching the end-effector of a serial chain to the base link. This condition ensures that the velocity, acceleration, and jerk, both angular and of any point fixed to the end-effector are zero. Afterwards, a comparison between the kinematic equations of motion, up to the jerk analysis, obtained by traditional methods with those obtained by means of screw theory reveals the corresponding influence coefficients associated to the generalized coordinates employed to represent the motion of the closed chain. Finally, a numerical example is provided. Sommario. In questo lavoro viene proposto un nuovo metodo per la determinazione dei coefficienti che consentono di sviluppare l'analisi cinematica (jerk incluso) di catene chiuse a molti gradi di liberta' per mezzo della screw theory o algebra dei moti spaziali. La catena chiusa e' ottenuta attaccando rigidamente l'end-effector di una catena seriale al membro di base. Questa condizione assicura che velocita' accelerazione e jerk, sia nel moto angolare che per ciascun punto solidale con l'end-effector siano nulli. Un confronto tra le equazioni cinematiche del moto, inclusa l'analisi del jerk, ottenute con metodi tradizionali e quelle ottenute dalla screw theory, mostra i corrispondenti coefficienti di influenza associati alle coordinate generalizzate impiegate per descrivere il moto della catena chiusa. Un esempio numerico conclude il lavoro.     

Maximal <Emphasis Type="Italic">L</Emphasis><Superscript><Emphasis Type="Italic">p</Emphasis></Superscript>‐regularity for elliptic operators with VMO‐coefficients

In this paper we show that the parabolic problem associated with elliptic operators A having coefficients in has the property of maximal -regularity. RID="h1" ID="h1"In Memoriam Philippe Bénilan     

N2-broadening coefficients in the ν2 and ν4 bands of PH3 at low temperature

N₂-broadening coefficients have been measured for 41 transitions of PH₃ at −100 °C in the ^QR branch of the ν₂ band and the ^PP, ^RP, and ^SP branches of the ν₄ band, using a tunable diode-laser spectrometer. The recorded lines with J values ranging from 1 to 13 and K from 0 to 10 are located between 1026 and 1093 cm⁻¹. The collisional widths are determined by fitting each spectral line with a Voigt profile, a Rautian profile, and a speed-dependent Rautian profile. The latter models provide larger broadening coefficients than the Voigt model. These coefficients have also been calculated on the basis of a semiclassical model of interacting linear molecules by considering an atom-atom Lennard-Jones potential in addition to the electrostatic contributions. By comparing broadening coefficients at room and low temperatures, the temperature dependence of these broadenings has been determined both experimentally and theoretically.     

Diffusion coefficients from stopped-flow gas chromatography

Summary Mutual diffusion coefficients of two gases A and B can be determined in an empty gas chromatographic column by letting component B enter at an intermediate position of the column and continuously flow through a part only of it, as a carrier gas. The other component A is injected in a small amount instantaneously at the closed end of the column with the detector placed at the other end. By repeatedly stopping and then restoring after a short time the flow of B, narrow extra peaks are produced on the chromatographic elution curve, owing to diffusion of A into B. An equation is derived giving the area under the curve of each stop-peak as a function of time of the corresponding stop. Plotting the experimental data according to this equation permits the determination of the diffusion coefficient of A into B. Some results obtained by this method show negligible variations with changes in the experimental parameters.     

Nonstandard decision methods for the solvability of real polynomial equations

For a multivariate polynomial equation with coefficients in a computable ordered field, two criteria of this equation having real solutions are given. Based on the criteria, decision methods for the existence of real zeros and the semidefiniteness of binaly polynomials are provided. With the aid of computers, these methods are used to solve several examples. The technique is to extend the original field involved in the question to a computable non-Archimedean ordered field containing infinitesimal elements. Project supported by the National Natural Science Foundation of China (Grant No. 19661002) and the Climbing Project.