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131.
Alberto García‐Peas Yu Wang Alexandra Muoz‐Bonilla Marta Fernndez‐García Florian J. Stadler 《Journal of Polymer Science.Polymer Physics》2019,57(20):1386-1393
The effect of the molecular weight on the lower critical solution temperature (LCST) has been discussed extensively, where LCST increased with molar mass, decreased or kept constant, which leads to confusion. This work is focused on the preparation of poly(N‐isopropyl acrylamide) homopolymers, obtained in a wide molecular weights range. The LCST behavior is analyzed by calorimetry and rheology, and a deep study of molecular features is carried out for a better knowledge of the influence of various parameters involved on LCST. Finally, the molecular weight trend is observed, and its influence on LCST is compared with the effect of other parameters as polymer concentration in water, end‐group effect, and tacticity. It is observed that other parameters such tacticity and end‐group effect will affect the LCST behavior over molecular weight, if this one is not high enough. Furthermore, the study of the LCST ranges will be a useful tool for analyzing the molecular weight trends. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 1386–1393 相似文献
132.
133.
134.
Pool boiling heat transfer performances of Cu-Al2O3-coated copper surfaces have been studied experimentally for its potential use in heat transfer applications. In the present study, a two-step electrochemical deposition method is examined. This method provides an easy control on surface properties such as porosity and coating thickness. The deposition method is studied carefully and responsible surface morphology parameters are reported. After performing the pool boiling experiments on coated surfaces with DI water, the maximum critical heat flux of 1800 kW/m2 and heat transfer coefficient of 193 kW/m2 K, which are 68% and 260% higher than that of bare surface, respectively. 相似文献
135.
The effect of the quenching rate on the phase separation of partially miscible liquid mixtures is studied, showing that it may influence the growth rate of single-phase domains. In particular, the phase separation of metastable binary mixtures in the presence of strong emulsifiers appears to be heavily retarded. These effects constitute an important limitation to the phase transition extraction process introduced by the authors in previous works, which is based on the fact that phase separation of unstable mixtures is rapid, even in the presence of surface active compounds. 相似文献
136.
137.
A model is considered in which the bonds of a lattice are covered by rodlike molecules. Neighboring molecular ends interact with orientation-dependent interactions. The model exhibits closed -loop phase diagrams and double critical points. Exact coexistence surfaces are calculated for the model on the Bethe, honeycomb, and square lattices. The nature of the doubling of the critical exponent near a double critical point is calculated. The behavior of the critical line in the neighborhood of a double critical point is calculated exactly. 相似文献
138.
A theoretical framework for treating the effects of magnetic fieldH on the pairing theory of superconductivity is considered, where the field is taken in an arbitrary direction with respect
to crystal axes. This is applicable to closed, as well as open normal state Fermi surface (FS), including simple layered metals.
The orbital effects of the magnetic field are treated semiclassically while retaining the full anisotropic paramagnetic contribution.
Explicit calculations are presented in the limits |H| → |H
c2(T)|,T ∼ 0 andT →T
c(|H|), |H| ∼ 0. Effects of weak nonmagnetic impurity scattering, without vertex corrections, have also been taken into account in a
phenomenological way. The final results for the case of open FS and layered materials are found to differ considerably from
those of the closed FS. For example, an important parameter,h(T=0)=|Hc2(0)|/[-Tδ|H
c2
T|δT]T{s0} for the case of a FS open ink
z-direction with thek
z-bandwidth, 4t
3, very small compared to the Fermi energy,E
F, is close to 0.5906, compared to 0.7273 for the closed FS, in the clean limit. Analytical results are given for the magnetic
field dependence ofT
c and the temperature dependence of H
c2 for a model of layered superconductors with widely open FS. For a set of band structure parameters for YBa2Cu3O7 used elsewhere, we find reasonable values for the upper critical fieldH
c2(0), the slope (dH
c2/dT)T
c0, anisotropic coherence lengths ζi(T=0),i=x, y, z, and (dT
c/d|H|)|H| → 0. 相似文献
139.
LetΩR~N be a smooth bounded domain such that 0∈Ω,N≥5,2~*:=(2N)/(N-4) is the critical Sobolev exponent,and f(x) is a given function.By using the variational methods, the paper proves the existence of solutions for the singular critical in the homogeneous problemΔ~u-μu/(|x|~4)=|u|~(2~*-2)u f(x) with Dirichlet boundary condition on Ωunder some assumptions on f(x) andμ. 相似文献
140.
René Michel 《Extremes》2007,10(3):83-107
The investigation of multivariate generalized Pareto distributions (GPDs) has begun only recently. For further progress with
these distributions simulation methods are an important part. We describe several methods of simulating GPDs, beginning with
an efficient method for the logistic GPD. The algorithm is based on the Shi transformation, which was already used for the
simulation of multivariate extreme value distributions (EVDs) of logistic type. In the sequel another algorithm is presented
simulating a broader class of GPDs. Due to its numerical complexity it is only practicably applicable in low dimensions. A
method is given to generate unconditional GPD random vectors from conditionally GPD distributed random vectors. A short application
of the simulation methods in the analysis of a real hydrological data set concludes the article. The simulation algorithms
are available on the author’s home page .
相似文献