Search for a Steric Penultimate Effect: Copolymerization of 2,3,4-Trimethyl-3-pentyl Methacrylate with Styrene

The hindered monomer, 2,3,4-trimethyl-3-pentyl methacrylate (I), was synthesized for penultimate effect studies. Since it readily homopoiymerized (km¹¹¹≠ 0) and readily copolymerized with styrene, copolymerizations of I with styrene were carried out at 60°C in benzene with AIBN as initiator. The conversion to copolymer and the copolymer composition were determined by using GLC techniques. Composition-conversion data was analyzed by performing a computerized nonlinear least-squares fitting to the integrated form of the penultimate model equation. The experimental design included the use of optimized M¹°/M²° ratios. The penultimate reactivity ratios calculated from these data were r¹′ = 0.23, r¹′= 0.59, r² = 0.59, r²′ = 1.34. Thus, when I is the penultimate unit, a terminal styryl radical prefers to add styrene, whereas when styrene is the penultimate unit, terminal styryl radicals prefer to add I. These results constitute the best evidence for a steric penultimate effect yet available in the literature from composition-conversion studies. However, the case is not yet proved. Further studies to strengthen this conclusion are proposed.     

一类雨量预报准确性评价方法

给出了一种利用网格点的预报雨量来模拟区域内任一点预报雨量的方法,建立了预报雨量函数,进而得出预报雨量与实测雨量的整体偏方差的数学模型;利用QPF方法建立出准确率、预报效率、空报率、漏报率等评价预报方法优劣指标的数学模型,并对两种预报方法得出的数据进行了计算,得出上述模型中的数值如下:方案方法总体偏方差预报准确率漏报率空报率预报效率方法1 0.99987×10679.431%11.463%25.621%62.256%方法2 1.00518×10657.509%26.976%31.705%58.936%比较这些指标,可得第一种预报结果较好.     

A control volume finite element method for three-dimensional three-phase flows

A novel control volume finite element method with adaptive anisotropic unstructured meshes is presented for three-dimensional three-phase flows with interfacial tension. The numerical framework consists of a mixed control volume and finite element formulation with a new P₁DG-P₂ elements (linear discontinuous velocity between elements and quadratic continuous pressure between elements). A “volume of fluid” type method is used for the interface capturing, which is based on compressive control volume advection and second-order finite element methods. A force-balanced continuum surface force model is employed for the interfacial tension on unstructured meshes. The interfacial tension coefficient decomposition method is also used to deal with interfacial tension pairings between different phases. Numerical examples of benchmark tests and the dynamics of three-dimensional three-phase rising bubble, and droplet impact are presented. The results are compared with the analytical solutions and previously published experimental data, demonstrating the capability of the present method.     

Evolution of vortices in the wake of an ARJ21 airplane: Application of the lift-drag model

Wake separation is crucial to aircraft landing safety and is an important factor in airport operational efficiency. The near-ground evolution characteristics of wake vortices form the foundation of the wake separation system design. In this study, we analysed the near-ground evolution of vortices in the wake of a domestic aircraft ARJ21 initialised by the lift-drag model using large eddy simulations based on an adaptive mesh. Evolution of wake vortices formed by the main wing, flap and horizontal tail was discussed in detail. The horizontal tail vortices are the weakest and dissipate rapidly, whereas the flap vortices are the strongest and induce the tip vortex to merge with them. The horizontal tail and flap of an ARJ21 do not significantly influence the circulation evolution, height change and movement trajectory of the wake vortices. The far-field evolution of wake vortices can therefore be analysed using the conventional wake vortex model.     

一类无结构三角网上抛物方程的有限差分区域分解算法

本文讨论了一类在无结构三角网上数值求解二维热传导方程的有限差分区域分解算法．在这个算法中,将通过引进两类不同类型的内界点,将求解区域分裂成若干子区域．一旦内界点处的值被计算出来,其余子区域上的计算可完全并行．本文得到了稳定性条件和最大模误差估计,它表明我们的格式有令人满意的稳定性和较高的收敛阶．     

THE GENERALIZED MAXIMUM ANGLE CONDITION FOR THE Q1 ISOPARAMETRIC ELEMENT

We consider the quadrilateral Q1 isoparametric element and establish an optimal error estimate in H^1 norm for the interpolation operator under a weaker mesh condition which admits anisotropic quadrilaterals and allows the quadrilateral to become a regular triangle in the sense of maximum angle condition [5, 11].     

光学透明频率选择表面的设计研究

以氟化镁为基底材料, 采用基底、金属网栅与频率选择表面一体化设计方法设计了一种雷达波与光学波段双带通的结构. 利用模式匹配法对设计结构的传输特性进行了仿真研究, 并将设计结果与制备样件的测试结果进行了对比分析. 结果发现: 采用一体化设计的方法设计光学透明频率选择表面, 不仅能够快速得到电场基函数而且还能够准确预估其谐振尺寸, 从而在提高计算效率的同时避免了模式互作用零点的出现. 采用一体化设计方法获得了具有稳定滤波特性的光学透明频率选择表面, 为雷达/红外双模制导头罩的电磁屏蔽技术和隐身技术提供了一种有效技术方案. 关键词： 复合制导 频率选择表面 金属网栅 一体化设计     

辐射流体力学的分子动理学自适应加密方法(英文)

通过构造新的平衡分布函数和结合分区自适应网格加密方法,对不带扩散项的平衡辐射流体力学方程,构造二阶的分子动理学BGK-AMR格式.一方面在关心的计算区域中局部加密计算网格,提高计算精度的同时大大节省了计算网格数量和计算时间;另一方面,不同于已有的参数强耦合平衡分布函数,新构造的平衡分布函数中各参数不相互依赖,简化了辐射流体力学分子动理学格式的计算.一维和二维的数值算例显示了格式的性能.     

求解带自由面渗流问题移动网格法的改进及其工程应用

采用有限元固定网格和移动网格相结合的方法,求解带自由面的坝体稳定渗流问题。本方法是针对一般坝体的结构,在有限元网格生成之后,又自动生成了网格移动所需的信息,实现了网格在迭代计算中随自由面的变化自动均匀移动;讨论了网格奇异的不同类型,提出了避免单元形状怪异的移动网格方法;在欧拉空间中分区记录坝体不同的渗透性能,在网格移动到新位置后,自动识别网格所在的物性空间,从而确定单元在新位置上的渗流系数。本文将该方法应用到吉林丰满混凝土重力坝防渗加固的实际工程当中,在考虑大坝原有防渗措施的前提下,利用数值分析,研究了防渗芯墙对大坝渗流性能的影响。计算结果表明,加芯墙后坝体自由面位置明显下移,湿水部分大为减少,坝基扬压力没有明显提升,下游出水点位置没有明显下降。计算过程表明,本文方法及措施具有很好的收敛性与稳定性,且收敛性与自由面初始位置的选择无关。     

求解二维三温辐射热传导方程组的一种网格自适应方法

在求解二维三温辐射热传导方程组的过程中,设计了一类新的基于Hessian矩阵的网格自适应算法.数值实验结果表明,与现在流行的基于一阶导数或通量的网格自适应技术相比,该算法能够大幅改善系统的能量守恒误差,并具有较高的整体计算效率.