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991.
Summary The structure of water in water/AOT/n-heptane reverse micelles has been studied as a function of the [H2O]/[AOT] ratio (W) by using the absorption IR due to O−H stretching modes in the 3800–3000 cm−1 range. The results show that the IR spectra can be expressed as a sum of contributions from bound- and bulk-like water. The
fraction of water in the two ?regions? within the water pool was evaluated as a function ofW. The ?bound? water region seems to hold 3.5 water molecules (corresponding to 7 O−H oscillators) per AOT molecule and its
formation is nearly complete atW>6.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
992.
ZHOU Shi-Qi 《理论物理通讯》2003,40(12)
Previous literature claims that the density functional theory for non-uniform non-hard sphere interaction potential fluid can be improved on by treating the tail part by the third order functional perturbation expansion approximation (FPEA) with the symmetrical and intuitive consideration-based simple function C0(3)(r1, r2, r3) =ζ∫ dr4a(r4 - r1)a(r4 - r2)a(r4 - r3) as the uniform third order direct correlation function (DCF) for the tail part,here kernel function a(r) = (6/πσ3)Heaviside(σ/2 - r). The present contribution concludes that for the mean spherical approximation-based second order DCF, the terms higher than second order in the FPEA of the tail part of the non-uniform first order DCF are exactly zero. The reason for the partial success of the previous a kernel function-based third order FPEA for the tail part is due to the adjustable parameter ζ and the short range of the a kernel function.Improvement over the previous theories is proposed and tested. 相似文献
993.
联合击中击不中变换相关器 总被引:9,自引:3,他引:6
将联合击中击 中变换相关器用于二值图像的目标识别。与常用的联合变换相关器相比,联合击中击不中变换相关器对联合变换相关器输入图像和参考图像进行互补编码。编码的目的在于通过联合变换相关器来一步实现形态学中的击中击不中变换。 相似文献
994.
上市公司经营绩效评价方法的典型相关分析 总被引:8,自引:0,他引:8
本文介绍了上市公司经营绩效的传统评价方法和EVA、MVA方法,并对几种方法进行了比较,采用典型相关分析方法,以沪市180指标股的相关数据进行了实证研究。我们发现EVA类指标与传统财务评价指标的结论是相一致的,都是公司经营绩效的有效反映。 相似文献
995.
Inthepreviouspaper',wedevelopedanewmodelforcorrelatingandpredictingthesolubilitiesofsolidsinsupercriticalfluids(SCFs),whichcanbegiveninthefollowingformin[yi/(l-"y,)]=njnon(RTdr)-'dp-inP BP C(l)wherethecoefficientofthepressuretermisgivenbyB=-n(RTd,')-,(2)InEqs(1)and(2),yZisthemolefractionofthesoluteinSCFphase,d.thebulkdensityofthesolvent,d,'thelocaldensityofthesolventsurroundingthesolute,Tabsollltetemperatllre,Ppressure,Rgasconstallt,andCconstant.Thevalidityofamodelshouldbeverifiedbycor… 相似文献
996.
We discuss the origins and the effects of mobility fluctuations of rigid, globular macromolecules on a solution's electrophoretic light scattering spectrum. Assuming a dilute solution, a modified van Hove self-correlation function is calculated via van Kampen's time-ordered cumulant method and the results are compared with less rigorous approaches. The consequences of generalizing to dynamic external fields are briefly considered. 相似文献
997.
Yasuyuki Toyooka 《Journal of multivariate analysis》1985,17(2):107-126
First, the second-order bias of the estimator of the autoregressive parameter based on the ordinary least squares residuals in a linear model with serial correlation is given. Second, the second-order expansion of the risk matrix of a generalized least squares estimator with the above estimated parameter is obtained. This expansion is the same as that based on a suitable estimator of the autoregressive parameter independent of the sample. Third, it is shown that the risk matrix of the generalized least squares estimator is asymptotically equivalent to that of the maximum likelihood estimator up to the second order. Last, a sufficient condition is given for the term due to the estimation of the autoregressive parameter in this expansion to vanish under Grenander's condition for the explanatory variates. 相似文献
998.
利用强子-强子碰撞的模型PYTHIA以及核-核碰撞的模型RQMD比较了各种电荷起伏测量量的快度依赖性,结果发现,这些测量量对快度的依赖性依赖于模型. 但是,电荷关联能很好地测量整体电荷守恒以及短程快度关联性质. 因此,被认为是一个好的反应电荷起伏的测量量. 相似文献
999.
In the strain field measurements, especially in large strain field measurements, the correlation coefficient values obtained by the digital speckle correlation method are usually very low due to the relative pixel movement of the subset. The measuring error, therefore, is increased. A primary method, that is called compensation algorithm, is introduced for improving the correlation coefficient. A flow scheme with the compensation algorithm of our software is developed and some improved techniques for reducing the calculation time and error are discussed in the paper. After obtaining a set of displacement data with high correlation coefficient, a de-noise wavelet processing is adopted. It is obvious that the measuring accuracy of the strain field is better then before. A strain field of testing experiment is performed with this compensation technique. The correlation coefficients can increase from 0.70 to 0.99, which will be of much benefit for the improvements of the measuring accuracy. 相似文献
1000.