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61.
毛细管电色谱研究进展 总被引:7,自引:2,他引:7
毛细管电色谱是一种新兴的具有高效,高选择性的微分离技术。本文评述了毛细管电色说的发展状况和相关的技术,并对其发展前景进行了展望,引用文献24篇 。 相似文献
62.
The solid diffusion coefficient of lithium-ion in LiCoO2 cathode material has been investigated by the capacity intermittent titration technique (CITT) at different voltages and at different charge/discharge cycles. By SEM, XRD and FTIR techniques, the structure of LiCoO2 was studied before and after charge-discharge cycles, and the relationship between solid diffusion coefficient and crystal structure was further discussed. CITT results show that the value of Li+ solid diffusion coefficient of LiCoO2 is about 10-12 cm2·s-1. During the whole charge-discharge cycles, the Li+ solid diffusion coefficient decreased within the voltage of 4.0~4.3 V, which is attributed to the change of the structure of LiCoO2. 相似文献
63.
64.
I. Esteban-Díez 《Analytica chimica acta》2006,555(1):84-95
Orthogonal WAVElet correction (OWAVEC) is a pre-processing method aimed at simultaneously accomplishing two essential needs in multivariate calibration, signal correction and data compression, by combining the application of an orthogonal signal correction algorithm to remove information unrelated to a certain response with the great potential that wavelet analysis has shown for signal processing. In the previous version of the OWAVEC method, once the wavelet coefficients matrix had been computed from NIR spectra and deflated from irrelevant information in the orthogonalization step, effective data compression was achieved by selecting those largest correlation/variance wavelet coefficients serving as the basis for the development of a reliable regression model. This paper presents an evolution of the OWAVEC method, maintaining the first two stages in its application procedure (wavelet signal decomposition and direct orthogonalization) intact but incorporating genetic algorithms as a wavelet coefficients selection method to perform data compression and to improve the quality of the regression models developed later. Several specific applications dealing with diverse NIR regression problems are analyzed to evaluate the actual performance of the new OWAVEC method. Results provided by OWAVEC are also compared with those obtained with original data and with other orthogonal signal correction methods. 相似文献
65.
自动化流动注射停流动力学分析仪的研制及其性能测试 总被引:1,自引:0,他引:1
本文研制了一套自动化流动注射停流动力学分析仪,该仪器由苹果Ⅱ型微机通过12位AD/DA卡,流动注射停流控制仪及用BASIC语言编制的软件控制泵的起动和停止,试样的输送和混合,数据采集和处理,结果显示和打印,通过以铁(Ⅲ)与硫氰酸盐的反应体系采用固定时间法和以钒(V)的胶束催化反庆体系采用安始速法的现场测试证明,该仪器具有结构简单,操作方便,恒温性能好,通用性强等特点。 相似文献
66.
脱蜡剂DF-1是一种含多种有机成分的碳氢化合物,经气相色谱-红外光谱联用分析后,确定了这些组分的组成与含量。 相似文献
67.
I. K. Battisha A. El Beyally S. Abd El Mongy A. M. Nahrawi 《Journal of Sol-Gel Science and Technology》2007,41(2):129-137
Structural characteristics of pure silica gel (silica-xerogel, SiO2) and silica gel doped with some rare earth elements (REEs) such as, praseodymium Pr3+, and Europium Eu3+, Erbium Er3+ and Holmium Ho3+ ions, with different concentrations ranging from 1 up to 6%, in the form of monolith materials were prepared by sol-gel technique,
Using tetra-ethoxysilane as precursor materials, which are of particular interest for sol-gel integrated optics applications.
Some structural features of sol-gel derived monolith are analyzed, namely the structure of nano-particle momolith samples,
based on X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR). We show that the XRD spectra of α-crystobalite are
obtained for the pure samples at 1100°C and even by doping with the four REEs ions. 相似文献
68.
O. F. Shlensky 《Journal of Thermal Analysis and Calorimetry》1993,40(3):941-947
New modifications of a contact heater are suggested for investigating thermal decomposition processes, as well as for determining
kinetic characteristics of substances under conditions of intense heating to a fixed constant temperature.
Zusammenfassung Zur Untersuchung von thermischen Zersetzungsprozessen und der Bestimmung der Reaktionskinetik von Substanzen bei intensivem Erhitzen auf vorgegebene konstante Temperaturen wird eine neue Abart von Kontakterhitzern beschrieben.相似文献
69.
A new element tracer technique has firstly been established to estimate the contributions of mineral aerosols from both inside and outside Beijing. The ratio of Mg/Al in aerosol is a feasible element tracer to distinguish between the sources of inside and outside Beijing. Mineral aerosol, inorganic pollution aerosol mainly as sulfate and nitrate, and organic aerosol are the major components of airborne particulates in Beijing, of which mineral aerosol accounted for 32%―67% of total suspended particles (TSP), 10%―70% of fine particles (PM2.5), and as high as 74% and 90% of TSP and PM2.5, respectively, in dust storm. The sources from outside Beijing contributed 62% (38%―86%) of the total mineral aerosols in TSP, 69% (52%―90%) in PM10, and 76% (59%―93%) in PM2.5 in spring, and 69% (52%―83%), 79% (52%―93%), and 45% (7%―79%) in TSP, PM10, and PM2.5, respectively, in winter, while only ~20% in summer and autumn. The sources from outside Beijing contributed as high as 97% during dust storm and were the dominant source of airborne particulates in Beijing. The contributions from outside Beijing in spring and winter are higher than those in summer, indicating clearly that it was related to the various meteorological factors. 相似文献
70.
毛细管色谱直接进样法测定白酒中高碳脂肪酸乙酯的研究 总被引:2,自引:0,他引:2
介绍了采用FFAP键合毛细管柱直接进样测定白酒中5种高碳脂肪酸乙酯的方法,操作简捷,定量准确,检测限低达04mg/L。用该法测定了各种香型近90个白酒样品。改变色谱条件后,在一次直接进样分析中除能测定高碳脂肪酸乙酯外,而且还能对白酒中醇、酯、醛、酮以及有机酸等52种香味组分进行定量测定,结果重现性良好。 相似文献