全文获取类型
收费全文 | 16142篇 |
免费 | 3219篇 |
国内免费 | 2349篇 |
专业分类
化学 | 9703篇 |
晶体学 | 273篇 |
力学 | 2589篇 |
综合类 | 152篇 |
数学 | 1825篇 |
物理学 | 7168篇 |
出版年
2024年 | 37篇 |
2023年 | 229篇 |
2022年 | 526篇 |
2021年 | 456篇 |
2020年 | 631篇 |
2019年 | 531篇 |
2018年 | 554篇 |
2017年 | 645篇 |
2016年 | 814篇 |
2015年 | 748篇 |
2014年 | 1019篇 |
2013年 | 1629篇 |
2012年 | 1118篇 |
2011年 | 1113篇 |
2010年 | 916篇 |
2009年 | 973篇 |
2008年 | 1024篇 |
2007年 | 1087篇 |
2006年 | 968篇 |
2005年 | 842篇 |
2004年 | 777篇 |
2003年 | 708篇 |
2002年 | 559篇 |
2001年 | 520篇 |
2000年 | 523篇 |
1999年 | 405篇 |
1998年 | 388篇 |
1997年 | 298篇 |
1996年 | 281篇 |
1995年 | 249篇 |
1994年 | 228篇 |
1993年 | 169篇 |
1992年 | 143篇 |
1991年 | 110篇 |
1990年 | 76篇 |
1989年 | 77篇 |
1988年 | 63篇 |
1987年 | 46篇 |
1986年 | 45篇 |
1985年 | 36篇 |
1984年 | 34篇 |
1983年 | 8篇 |
1982年 | 26篇 |
1981年 | 12篇 |
1980年 | 16篇 |
1979年 | 13篇 |
1978年 | 8篇 |
1973年 | 6篇 |
1971年 | 6篇 |
1957年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Rachel L. McSwain Alison R. Markowitz Kenneth R. Shull 《Journal of Polymer Science.Polymer Physics》2004,42(20):3809-3821
To develop a greater understanding of interfacial interactions between a semicrystalline polymer and a glassy polymer, adhesion tests were performed on very thin layers of poly(ethylene oxide) (PEO) sandwiched between two layers of poly(tetramethyl bisphenol A polycarbonate) (TMPC). The tests were designed to provide intimate contact between the surfaces while they were heated above the melting point of the PEO and cooled back to room temperature. A contact mechanics approach, based on the Johnson, Kendall, and Roberts theory, was used to determine values of the energy release rate describing the energetic driving force for crack propagation within the interfacial region. The ability to measure crack propagation at large values of the energy release rate was limited by rupture of the silicone elastomer that was used to provide a sufficiently compliant matrix for the adhesion experiment. By cycling the tensile stress at relatively low loading levels, we were able to measure fatigue crack propagation at values of the energy release rate that did not result in failure of the elastomer. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3809–3821, 2004 相似文献
32.
Jem‐Kun Chen I‐Kuan Lin Fu‐Hsiang Ko Chih‐Feng Huang Kuo‐Shen Chen Chia‐Hao Chan Feng‐Chih Chang 《Journal of Polymer Science.Polymer Physics》2004,42(22):4063-4074
Polybenzoxazine (PBZZ) thin films can be fabricated by the plasma‐polymerization technique with, as the energy source, plasmas of argon, oxygen, or hydrogen atoms and ions. When benzoxazine (BZZ) films are polymerized through the use of high‐energy argon atoms, electronegative oxygen atoms, or excited hydrogen atoms, the PBZZ films that form possess different properties and morphologies in their surfaces. High‐energy argon atoms provide a thermodynamic factor to initiate the ring‐opening polymerization of BZZ and result in the polymer surface having a grid‐like structure. The ring‐opening polymerization of the BZZ film that is initiated by cationic species such as oxygen atoms in plasma, is propagated around nodule structures to form the PBZZ. The excited hydrogen atom plasma initiates both polymerization and decomposition reactions simultaneously in the BZZ film and results in the formation of a porous structure on the PBZZ surface. We evaluated the surface energies of the PBZZ films polymerized by the action of these three plasmas by measuring the contact angles of diiodomethane and water droplets. The surface roughness of the films range from 0.5 to 26 nm, depending on the type of carrier gas and the plasma‐polymerization time. By estimating changes in thickness, we found that the PBZZ film synthesized by the oxygen plasma‐polymerization process undergoes the slowest rate of etching in CF4 plasma. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4063–4074, 2004 相似文献
33.
Junchai Zhao Shichun Jiang Xiangling Ji Lijia An Bingzheng Jiang 《Journal of Polymer Science.Polymer Physics》2004,42(18):3496-3504
The surface morphologies of poly(styrene‐b‐4vinylpyridine) (PS‐b‐P4VP) diblock copolymer and homopolystyrene (hPS) binary blend thin films were investigated by atomic force microscopy as a function of total volume fraction of PS (?PS) in the mixture. It was found that when hPS was added into symmetric PS‐b‐P4VP diblock copolymers, the surface morphology of this diblock copolymer was changed to a certain degree. With ?PS increasing at first, hPS was solubilized into the corresponding domains of block copolymer and formed cylinders. Moreover, the more solubilized the hPS, the more cylinders exist. However, when the limit was reached, excessive hPS tended to separate from the domains independently instead of solubilizing into the corresponding domains any longer, that is, a macrophase separation occurred. A model describing transitions of these morphologies with an increase in ?PS is proposed. The effect of composition on the phase morphology of blend films when graphite is used as a substrate is also investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3496–3504, 2004 相似文献
34.
Becky Lavi Abraham Marmur 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,250(1-3):409-414
An equation for the kinetics of partial drop spreading is proposed. This equation was empirically derived from experimental data for the spreading kinetics of partially wetting liquids in terms of the wet area versus time. The equation has the form of an exponential power law (EPL), and transforms into the well-known power law for complete wetting, when the equilibrium contact angle approaches zero. The EPL fits very well available experimental data. To lend additional support to the validity of this generalized equation, it will be demonstrated that when it is transformed to present the dynamic contact angle (DCA), it fits very well DCA experimental data for other wetting processes, such as capillary flow and tape coating. 相似文献
35.
Jayanth R. Banavar Oscar Gonzalez John H. Maddocks Amos Maritan 《Journal of statistical physics》2003,110(1-2):35-50
Physical strands or sheets that can be modelled as curves or surfaces embedded in three dimensions are ubiquitous in nature, and are of fundamental importance in mathematics, physics, biology, and engineering. Often the physical interpretation dictates that self-avoidance should be enforced in the continuum model, i.e., finite energy configurations should not self-intersect. Current continuum models with self-avoidance frequently employ pairwise repulsive potentials, which are of necessity singular. Moreover the potentials do not have an intrinsic length scale appropriate for modelling the finite thickness of the physical systems. Here we develop a framework for modelling self-avoiding strands and sheets which avoids singularities, and which provides a way to introduce a thickness length scale. In our approach pairwise interaction potentials are replaced by many-body potentials involving three or more points, and the radii of certain associated circles or spheres. Self-interaction energies based on these many-body potentials can be used to describe the statistical mechanics of self-interacting strands and sheets of finite thickness. 相似文献
36.
K. S. Birdi 《Colloid and polymer science》1997,275(6):561-566
The surface tension versus temperature data of homologous series of n-alkanes and n-alkenes is analyzed. Critical temperatures are shown to be predicted from these data, with a very high precision, after some
corrections are made. The corrections are shown to arise from the effect of the critical pressure on the extrapolated data
to surface tension approaching zero.
Received: 29 October 1996 Accepted: 13 December 1996 相似文献
37.
A model of two interacting (chemically different) linear polymer chains is solved exactly using the real-space renormalization
group transformation on a family of Sierpinski gasket type fractals and on a truncated 4-simplex lattice. The members of the
family of the Sierpinski gasket-type fractals are characterized by an integer scale factorb which runs from 2 to ∞. The Hausdorff dimensiond
F of these fractals tends to 2 from below asb → ∞. We calculate the contact exponenty for the transition from the State of segregation to a State in which the two chains are entangled forb = 2-5. Using arguments based on the finite-size scaling theory, we show that forb→∞, y = 2 - v(b) d
F, wherev is the end-toend distance exponent of a chain. For a truncated 4-simplex lattice it is shown that the system of two chains
either remains in a State in which these chains are intermingled in such a way that they cannot be told apart, in the sense
that the chemical difference between the polymer chains completely drop out of the thermodynamics of the system, or in a State
in which they are either zipped or entangled. We show the region of existence of these different phases separated by tricritical
lines. The value of the contact exponenty is calculated at the tricritical points. 相似文献
38.
Many recent algorithmic approaches involve the construction of a differential equation model for computational purposes, typically
by introducing an artificial time variable. The actual computational model involves a discretization of the now time-dependent differential system, usually
employing forward Euler. The resulting dynamics of such an algorithm is then a discrete dynamics, and it is expected to be
“close enough” to the dynamics of the continuous system (which is typically easier to analyze) provided that small – hence
many – time steps, or iterations, are taken. Indeed, recent papers in inverse problems and image processing routinely report
results requiring thousands of iterations to converge. This makes one wonder if and how the computational modeling process
can be improved to better reflect the actual properties sought.
In this article we elaborate on several problem instances that illustrate the above observations. Algorithms may often lend
themselves to a dual interpretation, in terms of a simply discretized differential equation with artificial time and in terms
of a simple optimization algorithm; such a dual interpretation can be advantageous. We show how a broader computational modeling
approach may possibly lead to algorithms with improved efficiency.
AMS subject classification (2000) 65L05, 65M32, 65N21, 65N22, 65D18 相似文献
39.
An infinite row of periodically spaced, identical rigid circularcylinders is excited by an acoustic line source which is parallelto the generators of the cylinders. A method for calculatingthe scattered field accurately and efficiently is presented.When the cylinders are sufficiently close together, Rayleigh–Blochsurface waves that propagate energy to infinity along the arrayare excited. An expression is derived which enables the amplitudesof these surface waves to be computed without requiring thesolution to the full scattering problem. 相似文献
40.
Ben-Yuan Gu Yao Lu Tzong-Jer Yang 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):493-502
We present numerical investigations of the transmission properties of electrons in a normal quantum wire tangentially attached
to a superconductor ring threaded by magnetic flux. A point scatterer with a δ -function potential is placed at node to model
scattering effect. We find that the transmission characteristics of electrons in this structure strongly depend on the normal
or superconducting state of the ring. The transmission probability as a function of the energy of incident electrons, in the
case of a superconductor ring threaded by one quantum magnetic flux, emerges one deep dip, imposed upon the first broad bump
in spectrum. This intrinsic conductance dip originates from the superconductor state of the ring. When increasing the magnetic
flux from one quantum magnetic flux to two, the spectrum shifts toward higher energy region in the whole. This conductance
dip accordingly shifts and appears in the second bump. In the presence of a point-scatterer at the node, the spectrum is substantially
modified. Based on the condition of the formation of the standing wave functions in the ring and the broken of the time-reserve
symmetry of Schr?dinger equation after switching magnetic flux, the characteristics of transmission of electrons in this structure
can be well understood.
Received 6 November 2001 相似文献