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61.
Teruhiko Kai Yasunori Suma Shuichiro Ono Takeo Yamaguchi Shin‐ichi Nakao 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):846-856
We have investigated the effect of the surface state and surface treatment of the pores of an inorganic substrate on the plasma‐grafting behavior of pore‐filling‐type organic/inorganic composite membranes. Shirasu porous glass (SPG) was used as the inorganic substrate, and methyl acrylate was used as the grafting monomer. The grafting rate increased as the density of silanol on the SPG substrate increased. This result suggests that radicals are generated mainly at the silanol groups on the pore surface by plasma irradiation. The SPG substrates were treated with silane coupling agents used to control the mass of organic material bonded to the pore surface. The thickness of the grafted layer became thinner as the mass of organic material bonded to the pore surface of SPG increased. This decrease in the thickness of the grafted layer could be explained by the decrease in the penetration depth of vacuum ultraviolet rays contained in plasma having a wavelength of less than 160 nm that generated radicals in the pores of the substrate. The thickness of the grafted layer inside the SPG substrates could be controlled through the control of the mass of organic material bonded to the pore surface of the SPG substrate. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 846–856, 2006 相似文献
62.
Zhe Wang Hongzhe Ni Chengji Zhao Xianfeng Li Tiezhu Fu Hui Na 《Journal of Polymer Science.Polymer Physics》2006,44(14):1967-1978
The sulfonated poly(ether ether ketone sulfone) (SPEEKS)/heteropolyacid (HPA) composite membranes with different HPA content in SPEEKS copolymers matrix with different degree of sulfonation (DS) were investigated for high temperature proton exchange membrane fuel cells. Composite membranes were characterized by Fourier transfer infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). FTIR band shifts suggested that the sulfonic acid groups on the copolymer backbone strongly interact with HPA particles. SEM pictures showed that the HPA particles were uniformly distributed throughout the SPEEKS membranes matrix and particle sizes decreased with the increment of copolymers' DS. The holes were not found in SPEEKS‐4/HPA30 (consisting of 70% SPEEKS copolymers with DS = 0.8 and 30% HPA) composite membrane after composite membranes were treated with boiling water for 24 h. Thermal stabilities of the composite membranes were better than those of pure sulfonated copolymers membranes. Although the composite membranes possessed lower water uptake, it exhibited higher proton conductivity for SPEEKS‐4/HPA30 especially at high temperature (above 100 °C). Its proton conductivity linearly increased from 0.068 S/cm at 25 °C to 0.095 S/cm at 120 °C, which was higher than 0.06 S/cm of Nafion 117. In contrast, proton conductivity of pure SPEEKS‐4 membrane only increased from 0.062 S/cm at 25 °C to 0.078 S/cm at 80 °C. At 120 °C, proton conductivity decreased to poor 0.073 S/cm. The result indicated that composite membranes exhibited high proton conductivity at high temperature. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1967–1978, 2006 相似文献
63.
模糊神经网络在复合地基沉降量预测中的应用 总被引:1,自引:0,他引:1
复合地基后期沉降变形对于建筑物设计及安全具有重要意义,针对通过长期沉降观测以得到复合地基的最终沉降需要耗费较多资源的问题,提出了一种基于模糊神经网络的预测方法.该方法考虑沉降变化过程有较大的随机性和模糊性,直接将样本数据进行模糊化,所得的模糊数代表了样本点集与控制点集中各分量之间的相关度,并依此建立模糊BP神经网络进行学习和估算.实验结果表明了该方法对沉降进行预测是可行与有效的,且在相对误差的有效控制方面优于BP网络方法与灰色方法. 相似文献
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66.
LaB6-ZrB2共晶复合材料的组织特征及控制 总被引:2,自引:0,他引:2
用电弧炉和电子束悬浮区熔炉法制备了LaB6ZrB2共晶复合材料,并用SEM和TEM方法对其显微组织进行了研究。结果表明,LaB6ZrB2形成纤维状共晶组织,控制凝固条件可得到定向排列的组织,LaB6基体上均匀分布着直径为02~12μm的ZrB2纤维,纤维长度可达100μm以上。对于固液界面为平面生长的试样,其结晶学取向关系为[001]LaB6∥[001]ZrB2,(110)LaB6∥(010)ZrB2。 相似文献
67.
68.
酯交换法合成碳酸二苯酯用氧化铅-氧化锌催化剂的研究 总被引:15,自引:0,他引:15
制备了一种用于苯酚与碳酸二甲酯酯交换合成碳酸二苯酯的新型氧化铅-氧化锌多相催化剂.研究了制备方法、焙烧温度、不同母体和母体配比对催化剂催化性能的影响.应用XRD,TPR和原子吸收光谱对催化剂结构进行了表征,发现Pb3O4是主活性物相,ZnO为助催化剂,并以非晶态或微晶态存在于催化剂体系中.当焙烧温度为500℃,n(Pb)/n(Zn)≈2时,催化剂的活性最高,碳酸二苯酯产率可达45.6%.考察了催化剂的重复使用效果,并对失活原因进行了探讨. 相似文献
69.
Recently, low dimension nanostructures have gained considerable attention due to their technological potential as unique types of nanoscale building blocks for future optoelectronic devices and systems. Semiconducting composite nanomaterials, which can combine the advantages of two or more components, have been the focus in the area of nanomaterials synthesis and device application.In this paper, we report our work on the preparation of composite nanomaterials based on CNTs.CNTs were coated by organic or inorganic species via novel and facile methods (Fig. 1 and Fig.2).These functional CNTs based composites show eminent prospects and opportunities for new applications in a wide variation of areas. 相似文献
70.
P. Etienne J. Denape J. Y. Paris J. Phalippou R. Sempere 《Journal of Sol-Gel Science and Technology》1996,6(3):287-297
Transparent plastics are not scratch resistant. The damage leads to a loss of optical properties. Coatings prepared using either tetraethoxysilane or colloidal silica particles embedded in glymo is a way to avoid these disadvantages. Tribological experiments are carried out to better understand the surface modification due to a sliding friction. It is shown that the wear track is not directly related to usual mechanical properties such as Young's modulus and the hardness of the coating. The different stages leading to material loss are discussed in term of particle removal and debris circulation (accumulation or elimination) through the friction track. The mechanical properties of the film combined with the film to substrate adhesion are expected to play an important role as it can be deduced from results obtained as a function of the coating composition. 相似文献