基于故障树的城市雾霾天气模糊综合评判

以某市雾霾天气为例,找出导致该市雾霾发生的原因并建立相关的故障树,通过分析得出导致该市发生雾霾的主要原因为气象和人为原因.然后利用模糊综合评判法,对该市雾霾污染程度进行了量化评判,得出该市雾霾污染程度为重度污染,便于该市相关部门做好防范措施.结果表明,利用故障树分析法和模糊综合评判法对雾霾天气进行分析是可行的,为其他雾霾城市分析提供了参考依据.     

随机变量函数概率密度的定点算法

利用曲线积分和曲面积分作为工具,导出计算随机变量函数的密度函数的一种定点算法,并借助实例说明相应计算公式的应用.     

Evaluation of the 1077 keV γ-ray emission probability from 6SGa decay

6SGa decays to the excited states of aSzn through the electron capture decay mode. New recommended values for the emission probability of 1077 keV γ-ray given by the ENSDF and DDEP databases all use data from absolute measurements. In 2011, JIANG Li-Yang deduced a new value for 1077 keV γ-ray emission probability by measuring the 69Ga（n,2n） 6SGa reaction cross section. The new value is about 20% lower than values obtained from previous absolute measurements and evaluations. In this paper, the discrepancies among the measurements and evaluations are analyzed carefully and the new values are re-recommended. Our recommended value for the emission probability of 1077 keV γ-ray is （2.72±0.16）%.     

真彩色传递双波段图像融合

针对基于颜色传递的双波段（中波红外、可见光）图像融合时,由于参考图像选择不当,造成的彩色融合图像对比度差、图像边缘细节下降等问题,提出了基于拉普拉斯金字塔分解及对比度可调的色彩传递图像融合算法。对待融合的两幅图像进行拉普拉斯金字塔三级分解,每一级按照不同的融合规则进行融合,以重构后的灰度融合图像作为融合结构的亮度分量Y,将可见光与红外图像的差值图像作为U分量,以红外图像为V分量。在颜色传递公式中,加入可调的比例系数,通过适当调节比例系数可调节融合图像的对比度。实验结果表明,获得的融合图像较好地保留了可见光图像的细节,既突出了红外目标同时又具有参考图像的颜色特征。图像评价结果表明,融合图像的均值、方差、熵等评价指标均得到较大提高。     

Removal of Cr(VI) from aqueous solutions using EDCC-MCM-41: Isotherm,kinetics and thermodynamic evaluation

Abstract

EDCC-MCM-41, a novel ethylenediamine derivative of MCM-41 was synthesized from a sugar industry waste, bagasse fly ash. Studies were carried out on its ability to remove Cr(VI) from aqueous solution. Its performance was also compared with that of unmodified MCM-41 and an already known derivative NH₂-MCM-41 (both also synthesized from bagasse fly ash) at the same experimental conditions. Results show that the novel adsorbent produced a better sorption performance (adsorption capacity of 49.04?mg g^?1) than MCM-41 and NH₂-MCM-41 which produced adsorption capacities of 13.78?mg g^?1 and 25.29?mg g^?1 respectively. Thermodynamics, kinetics and isotherm studies confirm that the sorption process involving the novel adsorbent is favorable for Cr(VI) and can best be represented by pseudo-second-order kinetics model. The sorption process was also found to be multistep, involving both film diffusion and intraparticle diffusion into the pores on the adsorbent’s surface.

Abbreviations: BFA: Bagasse Fly Ash; MCM-41: Mobil Composition of matter no. 41; NH2-MCM-41: mine functionalized MCM-41; EDCC-MCM-41: Ethylenediamine grafted MCM-41; qe: Mass of material adsorbed at equilibrium per mass of adsorbent; qt: Mass of material adsorbed at any time t per mass of adsorbent; C0: The initial concentration; Ce: The residual concentration at equilibrium; Ct: Residual concentration at any time t; W: The weight of adsorbents; rRMSD: Root mean square deviation; R: Gas constant     

Synthesis and Antimicrobial Evaluation of Some New Thiophene Derivatives

2-(2-Cyano-acetylamino)-4,5,6,7-tetrahydro-benzo[b]thiophene-3-carboxamide(3) was used as starting material for synthesis of 4-thiazolidinone, thiazolidine, and thiophene derivatives 6, 7a, b, and 8a, b, respectively. Thiocarbomyl derivative 5, 4-thizolidinone 9, and thioxothiazolidine 10 were obtained from reaction of 3 with thioglycolic acid and phenyl isothiocyanate/sulfur, respectively. Condensation of 3 with selected cyclic ketones and aromatic aldehydes yielded the arylidine derivatives 11a, b and 13, respectively. Refluxing of 11a, b with sulfur and morpholine yielded the thiophene derivatives 12a, b, respectively. Diazocoupling of compound 3 withp-tolyl diazonium chloride yielded the hydrazone derivative 14. The newly synthesized compounds were characterized by infrared, ¹H NMR, and mass spectral studies. Representative compounds of the synthesized product were tested and evaluated as antimicrobial agents. Compound 12b gives very high antimicrobial activity against Ampicillin.     

高效液相色谱仪自动进样器校准方法及不确定度评定

建立高效液相色谱仪自动进样器的校准方法,并对其测量不确定度进行评定。参考欧洲医药管理局《质量控制文件》提供的方法对液相色谱仪自动进样器的进样体积误差、进样残留和进样重复性建立校准方法,经评定得进样体积误差的相对扩展不确定度为1.8%。高效液相色谱仪自动进样器校准方法及不确定度评定方法的建立,为高效液相色谱仪自动进样器的校准提供依据。     

VT-NMR and cytotoxic evaluation of some new ortho-(alkylchalcogen)acetanilides

Several novel atropisomeric N-alkyl-N-[(2-alkylchalcogen)phenyl)]acetamides have been synthesized and fully characterized by ¹H and ¹³C NMR, FTIR, and HRMS (FAB). The barriers of the restricted rotation about the N-aryl bond between the two atropisomeric forms were measured by accurate lineshape simulation of variable temperature NMR (VT-NMR) spectra obtained in DMSO-d₆ solution and ranged from 17.0 to 20.5 kcal/mol. The relationship between the structure of the different acetanilide moieties and both coalescence temperature and energy of rotation are herein discussed. Taking in mind the acetamide structural resemblances with nimesulide related compounds known by their anticancer activity, the in vitro cytotoxicity of 20 representative acetanilides, against human breast (MCF-7) and prostate (LNCaP) cancer cell lines as well as normal human dermal fibroblasts (NHDF) was also preliminary evaluated. Interestingly a selective antiproliferative activity was observed for cancerous cells with prominence to LNCaP within the most potent O- and/or N-benzylic and -hexyl acetanilides.     

化学计量中不确定度评定研究进展

测量不确定度是表征合理地赋予被测量之值的分散性的参数。本文针对化学计量不确定度评定基础模型仅适用于线性模型、概率分布为正态分布或缩放位移t分布等局限,介绍了近年来不确定度评定的研究热点:蒙特卡罗方法(Monte Carlo Method,MCM),不确定度评定的来源、评定概念、评估方法及其发展过程,扩大了测量不确定度评定与表示的适用范围。     

Age-based Markovian approximation of the G/M/1 queue

We extend the approach of Koole et al. (2012) [15] and Legros et al. (2018) [20] for the G/M/1 queue. The idea is to provide a Markovian approximation where a state represents the oldest customer's wait. This modeling is made possible by creating states with negative wait, representing an estimate of the time at which a new customer would arrive when the system is empty. We apply this method for performance evaluation and routing optimization. Finally, we further extend the model to the G/M/1+G queue.