高结晶性小分子给体材料应用于全小分子有机太阳能电池中的研究进展

随着新型小分子给体材料和非富勒烯小分子受体材料的开发和应用, 非富勒烯全小分子有机太阳能电池(NF-ASM OSCs)的光电转换效率已经突破15%, 并逐渐接近聚合物太阳能电池的效率. 相比于聚合物电子给体材料, 小分子电子给体材料拥有其独特的优势, 例如合成批次性差异小、分子量明确和易于提纯等; 但是, 对小分子给体材料的结晶性难于精确调控, 使获得合适的纳米级结构的混合膜仍然是一个挑战. 本综述以给体小分子中心共轭单元的扩展为主线, 从分子设计的角度汇总了近年来对苯并二噻吩、萘并二噻吩和二噻并苯并二噻吩类小分子给体材料的结晶性研究, 并为进一步改善电池活性层形貌和获得更高的光伏性能提供了未来发展的建议.     

广义中心α-Armendariz环

本文引入广义中心α-Armendariz环的概念,得到了广义中心α-Armendariz环的基本性质,研究了广义中心α-Armendariz环与其他环之间的一些关系.     

集束光水下图像系统

报道了一种新型的适用于浑水条件下的集束光水下图像系统.分析了目前水下观察采用的两种技术—同步扫描技术和距离选通技术,介绍了该水下图像系统的构成原理以及系统组成.通过水池实验,验证了系统的有效性.给出了集束光水下图像系统与水下激光图像系统在探测距离及其它性能方面的比较结果.该系统有望在海洋工程及军事上得到广泛应用.     

Simultaneous determination of haloanisoles and halophenols in water using in situ acylation combined with solid‐phase microextraction with gas chromatography and mass spectrometry

In this work, an in situ acylation combined with solid‐phase microextraction coupled to gas chromatography and mass spectrometry method has been developed for simultaneously determining haloanisoles (2,4,6‐trichloranisole, 2,4,6‐tribromoanisole), and their direct precursors (2,4,6‐trichlorophenol, 2,4,6‐tribromophenol) and indirect precursors (2‐chloropenol, 2,4‐dichlorophenol, 2‐bromophenol, 2,4‐dibromophenol) in water. The key parameters for the solid‐phase microextraction were determined by using Plackett–Burman screening and optimized by central composite optimization. Under optimal conditions, the eight compounds can be analyzed in a short time (33 min) with a strong linearity ranging from 2 to 200 ng/L (correlation coefficient greater than 0.996), showing good sensitivities with the limit of detection in a range of 0.23–0.91 ng/L and a limit of quantification of 0.77–3.03 ng/L, good repeatability (2.00–9.10%) and interday precision (1.67–11.3%). When environmental water samples were treated, the recoveries of target compounds were 75.5–127.3%, suggesting that the developed method could be applied in probing the origin of haloanisoles and monitoring halophenols and haloanisoles in natural waters at concentration levels of ng/L.     

Semi‐analytical description of the S = 9/2 quadrupole nutation NMR experiment: multinuclear application to 113In and 115In in indium phosphide

The density matrix of a spin S = 9/2 excited by a radiofrequency pulse is calculated. The interaction involved during the excitation of the spin system is first‐order quadrupolar. Consequently, the results are valid for any ratio of the quadrupolar coupling ω_Q to the pulse amplitude ω₁. The behavior of the central transition intensities versus the pulse length is discussed. The ¹¹⁵In and ¹¹³In nuclei in a powdered sample of indium phosphide (InP) are used to illustrate the results. It is found that the ratio of the quadrupolar coupling constants determined in this work is in excellent agreement with the ratio of the quadrupole moments of the two nuclei. Copyright © 2015 John Wiley & Sons, Ltd.     

Hybridization: A Chemical Bonding Nature of Atoms

Both the bonding mode and geometry can serve as the chemical bonding nature of central cation, which is essentially determined by the atomic orbital‐hybridization. In this work, we focus on the possible chemical bonding scheme of central cations on the basis of a quantitative analysis of electron domain of an atom. Starting from the hybridization of outer atomic orbitals that are occupied by valence electrons, we studied the possible orbital hybridization scheme of atoms in the periodic table and the corresponding coordination number as well as possible molecular geometries. According to distinct hybrid orbital sets, the chemical bonding of central cations can be classified into three typical types, resulting in the cations with a variety of coordination numbers ranging from 2 to 16. Owing to different hybridization modes, the highest coordination number of cations in IA and IIA groups is larger than that in IB‐VIIIB groups, and the coordination number of lanthanide elements is most abundant. We also selected NaNO₃ , Fe(NO₃ )₃•9H₂O , Zn(NO₃ )₂•6H₂O , Y(NO₃ )₃•3H₂O , and La(NO₃ )₃•6H₂O as examples to confirm the direct relationship between chemical bonding characteristics and orbital hybrid set by IR spectra. The present study opens the door to reveal the chemical bonding nature of atoms on the basis of hybridization and will provide theoretical guides in structural design at an atomic level.     

超特殊Z-群的自同构群

确定了超特殊Z-群的自同构群.设G是超特殊Z-群,即G={(1 α_1 α_2···α_n α_(n+1) 0 1 0···0 α_(n+2) ···0 0 0 ··· 0 α_2n 0 0 0··· 1 α_(2n+1) 0 0 0···1 α_(2n+1) 0 0 0···0 1)|α_j∈Z,j=1,2,3,...,2n+1}Aut_cG是AutG中平凡作用在ζG上的自同构形成的正规子群,则AutG=Aut_cG×Z_2,且1→Z···Z}2N→Aut_cG→Sp(2n,Z)→1是正合列.     

Sections of the regular simplex – Volume formulas and estimates

We state a general formula to compute the volume of the intersection of the regular n‐simplex with some k‐dimensional subspace. It is known that for central hyperplanes the one through the centroid containing vertices gives the maximal volume. We show that, for fixed small distances of a hyperplane to the centroid, the hyperplane containing vertices is still volume maximizing. The proof also yields a new and short argument for the result on central sections. With the same technique we give a partial result for the minimal central hyperplane section. Finally, we obtain a bound for k‐dimensional sections.