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91.
Yingchao Liu Jinsong Wu Sixiu Liu Dongxiao Zhuang Yongfei Wang Xuefei Shou Jianhong Zhu 《Colloids and surfaces. B, Biointerfaces》2009,71(2):187-193
Laser capture microdissection (LCM) technology combined with immunohistochemistry (immuno-LCM) is a valuable tool to obtain specific target cell populations and therefore this technique enables more accurate proteomic profile. In this study, we optimized the regular immuno-LCM technique to isolate and stain pure prolactin cells from either normal human pituitary (n = 6) or prolactioma (n = 11). Compared with the routine procedure, more intense and specific staining could be obtained when sections were pretreated with 0.2% Triton X-100 for 4 min. Interestingly, longer pretreatment (0.2% Triton X-100 for 10 min) or higher concentration (2% Triton X-100 for 4 and 10 min) greatly impaired labeling intensity and cell shape. Further scanning electron microscope study revealed that the component extracted from the cell surface by Triton X-100 was lipid. Using the optimized immuno-LCM technique, more pure prolactin cells could be isolated and prepared for further proteomic analysis. Taken together, we reported an optimized immuno-LCM technique that could effectively dissect pure target cells in different type pituitary adenomas for further proteomics analysis. 相似文献
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针对单测量向量模型(Single Measurement Vector,SMV)等传统压缩感知方法处理超声全矩阵数据时,存在重构精度低和重构耗时长等问题,本文研究了多测量向量模型(Multiple Measurement Vectors,MMV)应用的可行性。针对铝合金试块中不同深度的φ2 mm横通孔,分别使用MMV模型中的多测量稀疏贝叶斯(Multiple Sparse Bayesian Learning,MSBL)算法和SMV模型中的稀疏贝叶斯(Sparse Bayesian Learning,SBL)算法进行超声全矩阵数据重构,并实施全聚焦成像。随后,引入归一化均方误差和阵列性能因子评价图像和信号的重构效果。实验结果表明,SBL算法在25%采样率时的归一化均方误差为1.9%,而MSBL算法仅需15%采样率即可达到相似效果且耗时更少。 相似文献
96.
现有在轨服务的对接机构由于其尺寸大、结构复杂、对接目标单一等局限性因素,无法很好地为后续我国探月工程任务提供有力支撑,且受限于运载能力,对接机构的轻量化也是必不可少的一项环节.为研究可服务于未来月球空间站以及载人登月等高轨道任务的对接机构,设计了一种新型抱爪式对接机构,其采用异体同构周边式构型,可以实现主/被动飞行器之间的互换.利用 V 型槽与爪钩等结构部件实现飞行器对接过程中的捕获以 及能量消耗功能,从而实现两飞行器之间的稳固联接.该对接机构具备尺寸小、重量轻、结构简单、功能易实现等优势. 对其捕获缓冲系统进行了动力学分析,计算了缓冲元器件的参数对其捕获性能的影响,在 ADAMS 完成了数字虚拟样机的建立,结合实际两种典型的对接初始条件工况进行了仿真研究.研究结果表明,两种工况下的对接过程能量消耗满足设计要求,能够以较小的 V 型槽的碰撞力完成捕获,结果证明了捕获缓冲系统的可行性以及该构型对接机构具备较好实现任务的能力. 相似文献
97.
Gaetan?KerschenEmail author Alexander?F.?Vakakis Young?S.?Lee D.?Michael?Mcfarland Jeffrey?J.?Kowtko Lawrence?A.?Bergman 《Nonlinear dynamics》2005,42(3):283-303
The purpose of this study is to highlight and explain the vigorous energy transfers that may take place in a linear oscillator
weakly coupled to an essentially nonlinear attachment, termed a nonlinear energy sink. Although these energy exchanges are
encountered during the transient dynamics of the damped system, it is shown that the dynamics can be interpreted mainly in
terms of the periodic orbits of the underlying Hamiltonian system. To this end, a frequency-energy plot gathering the periodic
orbits of the system is constructed which demonstrates that, thanks to a 1:1 resonance capture, energy can be irreversibly
and almost completely transferred from the linear oscillator to the nonlinear attachment. Furthermore, it is observed that
this nonlinear energy pumping is triggered by the excitation of transient bridging orbits compatible with the nonlinear attachment being initially at rest, a common feature in most practical applications. A parametric
study of the energy exchanges is also performed to understand the influence of the parameters of the nonlinear energy sink.
Finally, the results of experimental measurements supporting the theoretical developments are discussed.
This study was carried out while the author was a postdoctoral fellow at the National Technical University of Athens and at
the University of Illinois at Urbana-Champaign. 相似文献
98.
Clicked Isoreticular Metal–Organic Frameworks and Their High Performance in the Selective Capture and Separation of Large Organic Molecules
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Chung Yen Ang Hongzhong Chen Dr. Jia Liu Prof. Dr. Ruqiang Zou Prof. Dr. Yanli Zhao 《Angewandte Chemie (International ed. in English)》2015,54(43):12748-12752
Three highly porous metal–organic frameworks (MOFs) with a uniform rht‐type topological network but hierarchical pores were successfully constructed by the assembly of triazole‐containing dendritic hexacarboxylate ligands with ZnII ions. These transparent MOF crystals present gradually increasing pore sizes upon extension of the length of the organic backbone, as clearly identified by structural analysis and gas‐adsorption experiments. The inherent accessibility of the pores to large molecules endows these materials with unique properties for the uptake of large guest molecules. The visible selective adsorption of dye molecules makes these MOFs highly promising porous materials for pore‐size‐dependent large‐molecule capture and separation. 相似文献
99.
Dr. Satesh Gangarapu Dr. Antonius T. M. Marcelis Dr. Yahia A. Alhamed Prof. Dr. Han Zuilhof 《Chemphyschem》2015,16(14):3000-3006
Quantum chemical studies are used to understand the electronic and steric effects on the mechanisms of the reaction of substituted ethanolamines with CO2. SCS‐MP2/6‐311+G(2d,2p) calculations are used to obtain the activation energy barriers and reaction energies for both the carbamate and bicarbonate formation. Implicit solvent effects are included with the universal solvation model SMD. Carbamate formation is more favorable than bicarbonate formation for monoethanolamine (MEA) both kinetically and thermodynamically. Increase of the steric hindrance on the C atoms around the N atom in substituted ethanolamines favors bicarbonate formation over carbamate formation with lower activation barriers and thereby higher reaction rates. In contrast, substitution by an N‐methyl or N‐ethyl group on MEA leads to a lower activation barrier for both carbamate formation and bicarbonate formation. As a result, higher reaction rates are expected as compared to MEA, and therefore these compounds have significant potential as industrial CO2 capturing solvents. 相似文献
100.
Dr. Guang‐Ping Hao Giovanni Mondin Dr. Zhikun Zheng Tim Biemelt Stefan Klosz René Schubel Prof. Alexander Eychmüller Prof. Stefan Kaskel 《Angewandte Chemie (International ed. in English)》2015,54(6):1941-1945
There is significant interest in high‐performance materials that can directly and efficiently capture water vapor, particularly from air. Herein, we report a class of novel porous carbon cuboids with unusual ultra‐hydrophilic properties, over which the synergistic effects between surface heterogeneity and micropore architecture is maximized, leading to the best atmospheric water‐capture performance among porous carbons to date, with a water capacity of up to 9.82 mmol g?1 at P/P0=0.2 and 25 °C (20 % relative humidity or 6000 ppm). Benefiting from properties, such as defined morphology, narrow pore size distribution, and high heterogeneity, this series of functional carbons may serve as model materials for fundamental research on carbon chemistry and the advance of new types of materials for water‐vapor capture as well as other applications requiring combined highly hydrophilic surface chemistry, developed hierarchical porosity, and excellent stability. 相似文献