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71.
Multiple ionization of argon accompanied by electron loss and capture of 0.22-6.35 MeV C^q+ ions
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In this paper a projectile ions recoil ions coincidence technique is employed to investigate the target ionization and projectile charge state changing processes in the collision of 0.22-6.35 MeV Cq^+ (q = 1 - 4) ions with argon atoms. The partial cross section ratios of the double, triple, quadruplicate ionization to the single ionization (or the single capture) of argon associated with single electron loss (or single electron capture) by the projectile are measured and compared with the previous experimental results. In the present experiment, it is observed that the ratios of ionization cross sections R associated with single loss and single capture depend strongly on the projectile charge state and vary significantly with different reaction channels as impact energy increases. In addition, this paper gets empirical scaling laws for the ionization cross section ratios R corresponding to the projectile single loss and finds that the ratios of the double ionization to the single ionization associated with single electron capture remain constant in the present energy range. 相似文献
72.
A.L. Barabanov 《The European Physical Journal A - Hadrons and Nuclei》1999,6(4):373-374
It is shown that new spin-orbit-like terms appear in the effective nonrelativistic weak Hamiltonian for nucleon provided
that nuclear potential is taken into account. Arguments for their considerable enhancement, in particular, in relativistic
nuclear model of Walecka are advanced.
Received: 29 July 1999 相似文献
73.
Sukhendusekhar Sarkar 《Pramana》1999,53(3):469-472
We examine the possible role of electron-capture on the thermally populated first 2+ excited state of 44Ti in hot astrophysical environments pertaining to post explosive nucleosynthesis supernova debris. We find in a simple schematic
model that the astrophysical weak interaction rate for electron-capture decay of 44Ti can depend considerably on temperature and hence on time. We propose a time varying decay rate for the evolving supernova
debris and demonstrate its consequence for the 44Ti mass yield of the supernova Cas A, observed through the measured 1.157 MeV γ-ray flux from the electron-capture decay of
44Ti. 相似文献
74.
D. Dane Quinn 《Nonlinear dynamics》2009,57(4):623-633
The response of a nonlinear, damped Jeffcott rotor with anisotropic stiffness is considered in the presence of an imbalance.
For sufficiently small external torque or large imbalance, resonance capture or rotordynamic stall can occur, whereby the
rotational velocity of the shaft is unable to increase beyond the fundamental resonance between the rotational and translational
motion. This phenomena provides a mechanism for energy transfer from the rotational to the translational mode. Using the method
of averaging a reduced-order model is developed, valid near the resonance, that describes this resonant behavior. The equilibrium
points of these averaged equations, which correspond to stationary solutions of the original equations and rotordynamic stall,
are described as the applied torque, damping, and anisotropy vary. As the anisotropy increases, assumed to arise from increasing
shaft cracks, the torque required to eliminate the possibility of stall increases. However, when the system is started with
zero initial conditions, the minimum torque required to pass through the resonance is approximately constant as the anisotropy
increases. The predictions from the reduced-order model are verified against numerical simulations of the original equations
of motion. 相似文献
75.
恒星能量下俘获截面非常难于直接测量.因此,通常借助于非直接方法或从最低能量下的实验数据外推到天体物理感兴趣能区.首先证明了用渐近归一化常数方法得到的结果近似与模型无关.因此,转移反应的渐近归一化常数方法处理提供了一可靠的途径用以确定恒星能量下的俘获截面. 鉴于此优点, 用渐近归一化常数方法计算了10Be(n,γ)11Be反应的俘获截面. 11Be是一个众所周知的具有两弱束缚态的晕核.作为一个典型的例子,演示了俘获到晕态的辐射俘获截面明显增大, 证明了入射中子波函数与晕的伸展尾部有较大重叠是俘获截面异常增大的原因. 相似文献
76.
建立了柱前衍生-气相色谱-电子捕获(GC-ECD)法同时测定水中PFBA、PFPeA、PFHxA、PFHpA,PFOA,PFNA,PFDA,PFUnA及PFDoA等(全称见正文)9种全氟羧酸(Perfluorinated carboxylic acids,PFCAs).使用2,4-二氟苯胺(2,4-Difluoroaniline,2,4-DFA)为衍生剂,N,N'-二环己基碳二亚胺(N,N'-Dicy-clohexylcarbodiimide,DCC)为脱水剂,与PFCAs形成酰胺衍生产物,衍生产物通过TR-5毛细管色谱柱分离,并以ECD检测器进行检测.对全氟羧酸衍生化过程中2,4-DFA和DCC用量、衍生反应溶剂、反应温度、反应时间等条件进行了优化,得出最佳衍生化条件.结果表明,在最优实验条件下,9种PFCAs衍生产物的线性相关系数>0.99,检出限为0.62~ 1.38 μg/L,相对标准偏差RSD为1.3%~7.5%.应用本方法对城市污水中全氟类羧酸进行了分析,城市污水中存在以PFPeA、PFHpA和PFOA为主的痕量PFCAs化合物,实际样品的加标回收率在84.4% ~ 120.9%之间.本方法稳定、可靠、成本低,能够满足水样中多种全氟羧酸的同时检测的要求,可为水体中全氟化合物的污染评价提供技术支持. 相似文献
77.
Experimental study of non-linear energy pumping occurring at a single fast frequency 总被引:3,自引:0,他引:3
D. Michael McFarland 《International Journal of Non》2005,40(6):891-899
Experimental verification of passive non-linear energy pumping in a two-degree-of-freedom system comprising a damped linear oscillator coupled to an essentially non-linear attachment is carried out. In the experiments presented the non-linear attachment interacts with a single linear mode and, hence, energy pumping occurs at a single ‘fast’ frequency in the neighborhood of the eigenfrequency of the linear mode. Good agreement between simulated and experimental results was observed, in spite of the strongly (essentially) non-linear and transient nature of the dynamics of the system considered. The experiments bear out earlier predictions that a significant fraction of the energy introduced directly to a linear structure by an external impulsive (broadband) load can be transferred (pumped) to an essentially non-linear attachment, and dissipated there locally without spreading back to the system. In addition, the reported experimental results confirm that (a) non-linear energy pumping in systems of coupled oscillators can occur only above a certain threshold of the input energy, and (b) there is an optimal value of the energy input at which a maximum portion of the energy is absorbed and dissipated at the NES. 相似文献
78.
Elisa Barea Dr. Giulia Tagliabue Wen‐Guo Wang Dr. Manuel Pérez‐Mendoza Dr. Laura Mendez‐Liñan Francisco J. López‐Garzon Prof. Simona Galli Dr. Norberto Masciocchi Prof. Jorge A. R. Navarro Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(3):931-937
The novel coordination polymers [Cu(Hoxonic)(H2O)]n ( 1 ) and [Cu(Hoxonic)(bpy)0.5]n ? 1.5 n H2O ( 2?H2O ) (H3oxonic: 4,6‐dihydroxy‐1,3,5‐triazine‐2‐carboxylic acid; bpy: 4,4′‐bipyridine) have been isolated and structurally characterised by ab initio X‐ray powder diffraction. The dense phase 1 contains 1D zig‐zag chains in which Hoxonic dianions bridge square‐pyramidal copper(II) ions, apically coordinated by water molecules. On the contrary, 2?H2O , prepared by solution and solventless methods, is based on 2D layers of octahedral copper(II) ions bridged by Hoxonic ligands, further pillared by bpy spacers. The resulting pro‐porous 3D network possesses small hydrated cavities. The reactivity, thermal, magnetic and adsorptive properties of these materials have been investigated. Notably, the adsorption studies on 2 show that this material possesses unusual adsorption behaviour. Indeed, guest uptake is facilitated by increasing the thermal energy of both the guest and the framework. Thus, neither N2 at 77 K nor CO2 at 195 K are incorporated, and CH4 is only minimally adsorbed at 273 K and high pressures (0.5 mmol g?1 at 2500 kPa). By contrast, CO2 is readily incorporated at 273 K (up to 2.5 mmol g?1 at 2500 kPa). The selectivity of 2 towards CO2 over CH4 has been investigated by means of variable‐temperature zero coverage adsorption experiments and measurement of breakthrough curves of CO2/CH4 mixtures. The results show the highly selective incorporation of CO2 in 2 , which can be rationalised on the basis of the framework flexibility and polar nature of its voids. 相似文献
79.
An in-syringe ultrasound-assisted emulsification microextraction (USAEME) was developed for the extraction of organophosphorus pesticides (OPPs) from water samples. The OPPs subsequently analyzed gas chromatography (GC) using a microelectron capture detector (μECD). Ultrasound radiation was applied to accelerate the emulsification of μL-level low-density organic solvent in aqueous solutions to enhance the microextraction efficiency of OPPs in the sample preparation for GC-μECD. Parameters affecting the efficiency of USAEME, such as the extraction solvent, solvent volume, pH, salt-addition, and extraction time were thoroughly investigated. Based on experimental results, OPPs were extracted from a 5 mL aqueous sample by the addition of 20 μL toluene as the extraction solvent, followed by ultrasonication for 30 s, and then centrifugation for 3 min at 3200 rpm, offered the best extraction efficiency. Detections were linear in the concentration of 0.01–1 μg/L with detection limits between 1 ng/L and 2 ng/L for OPPs. Enrichment factors ranged from 330 to 699. Three spiked aqueous samples were analyzed, and recovery ranged from 90.1% to 104.7% for farm-field water, and 90.1% to 101.8% for industrial wastewater. The proposed method provides a simple, rapid, sensitive, inexpensive, and eco-friendly process for determining OPPs in water samples. 相似文献
80.
Bharat V. Bhut Kenneth A. Christensen Scott M. Husson 《Journal of chromatography. A》2010,1217(30):4946-4957
This contribution describes the purification of anthrax protective antigen (PA) protein from Escherichia coli lysate using bind-and-elute chromatography with newly designed weak anion-exchange membranes. Protein separation performance of the new AEX membrane adsorber was compared with the commercial Sartobind® D membrane adsorber and HiTrap™ DEAE FF resin column under preparative scale conditions. Dynamic protein binding capacities of all three stationary phases were determined using breakthrough curve analysis. The AEX membrane showed higher binding capacities than the Sartobind® D membrane at equivalent volumetric throughput and higher capacities than the HiTrap™ DEAE FF resin column at 15 times higher volumetric throughput. Anion-exchange chromatography was performed using all three stationary phases to purify PA protein. Quantitative SDS-PAGE analysis of effluent fractions showed that the purity of PA protein was higher for membrane adsorbers than the HiTrap™ DEAE FF resin column and was the same for the new AEX membrane and Sartobind® D membrane adsorbers. The effects of E. coli lysate load volume and volumetric flow rate on PA protein separation resolution using the membrane adsorbers were minor, and the peak elution profile remained un-changed even under conditions where >75% of the total protein dynamic binding capacity of the membranes had been utilized. PA protein peak resolution was higher using pH-gradient elution than with ionic strength gradient elution. Overall, the results clearly demonstrate that membrane chromatography is a high-capacity, high-throughput, high-resolution separation technique, and that resolution in membrane chromatography can be higher than resin column chromatography under preparative conditions and at much higher volumetric throughput. 相似文献