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排序方式: 共有1007条查询结果,搜索用时 859 毫秒
51.
Dr. Renata Avena Maia Felipe Lopes Oliveira Prof. Vincent Ritleng Prof. Qiang Wang Dr. Benoît Louis Prof. Pierre Mothé Esteves 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(30):8048-8055
Covalent organic frameworks (COFs) RIO-13, RIO-12, RIO-11, and RIO-11m were investigated towards their CO2 capture properties by thermogravimetric analysis at 1 atm and 40 °C. These microporous COFs bear in common the azine backbone composed of hydroxy-benzene moieties but differ in the relative number of hydroxyl groups present in each material. Thus, their sorption capacities were studied as a function of their textural and chemical properties. Their maximum CO2 uptake values showed a strong correlation with an increasing specific surface area, but that property alone could not fully explain the CO2 uptake data. Hence, the specific CO2 uptake, combined with DFT calculations, indicated that the relative number of hydroxyl groups in the COF backbone acts as an adsorption threshold, as the hydroxyl groups were indeed identified as relevant adsorption sites in all the studied COFs. Additionally, the best performing COF was thoroughly investigated, experimentally and theoretically, for its CO2 capture properties in a variety of CO2 concentrations and temperatures, and showed excellent isothermal recyclability up to 3 cycles. 相似文献
52.
Ao Yu Guoming Ma Jintian Jiang Yajing Hu Mingming Su Wangtao Long Shixin Gao Dr. Hsien-Yi Hsu Dr. Ping Peng Prof. Fang-Fang Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(40):10405-10412
Inspired by the spongy bone structures, three-dimensional (3D) sponge-like carbons with meso-microporous structures are synthesized through one-step electro-reduction of CO2 in molten carbonate Li2CO3−Na2CO3−K2CO3 at 580 °C. SPC4-0.5 (spongy porous carbon obtained by electrolysis of CO2 at 4 A for 0.5 h) is synthesized with the current efficiency of 96.9 %. SPC4-0.5 possesses large electrolyte ion accessible surface area, excellent wettability and electronical conductivity, ensuring the fast and effective mass and charge transfer, which make it an advcanced supercapacitor electrode material. SPC4-0.5 exhibits a specific capacitance as high as 373.7 F g−1 at 0.5 A g−1, excellent cycling stability (retaining 95.9 % of the initial capacitance after 10000 cycles at 10 A g−1), as well as high energy density. The applications of SPC4-0.5 in quasi-solid-state symmetric supercapacitor and all-solid-state flexible devices for energy storage and wearable piezoelectric sensor are investigated. Both devices show considerable capacitive performances. This work not only presents a controllable and facile synthetic route for the porous carbons but also provides a promising way for effective carbon reduction and green energy production. 相似文献
53.
G. Brunner 《Isotopes in environmental and health studies》2013,49(12):420-424
Modern radiometric analytics demands a complex consideration of nuclear and electron shell processes, if more pretentious aims are envisaged. As an example the small variation of decay rates of radionuclides presents possibilities for information on chemical situations of decaying atoms. In principle this phenomenon is well known since many years, but now the situation is such that, e.g. in 99mTc internal conversion, a full agreement of the difficult experiments and the respective theory was established. The secondary emission of X-rays as a consequence of high excitation of electron shells in combination with nuclear transitions supplies another example for a methodical progress of radiometry. Investigations on 51Cr as an electron capture nuclide have shown that chemically induced variations of the Kα to Kβ X-ray intensity ratio is at least qualitatively understood. 相似文献
54.
《Analytical letters》2012,45(11):1005-1012
Abstract A procedure for the determination of propoxyphene (α-d-dimethylamino-1, 2 -diphenyl-3 -methyl-2 -propionoxybutane) in plasma is reported. The method is based on the electron capture characteristics of propoxyphene. The plasma is rendered basic to generate the free amine and extracted with ether. The extract is analyzed by gas chromatography using a 4 foot OV-225 column. An internal standard of imipramine hydrochloride is used to quantitate the propoxyphene. This internal standard is carried through the entire procedure. The ratio of the peak heights of propoxyphene to imipramine is compared to ratios obtained from standards placed in plasma and treated in the same manner as the samples. Six subjects were given propoxyphene at different time intervals, and the data are presented concerning these subjects. 相似文献
55.
A multiscale information measure (MIM), calculable from per-pixel wavelet coefficients, but relying on global statistics of synthetic aperture radar (SAR) image, is proposed. It fully exploits the variations in speckle pattern when the image resolution varies from course to fine, thus it can capture the intrinsic texture of the scene backscatter and the texture due to speckle simultaneously. Graph spectral segmen- tation methods based on MIM and the usual similarity measure are carried out on two real SAR images. Experimental results show that MIM can characterize texture information of SAR image more effectively than the commonly used similarity measure. 相似文献
56.
57.
An alternate and a new interpretation is given for the event attributed to a magnetic monopole by Price and coworkers found
in an emulsion plastic sandwich stack flown from Sioux City, Iowa, USA on 18 September 1973. The electron pick-up and stripping
cross-sections of nuclei ofZ∼70–80 andv∼0.6–0.7c in Lexan polycarbonate are calculated using the formulae given by Nikolaev. It is shown that the corresponding mean free
paths are of the order of thickness (∼250μ) of Lexan plastic sheets used by them. In such a case asnapshot of these processes is believed to have been observed in plastic sheets. Monte-Carlo simulations of the event have been made
for three values of charges at the top of the main Lexan stack, namelyZ=83, 78 and 70 respectively. The event is thus interpreted as a cosmic ray nucleus ofZ=70–83 andv=0.6–0.7c losing and capturing electrons (mainly the latter) as it passes through the stack. The probability of the occurrence of such
an event is estimated by several methods. 相似文献
58.
H. V. Klapdor-Kleingrothaus 《Foundations of Physics》2003,33(5):813-829
Double beta decay is indispensable to solve the question of the neutrino mass matrix together with oscillation experiments. Recent analysis of the most sensitive experiment since nine years—the HEIDELBERG-MOSCOW experiment in Gran-Sasso—yields a first indication for the neutrinoless decay mode. This result is the first evidence for lepton number violation and proves the neutrino to be a Majorana particle. We give the present status of the analysis in this report. It excludes several of the neutrino mass scenarios allowed from present neutrino oscillation experiments—only degenerate scenarios and those with inverse mass hierarchy survive. This result allows neutrinos to still play an important role as dark matter in the Universe. To improve the accuracy of the present result, considerably enlarged experiments are required, such as GENIUS. A GENIUS Test Facility has been funded and will come into operation by early 2003. 相似文献
59.
60.
采用微扰静态(PSS)模型近似处理极化和结合能效应,并引入了相对论效应、能量损失效应和库仑偏转效应修正的ECPSSR理论是描述直接库仑电离过程最成功的理论,但对于低能离子入射时, 其结果明显低于实验值. 采用联合分离原子(USA)模型替代ECPSSR中的PSS模型,考虑分子轨道效应得到了基于USA模型的电离理论——MECUSAR理论. 对部分碰撞系统进行了计算,得到的碰撞截面与实验结果基本符合. 结合OBKN(Oppenheimer-Brinkman-Kramers formulas of Nikolae
关键词:
X射线产生截面
离子-原子碰撞
电子俘获 相似文献