某电站大型地下洞室群主变洞确定性块体稳定性评价

以黄河上游某大型电站地下洞室群主变洞为例,通过在AutoCAD软件中建立洞室与结构面的三维实体模型,借助自编程序切割,展示这些结构面在主变洞边墙及拱顶的出露情况,在此基础上检索出组合块体21个,最后对这21个块体进行了确定性块体稳定性评价,给出其在主变洞上下游边墙及拱顶的块体组合情况、滑动方式、出露桩号和高度、出露面积、分布深度、体积、稳定性系数等。     

Reiterated Homogenization and the Double-Porosity Model

We consider the effects of a hierarchical, multiple layered system of fractures on the flow of a single-phase, slightly compressible fluid through a porous medium. A microscopic flow model is first defined which describes precisely the physics of the flow and the geometry of the fracture system and porous matrix, all of which depends on a positive parameter that determines the scale of the various fracture-level thicknesses. We then show by a rigorous mathematical argument that the unique solution of this microscopic problem converges as 0 to the solution of a double-porosity model of the global macroscopic flow. Our techniques make use of the concept of reiterated homogenization and essentially consist of an adaptation of the methods of extension and dilation operators to the reiterated-homogenization context. We show how the porosities and permeability tensor of the porous medium are determined in a precise way by certain physical and geometric features of the microscopic fracture domain, the microscopic matrix blocks, and the interface between them.     

A concise formal stereoselective total synthesis of （-）-swainsonine

A short formal stereoselective synthesis of （-）-swainsonine （1） is described. Our synthesis started with the versatile building block （R）-3-benzyloxyglutarimide 5. Through controlled regioselective reduction, Ley＇s-sulfone chemistry （N-α-sulfonylation and ZnCl2-catalyzed N-α-amidovinylation）, an RCM reaction, and an amide reduction, the synthesis of unsaturated indolizidine （8R,8aS）-3 has been achieved in five steps. The indolizidine （8R,8aS）-3 is an advanced intermediate toward the synthesis of （-）-swainsonine （1）.     

Parallelism error characterization with mechanical and interferometric methods

Two methods for measuring the parallelism error of gauge blocks are discussed. The first method makes use of contact probes, sampling the gauge thickness at fixed locations; the parallelism error is given by the difference between maximum and minimum thickness over the sampled area. The second method is based on interferometry, producing the height maps of the opposing surfaces with respect to one another; the parallelism error is obtained after processing of the interferometric data. The two methods have been implemented in different laboratories, and compared by measuring five different gauge blocks. The results are reported, showing that the first method is more straightforward and simple, but requires prior calibration and provides information only on a limited number of sample points. The second method is more demanding in terms of equipment and measuring procedure, but in principle it is an absolute method, and provides information over a large number of data points.     

Discrete-time analysis of the GI/G/1 system with Bernoulli retrials: An algorithmic approach

In this paper, we show that the discrete GI/G/1 system with Bernoulli retrials can be analyzed as a level-dependent QBD process with infinite blocks; these blocks are finite when both the inter-arrival and service times have finite supports. The resulting QBD has a special structure which makes it convenient to analyze by the Matrix-analytic method (MAM). By representing both the inter-arrival and service times using a Markov chain based approach we are able to use the tools for phase type distributions in our model. Secondly, the resulting phase type distributions have additional structures which we exploit in the development of the algorithmic approach. The final working model approximates the level-dependent Markov chain with a level independent Markov chain that has a large set of boundaries. This allows us to use the modified matrix-geometric method to analyze the problem. A key task is selecting the level at which this level independence should begin. A procedure for this selection process is presented and then the distribution of the number of jobs in the orbit is obtained. Numerical examples are presented to demonstrate how this method works.     

A new homobimetallic arenediyl diplatinum(II) unit as building block for macromolecular synthesis. X-ray crystal structure of [C6H2{CH2NMe2}2-1,5-{PtCl(PPh3)}2-2,4]

Treatment of the diaminobenzene [C₆H₄{CH₂NMe₂}₂-1,3] (NCN-H, 1) with one or two equivalents of cis-PtCl₂(DMSO)₂ leads to exclusive formation of the doubly cycloplatinated species [C₆H₄{CH₂NMe₂}₂-1,5-{PtCl(DMSO)}₂-2,4] (3), which upon addition of triphenylphosphine yields the bisphosphine adduct [C₆H₄{CH₂NMe₂}₂-1,5-{PtCl(PPh₃)}₂-2,4] (4). The X-ray molecular structure of 4 revealed the presence of highly distorted square planar Pt(II) centers which is caused by close proximity of the two phosphine donor ligands. Complexes of type 3 can be regarded as suitable starting materials for the directional build-up of larger macromolecular structures.     

Quantum aspects of black hole entropy

This survey intends to cover recent approaches to black hole entropy which attempt to go beyond the standard semiclassical perspective. Quantum corrections to the semiclassical Bekenstein-Hawking area law for black hole entropy, obtained within the quantum geometry framework, are treated in some detail. Their ramification for the holographic entropy bound for bounded stationary spacetimes is discussed. Four dimensional supersymmetric extremal black holes in string-based N=2 supergravity are also discussed, albeit more briefly.     

Synthesis,structure, magnetism and antibacterial properties of a 2-D nickel(II) metal–organic framework based on 3-nitrophthalic acid and 4,4′-bipyridine

A 2-D nickel(II) mixed-ligand metal–organic framework [Ni(NPTA)(4,4′-bipy)(H₂O)]_n (1) was synthesized by reaction of 3-nitrophthalic acid (H₂NPTA) and 4,4′-bipyridine (4,4′-bipy) with Ni(II) under hydrothermal condition and characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound 1 possesses a 2-D layer structure constructed from dinuclear nickel(II) building blocks in which two crystallographically equivalent Ni ions are bridged by two NPTA ligands. Furthermore, the layers are connected into 3-D supramolecular network by hydrogen bonds. The magnetism and antibacterial activity of 1 were investigated.