光学波段菲波纳契序列一维光子晶体纳米膜传输特性研究

为了研究光学波段菲波纳契序列一维光子晶体纳米膜的传输特性,应用传输矩阵方法数值模拟各种情况下的透射率即传输函数随频率的变化.数值结果表明在正入射时,菲波纳契序列一维光子晶体中的禁带宽度、中心位置、数目都与构成序列的项数、组元物理厚度、组成序列组元初始次序、组元折射率差值都对传输特性有较大影响,在可见光区组元折射率差值越大越易形成较宽禁带,进一步研究广义菲波纳契序列一维光子晶体纳米膜的传输特性,发现比典型情况更易在可见光区形成禁带.     

A Novel Implementation Technique of Conical Scan Radar Using A Programmable Phased Array

In radar, planar phased array antenna plays vital role in electronic scanning in the azimuth and elevation direction to the horizon. In most operations using planar phased array both the coordinates of azimuth and elevation, are steered electronically. In this paper a conceptual schematic of a phased array antenna with programmable time delay units has been presented. It is shown that by suitably exploiting the time delay matrix one can have electronic beam rotation around the target axis as required in conical scan. Thus both the elevation and azimuth motors in conical scan system are replaced by electronic scanning. Heuristically, we have selected eight consecutive points for beam rotation in a polygon shape and can also be extended almost circular shape by increasing number of array elements and phase shifter (delays) in the delay matrix. The array requires dual control of phase gradient and individual phase values. The whole array is controlled by micro-controller. This presents exciting possibilities in radar operation.     

Homography of central points for optical distortion compensation

The paper presents a novel radial lens distortion modelling method for vision systems. It is based on single images of chessboard planar pattern, in which calibration points (corners of chessboard squares) are localised. The points, which are situated near the image centre, where the distortion is negligible, are used to determine undistorted grid of calibration points by the estimation of homographic matrix. The differences in the localisation of undistorted and distorted points are used to find parameters of radial model by the linear least square method. Having the distortion model, the dense compensation is performed with support of bilinear interpolation and a sparse compensation by Newton iterative scheme providing subpixel accuracy.     

应用键轨道连接矩阵方法预测烷烃折光率.

应用键轨道连接矩阵方法提取结构参数PX1CC和PX1CH， 并用于建立预测烷烃折光率的QSPR模型．该模型不仅预测精度较高(其误差仅为0.0048)，而且模型中采用的参数表达了直接与分子的折光能力相关的结构信息(即烷烃分子中电子被极化的能力)．此参数提取简单，既具备拓扑指数简单、易算，物理意义明确．     

Nearest-neighbour spacing distributions of the β-Hermite ensemble of random matrices

The evolution with β of the distributions of the spacing ‘s’ between nearest-neighbour levels of unfolded spectra of random matrices from the β-Hermite ensemble (β-HE) is investigated by Monte Carlo simulations. The random matrices from the β-HE are real symmetric and tridiagonal where β, which can take any positive value, is the reciprocal of the temperature in the classical electrostatic interpretation of eigenvalues. The distribution of eigenvalues coincide with those of the three classical Gaussian ensembles for β=1, 2, 4. The use of the β-HE ensemble results in an incomparable speed up and efficiency of numerical simulations of all spectral characteristics of large random matrices. Generalized gamma distributions are shown to be excellent approximations of the nearest-neighbor spacing (NNS) distributions for any β while being still simple. They account both for the level repulsion in ∼s^β when s→0 and for the whole shape of the NNS distributions in the range of ‘s’ which is accessible to experiment or to most numerical simulations. The exact NNS distribution of the GOE (β=1) is in particular significantly better described by a generalized gamma distribution than it is by the Wigner surmise while the best generalized gamma approximation coincides essentially with the Wigner surmise for β>∼2. They describe too the evolution of the level repulsion between that of a Poisson distribution and that of a GOE distribution when β increases from 0 to 1. The distribution of ln (s), related to the electrostatic interaction energy between neighbouring charges, is accordingly well approximated by a generalized Gumbel distribution for any β?0. The distributions of the minimum NN spacing between eigenvalues of matrices from the β-HE, obtained both from as-calculated eigenvalues and from unfolded eigenvalues are Brody distributions which are classically used to characterize the spectral fluctuations of various physical systems.     

一种处理原子核多体问题的有效方法

由二级散射矩阵元出发计算了核物质内强子的二级自能修正, 并且归纳了一种研究原子核多体问题的有效方法. 另外, 还讨论了各种密度相关的相对论多体方法之间的关系.     

正切平方势阱中线性与非线性光学折射率变化的研究

利用正切平方势把电子的Schrodinger方程化为了超几何方程，并用超几何函数严格求解了电子的本征值和本征函数利用量子力学中的密度矩阵算符理论导出了正切平方势阱中的线性与三阶非线性光学折射率的解析表达式计算了该系统中的线性与非线性光学折射率变化的大小，讨论了影响折射率变化因素文章以典型的GaAs/AlGaAs势阱为例作了数值计算,数值计算结果表明，势阱的形状和入射光强对光学折射率的变化有着重要的影响.     

A new thermo‐responsive block copolymer with tunable upper critical solution temperature and lower critical solution temperature in the alcohol/water mixture

The multi‐thermo‐responsive block copolymer of poly[2‐(2‐methoxyethoxy)ethyl methacrylate]‐block‐poly[N‐(4‐vinylbenzyl)‐N,N‐diethylamine] (PMEO₂MA‐b‐PVEA) displaying phase transition at both the lower critical solution temperature (LCST) and the upper critical solution temperature (UCST) in the alcohol/water mixture is synthesized by reversible addition‐fragmentation chain transfer polymerization. The poly[2‐(2‐methoxyethoxy)ethyl methacrylate] (PMEO₂MA) block exhibits the UCST phase transition in alcohol and the LCST phase transition in water, while the poly[N‐(4‐vinylbenzyl)‐N,N‐diethylamine] (PVEA) block shows the UCST phase transition in isopropanol and the LCST phase transition in the alcohol/water mixture. Both the polymer molecular weight and the co‐solvent/nonsolvent exert great influence on the LCST or UCST of the block copolymer. By adjusting the solvent character including the water content and the temperature, the block copolymer undergoes multiphase transition at LCST or UCST, and various block copolymer morphologies including inverted micelles, core‐corona micelles, and corona‐collapsed micelles are prepared. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4399–4412     

Polymersome‐forming amphiphilic glycosylated polymers: Synthesis and characterization

Copper‐catalyzed azide‐alkyne cycloaddition (CuAAC) was used to prepare glycosylated polyethylene (PE)–poly(ethylene glycol) (PEG) amphiphilic block copolymers. The synthetic approach involves preparation of alkyne‐terminated PE‐b‐PEG followed by CuAAC reaction with different azide functionalized sugars. The alkyne‐terminated PE‐b‐PEG was prepared by etherification reaction between hydroxyl‐terminated PE‐b‐PEG (M_n ～ 875 g mol^?1) and propargyl bromide and azidoethyl glycosides were prepared by glycosylation of 2‐azidoethanol. Atmospheric pressure solids analysis probe‐mass spectrometry was used as a novel solid state characterization tool to determine the outcome of the CuAAC click reaction and end‐capping of PE‐b‐PEG by the azidoethyl glycoside group. The aqueous solution self‐assembly behavior of these amphiphilic glycosylated polymers was explored by TEM and dye solubilization studies. Carbohydrate‐bearing spherical aggregates with the ability to solubilize a hydrophobic dye were observed. The potential of these amphiphilic glycosylated polymers to self‐assemble via electro‐formation into giant carbohydrate‐bearing polymersomes was also investigated using confocal fluorescence microscopy. An initial bioactivity study of the carbohydrate‐bearing aggregates is furthermore presented. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 5184–5193     

Synthesis of photocleavable poly(methyl methacrylate‐block‐d‐lactide) via atom‐transfer radical polymerization and ring‐opening polymerization

The synthesis and characterization of a photocleavable block copolymer containing an ortho‐nitrobenzyl (ONB) linker between poly(methyl methacrylate) and poly(d ‐lactide) blocks is presented here. The block copolymers were synthesized via atom transfer radical polymerization (ATRP) of MMA followed by ring‐opening polymerization (ROP) of d ‐Lactide and ROP of d ‐lactide followed by ATRP of MMA from a difunctional photoresponsive ONB initiator, respectively. The challenges and limitations during synthesis of the photocleavable block copolymers using the difunctional photoresponsive ONB initiator are discussed. The photocleavage of the copolymers occurs under mild conditions by simple irradiation with 302 nm wavelength UV light (Relative intensity at 7.6 cm: 1500 μW/cm²) for several hours. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4309–4316