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A.A. Yaremchenko A.V. Kovalevsky E.N. NaumovichV.V. Kharton J.R. Frade 《Solid State Ionics》2011,192(1):252-258
Phase relationships, thermal expansion and electrical properties of Mg1 − xFexO (x = 0.1-0.45) cubic solid solutions and Fe3 − x − yMgxCryO4 ± δ (x = 0.7-0.95; y = 0 or 0.5) spinels were studied at 300-1770 K in the oxygen partial pressure range from 10 Pa to 21 kPa. Increasing iron content enlarges the spinel phase stability domain at reduced oxygen pressures and elevated temperatures. The total conductivity of the spinel ceramics is predominantly n-type electronic and is essentially p(O2)-independent within the stability domain. The computer simulations using molecular dynamics technique confirmed that overall level of ion diffusion remains low even at high temperatures close to the melting point. Temperature dependencies of the total conductivity in air exhibit a complex behavior associated with changing the dominant defect-chemistry mechanism from prevailing formation of the interstitial cations above 1370-1470 K to the generation of cation vacancies at lower temperatures, and with kinetically frozen cation redistribution in spinel lattice below 700-800 K. The average thermal expansion coefficients of the spinel ceramics calculated from dilatometric data in air vary in the range (9.6-10.0) × 10− 6 K− 1 at 300-500 K and (13.2-16.1) × 10− 6 K− 1 at 1050-1370 K. Mg1 − xFexO solid solutions undergo partial decomposition on heating under oxidizing and mildly reducing conditions, resulting in the segregation of spinel phase and conductivity decrease. 相似文献
74.
《Physics letters. A》2014,378(30-31):1992-1996
Due to quantum size effects (QSEs), the isobaric thermal expansion coefficient and isothermal compressibility well defined for macroscopic systems are invalid for finite-size systems. The two parameters are redefined and calculated for a finite-size ideal Fermi gas confined in a rectangular container. It is found that the isobaric thermal expansion coefficient and isothermal compressibility are generally anisotropic, i.e., they are generally different in different directions. Moreover, it is found the thermal expansion coefficient may be negative in some directions under the condition that the pressures in all directions are kept constant. 相似文献
75.
We argue that the recently introduced statefinder parameters (Sahni et al., JETP Lett. 77, 201 (2003)), that include the third derivative of the cosmic scale factor, are useful tools to characterize interacting quintessence models. We specify the statefinder parameters for two classes of models that solve, or at least alleviate, the coincidence problem. 相似文献
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To exploit the parallelism of optics in data processing,a suitable number system and an efficient encoding/decoding scheme for handling the data are very essential.In the field of optical computing and parallel information processing,several number systems like binary,quaternary,octal,hexadecimal,etc.have been used for different arithmetic and algebraic operations.Here,we have proposed an all-optical conversion scheme from its binary to its other 2n radix based form with the help of terahertz optical asymmetric demultiplexer (TOAD) based tree-net architecture. 相似文献
79.
Radiofrequency ablation is the most common minimally invasive therapy used in the United States to treat hepatocellular carcinoma and liver metastases. The ability to perform real-time temperature imaging while a patient is undergoing ablation therapy may help reduce the high recurrence rates following ablation therapy. Ultrasound echo signals undergo time shifts with increasing temperature due to sound speed and thermal expansion, which are tracked using both 1D cross correlation and 2D block matching based speckle tracking methods. In this paper, we present a quantitative evaluation of the accuracy and precision of temperature estimation using the above algorithms on both simulated and experimental data.A finite element analysis simulation of radiofrequency ablation of hepatic tissue was developed. Finite element analysis provides a method to obtain the exact temperature distribution along with a mapping of the tissue displacement due to thermal expansion. These local displacement maps were combined with the displacement due to speed of sound changes and utilized to generate ultrasound radiofrequency frames at specified time increments over the entire ablation procedure. These echo signals provide an ideal test-bed to evaluate the performance of both speckle tracking methods, since the estimated temperature results can be compared directly to the exact finite element solution. Our results indicate that the 1D cross-correlation (CC) method underestimates the cumulative displacement by 0.20 mm, while the underestimation with 2D block matching (BM) is about 0.14 mm after 360 s of ablation. The 1D method also overestimates the size of the ablated region by 5.4% when compared to 2.4% with the 2D method after 720 s of ablation. Hence 2D block matching provides better tracking of temperature variations when compared to the 1D cross-correlation method over the entire duration of the ablation procedure. In addition, results obtained using 1D cross-correlation diverge from the ideal finite element results after 7 min of ablation and for temperatures greater than 65 °C.In a similar manner, experimental results presented using a tissue-mimicking phantom also demonstrate that the maximum percent difference with 2D block matching was 5%, when compared to 31% with the 1D method over the 700 s heating duration on the phantom. 相似文献
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大气信道中的大气湍流是影响无线激光通信系统性能的主要因素之一, 其引起的强度闪烁效应会对接收信号的提取和还原造成很大干扰。基于Gamma-Gamma概率分布的大气湍流信道统计模型, 研究了利用副载波相移键控(PSK)强度调制技术的大气光通信系统的误码特性; 推导了副载波二进制相移键控(BPSK)及开关键控(OOK)两种调制模式下的系统误码率表达式; 对在一定条件下的大气光通信系统, 比较了副载波BPSK和OOK两种调制模式的误码特性; 分析了链路特征、接收口径尺寸、通信波长和天顶角等因素对系统误码率的影响。结果表明, 增大接收孔径和通信波长都能有效地降低系统误码率, 而天顶角的增大则会使系统误码率增加, 副载波BPSK调制模式的误码特性要优于OOK调制模式的误码特性。 相似文献