全文获取类型
收费全文 | 760篇 |
免费 | 75篇 |
国内免费 | 59篇 |
专业分类
化学 | 213篇 |
力学 | 23篇 |
综合类 | 8篇 |
数学 | 357篇 |
物理学 | 293篇 |
出版年
2024年 | 2篇 |
2023年 | 14篇 |
2022年 | 11篇 |
2021年 | 20篇 |
2020年 | 25篇 |
2019年 | 39篇 |
2018年 | 21篇 |
2017年 | 27篇 |
2016年 | 30篇 |
2015年 | 18篇 |
2014年 | 39篇 |
2013年 | 73篇 |
2012年 | 32篇 |
2011年 | 51篇 |
2010年 | 44篇 |
2009年 | 56篇 |
2008年 | 54篇 |
2007年 | 40篇 |
2006年 | 31篇 |
2005年 | 27篇 |
2004年 | 21篇 |
2003年 | 15篇 |
2002年 | 21篇 |
2001年 | 22篇 |
2000年 | 22篇 |
1999年 | 16篇 |
1998年 | 11篇 |
1997年 | 13篇 |
1996年 | 15篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1993年 | 9篇 |
1992年 | 9篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 8篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1973年 | 1篇 |
排序方式: 共有894条查询结果,搜索用时 15 毫秒
121.
Arakelov and Faltings developed an admissible theory on regulararithmetic surfaces by using Arakelov canonical volume formson the associated Riemann surfaces. Such volume forms are inducedfrom the associated Kähler forms of the flat metric onthe corresponding Jacobians. So this admissible theory is inthe nature of Euclidean geometry, and hence is not quite compatiblewith the moduli theory of Riemann surfaces. In this paper, wedevelop a general admissible theory for arithmetic surfaces(associated with stable curves) with respect to any volume form.In particular, we have a theory of arithmetic surfaces in thenature of hyperbolic geometry by using hyperbolic volume formson the associated Riemann surfaces. Our theory is proved tobe useful as well: we have a very natural Weil function on themoduli space of Riemann surfaces, and show that in order tosolve the arithmetic Bogomolov-Miyaoka-Yau inequality, it issufficient to give an estimation for Petersson norms of somemodular forms. 1991 Mathematics Subject Classification: 11G30,11G99, 14H15, 53C07, 58A99. 相似文献
122.
Valeriy V. Bezrodnyi Sofia E. Mikhtaniuk Oleg V. Shavykin Igor M. Neelov Nadezhda N. Sheveleva Denis A. Markelov 《Molecules (Basel, Switzerland)》2021,26(21)
Novel peptide dendrimer with Lys-2His repeating units was recently synthesized, studied by NMR (Molecules, 2019, 24, 2481) and tested as a nanocontainer for siRNA delivery (Int. J. Mol. Sci., 2020, 21, 3138). Histidine amino acid residues were inserted in the spacers of this dendrimer. Increase of their charge with a pH decrease turns a surface-charged dendrimer into a volume-charged one and should change all properties. In this paper, the molecular dynamics simulation method was applied to compare the properties of the dendrimer in water with explicit counterions at two different pHs (at normal pH with neutral histidines and at low pH with fully protonated histidines) in a wide interval of temperatures. We obtained that the dendrimer at low pH has essentially larger size and size fluctuations. The electrostatic properties of the dendrimers are different but they are in good agreement with the theoretical soft sphere model and practically do not depend on temperature. We have shown that the effect of pairing of side imidazole groups is much stronger in the dendrimer with neutral histidines than in the dendrimer with protonated histidines. We also demonstrated that the capacity of a nanocontainer based on this dendrimer with protonated histidines is significantly larger than that of a nanocontainer with neutral histidines. 相似文献
123.
124.
分析了20 < A < 190范围内丰中子核β衰变的实验数据,根据半衰期随质子数、中子数以及衰变能变化所呈现的壳效应和对效应等特点,提出了一种有效估算丰中子核β衰变寿命的公式。新的计算公式形式简单包含了较少的参数、计算量小。用该公式能较为准确地再现丰中子核的β衰变半衰期。用RIKEN最新测量丰中子核半衰期检验了该公式的外推能力,本工作可以为r-过程研究提供可靠的输入数据。Experimental data of the β--decay half-lives for the nuclei with atomic number between 20 and 190 are investigated. We have systematically studied the shell effects and pairing effects on β--decay half-lives versus the decay energy Q and nucleon numbers (Z, N). An empirical formula has been proposed to calculate the β--decay half-lives of neutron-rich nuclei. The empirical formula is simple and has relatively few parameters. Experimental β--decay half-lives of the neutron-rich nuclei are well reproduced by the new formula. In addition, the extrapolating capacity of this formula has been checked with the very recent experimental data from RIKEN. The predicted half-lives for r-process relevant nuclei with the current formula can be served as the reliable input of r-process model calculations. 相似文献
125.
采用基于推转壳模型的粒子数守恒方法对105Cd 和106Cd 中的反磁转动带进行了研究,在计算当中,粒子数严格守恒,并且堵塞效应也是严格考虑的。计算结果很好地再现了实验上观测到的I-Ω 关系、转动惯量以及约化跃迁几率B(E2)。通过检验双剪角,即两个质子空穴角动量的合拢,对反磁转动中的双剪刀机制进行了分析。研究表明剪刀角的合拢非常敏感地依赖于对关联。The antimagnetic rotation bands in 105;106Cd are investigated by the cranked shell model with pairing correlations treated by a particle-number conserving method, in which the blocking effects are taken into account exactly. The experimental moments of inertia, I-Ω relation and the reduced B(E2) transition probabilities are well reproduced. The two-shears-like mechanism for the antimagnetic rotation is investigated by examining the shears angle, i.e., the closing of the two proton hole angular momenta. The sensitive dependence of the shears angle on the nuclear pairing correlations is revealed. 相似文献
126.
A theoretical study of the fluctuation conductivity above Tc (paraconductivity) is reported for a d-wave superconductor with resonant scattering impurities. A d-wave system is modeled by tight-binding electrons in the two-dimensional squared lattice, and the impurity scattering is treated in the T-matrix approximation in a unitary limit. In calculating the Aslamazov–Larkin (AL) and the Maki–Thompson (MT) terms, we also consider effects of a short-wavelength cutoff in the fluctuation spectrum. The d-wave character in the AL and MT terms manifests itself to renormalization effects on the fluctuation amplitude and reduced temperature, whereas an anomalous-MT term is absent. The present calculations can describe fairly well experiments on the paraconductivity in zinc-doped cuprate superconductors provided that effects of a total-energy cutoff are taken into account. 相似文献
127.
128.
Medium polarization effects are studied for 1S0 pairing in nuclear matter within BHF approach. The screening potential is calculated in the RPA limit, suitably renormalized to cure the low density mechanical instability of nuclear matter. The self-energy corrections are consistently included resulting in a strong 相似文献
129.
The effects of UV synchrotron radiation on deoxyribonucleic acid (DNA) cast films have been systematically investigated by vacuum ultraviolet and infrared spectrophotometry as a function of irradiation time. Cast DNA films exposed at 140 nm (8.85 eV) for different irradiation times, revealed consistent changes in their VUV spectra which indicate a decrease of thymine groups and an increase of π → π* transition spectral signature associated with the CO group of the open sugar chain. This result was corroborated by a decrease in CO stretching vibration at 1061 cm−1 observed in the infrared spectra. Both these results are consistent with the creation of single strand breaks in the deoxyribose component of DNA molecule and a decrease in the phosphate groups. It was also shown that UV radiation is effective in damaging the thymine groups involved in Hoogsteen base pairing with adenine. The analysis of the infrared data suggests that the usual spectroscopic fingerprints of DNA denaturation are not necessarily a reliable measure of DNA damage. 相似文献
130.
Bruno Bernet Zeena Johar Anne Ritter Bernhard Jaun Andrea Vasella 《Helvetica chimica acta》2009,92(12):2596-2630
The tritylated and silylated self‐complementary A*[s]U*[s]A*[s]U* and U*[s]A*[s]U*[s]A* tetramers 18 and 24 , linked by thiomethylene groups (abbreviated as [s]) between a nucleobase and C(5′) of the neighbouring nucleoside unit were prepared by a linear synthesis based on S‐alkylation of 5′‐thionucleosides by 6‐(chloromethyl)uridines, 7 or 10 , or 8‐(chloromethyl)adenosines, 12 or 15 . The tetramers 18 and 24 were detritylated to the monoalcohols 19 and 25 , and these were desilylated to the diols 20 and 26 , respectively. The association of the tetramers 18 – 21 and 24 – 26 in CDCl3 or in CDCl3/(D6)DMSO 95 : 5 was investigated by the concentration dependence of the chemical shifts for H? N(3) or H2N? C(6). The formation of cyclic duplexes connected by four base pairs is favoured by the presence of one and especially of two OH groups. The diol 20 with the AUAU sequence prefers reverse‐Hoogsteen, and diol 26 with the UAUA sequence Watson–Crick base pairing. The structure of the cyclic duplex of 26 in CDCl3 at 2° was derived by a combination of AMBER* modeling and simulated annealing with NMR‐derived distance and torsion‐angle restraints resulting in a Watson–Crick base‐paired right‐handed antiparallel helix showing large roll angles, especially between the centre base pairs, leading to a bent helix axis. 相似文献