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951.
Professor A. Siginer 《Rheologica Acta》1991,30(5):447-473
Superposition of oscillatory shear imposed from the boundary and through pressure gradient oscillations and simple shear is investigated. The integral fluid with fading memory shows flow enhancement effects due to the nonlinear structure. Closed-form expressions for the change in the mass transport rate are given at the lowest significant order in the perturbation algorithm. The elasticity of the liquid plays as important a role in determining the enhancement as does the shear dependent viscosity. Coupling of shear thinning and elasticity may produce sharp increases in the flow rate. The interaction of oscillatory shear components may generate a steady flow, either longitudinal or orthogonal, resulting in increases in flow rates akin to resonance, and due to frequency cancellation, even in the absence of a mean gradient. An algorithm to determine the constitutive functions of the integral fluid of order three is outlined.Nomenclature
A
n
Rivlin-Ericksen tensor of order .
-
A
k
Non-oscillatory component of the first order linear viscoelastic oscillatory velocity field induced by the kth wave in the pressure gradient
-
d
Half the gap between the plates
-
e
x, e
z
Unit vectors in the longitudinal and orthogonal directions, respectively
-
G(s)
Relaxation modulus
-
G
History of the deformation
-
Stress response functional
-
I()
Enhancement defined as the ratio of the frequency dependent part of the discharge to the frequencyindependent part of it at the third order
-
I
*()
Enhancement defined as the ratio of the increase in discharge due to oscillations to the total discharge without the oscillations
-
k
Power index in the relaxation modulus G(s)
-
k
i
–1
Relaxation times in the Maxwell representation of the quadratic shear relaxation modulus (s
1, s
2)
-
m
i
–1, n
i
–1
Relaxation times in the Maxwell representations of the constitutive functions 1(s
1,s
2,s
3) and 4 (s
1, s
2,s
3), respectively
-
P
Constant longitudinal pressure gradient
-
p
Pressure field
-
mx
,(3)
nz
,(3)
Mean volume transport rates at the third order in the longitudinal and orthogonal directions, respectively
- 0,(3), 1,(3)
Frequency independent and dependent volume transport rates, respectively, at the third order
-
s = t-
Difference between present and past times t and 相似文献
952.
Shu-Xian Gu 《Acta Mechanica Solida Sinica》1988,1(4):369-381
In this paper, we treat the nonlinear stability problem of shallow spherical shells with large values ofk(k=12(1–v) · 2f/h,f = shell rise,h = shell thickness) under the action of uniformly distributed line load along a circle concentric with the shell boundary. Load-deflection curves are computed at successive increments of uniformly distributed line loads by using both cubic B-spline approximations and iterative techniques. Our algorithm yields fairly good convergent results for values ofk as large as 400. The limiting case in which shells are loaded along a circle of small radius has been specially investigated and the computed critical loads are compared with those obtained with central point loads by other authors. 相似文献
953.
Hai‐Yan Fu Hai‐Long Wu Yong‐Jie Yu Li‐Li Yu Shu‐Rong Zhang Jin‐Fang Nie Shu‐Fang Li Ru‐Qin Yu 《Journal of Chemometrics》2011,25(8):408-429
A novel third‐order calibration algorithm, alternating weighted residue constraint quadrilinear decomposition (AWRCQLD) based on pseudo‐fully stretched matrix forms of quadrilinear model, was developed for the quantitative analysis of four‐way data arrays. The AWRCQLD algorithm is based on the new scheme that introduces four unique constraint parts to improve the quality of four‐way PARAFAC algorithm. The tested results demonstrated that the AWRCQLD algorithm has the advantage of faster convergence rate and being insensitive to the excess component number adopted in the model compared with four‐way PARAFAC. Moreover, simulated data and real experimental data were analyzed to explore the third‐order advantage over the second‐order counterpart. The results showed that third‐order calibration methods possess third‐order advantages which allow more inherent information to be obtained from four‐way data, so it can improve the resolving and quantitative capability in contrast with second‐order calibration especially in high collinear systems. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
954.
A molecular thermodynamic model for polyelectrolyte systems—called pePC-SAFT—is proposed. The effect of charged monomers within the polyelectrolyte chain is explicitly taken into account in the reference term by replacing the hard-chain contribution of the PC-SAFT model by a charged-hard-chain contribution. Moreover, counterion condensation is accounted for to determine the effective number of charges along the polyion as well as of free counterions. The electrostatic contribution of the free counterions is described by a Debye–Hückel term. 相似文献
955.
Lei Xiao Edmund J. F. Dickinson Gregory G. Wildgoose Richard G. Compton 《Electroanalysis》2010,22(3):269-276
We report the comparison of electron transfer kinetic parameters of the ferrocene redox couple in both acetonitrile and in room temperature ionic liquid (RTIL) 1‐butyl‐3‐methylimidiazonium hexafluorophosphate ([C4mim] [PF6]), using edge plane pyrolytic graphite (EPPG), basal plane pyrolytic graphite (BPPG) and glassy carbon (GC) electrodes. Each electrode surface was characterized using SEM and AFM and the surface morphology was analyzed in terms of surface heterogeneity including the distribution of edge plane defects. The experimental data were modeled using both one and two dimensional simulations to correlate the electron transfer parameters obtained with the different surface structure of each electrode. Furthermore, we show that the diffusion domain approximation (commonly used to accurately simulate electron transfer kinetics at graphitic surfaces) breaks down when a BPPG electrode is used in RTIL and demonstrate the near impossibility of assigning rate constant to the basal plane surface. 相似文献
956.
The stability of the disordered structure in liquid or glass states could be characterized by the glass-forming ability (GFA) and thermal stability (TS), respectively. The two quantities are often, but not always, positively correlated. Here we show that the discrepancy between GFA and TS originates from the competition between entropy and enthalpy which fairly much relies on local structural characteristics. This inherent interaction and competition determines hierarchy of phase stability against temperature. As a result, the time susceptibility of GFA and temperature susceptibility of TS were derived from the time-temperature-transformation diagram, which are coincided with the above mentioned entropy-enthalpy competition perspective. Thus, the interrelationship among entropy, enthalpy and local cluster feature provides a potential resolution to design and optimize glass formers, and have implications for better understanding the nature of glass transition. 相似文献
957.
958.
959.
HUANG XuJian 《中国科学 数学(英文版)》2011,(6)
The main theme of this paper is to consider a notion of 'approximately unital operator systems' including both C*-algebras and unital operator systems.The goals are to prove a version of the Choi-Effros theorem for these systems,to introduce a functorial process for forming an approximately unital operator systems from a given matrix ordered vector space with a proper approximate order unit,to study second duals of these objects and to prove that a C*-algebra can be characterized as an approximately unital ... 相似文献
960.
特征值问题的预变换方法(I): 杨辉三角阵变换与二阶PDE 特征多项式 总被引:2,自引:0,他引:2
本文提出一类求解特征值问题的下三角预变换方法, 目标是通过相似变换后矩阵下三角元素平方和明显减少、且变换后的特征值及其特征向量较易求解, 使变换后的对角线可作为全体特征值很好的一组初值, 其作用如同对于解方程组找到好的预条件子, 加速迭代收敛. 以二阶PDE 数值计算为例,对于以Laplace 方程为代表的特征波向量组及正交多项式组有广泛的应用前景.
杨辉三角是我国古代数学家的一项重要成就. 本文引入杨辉三角矩阵作为预变换子, 给出一般矩阵用杨辉三角矩阵作为左、右预变换子时变为上三角矩阵的充要条件, 给出了元素为行指标二次多项式的两个矩阵类(三对角线阵与五对角线阵) 中特征值何时保持二次多项式的充要条件, 并应用于构造新的二元PDE 正交多项式. 相似文献
杨辉三角是我国古代数学家的一项重要成就. 本文引入杨辉三角矩阵作为预变换子, 给出一般矩阵用杨辉三角矩阵作为左、右预变换子时变为上三角矩阵的充要条件, 给出了元素为行指标二次多项式的两个矩阵类(三对角线阵与五对角线阵) 中特征值何时保持二次多项式的充要条件, 并应用于构造新的二元PDE 正交多项式. 相似文献