Branching and Crosslinking in Coordination Terpolymerizations

A general kinetic method, based upon population balances of generating functions, is applied to the prediction of the microstructure and molecular size of non‐linear terpolymers obtained through the coordination polymerization of two monovinyl monomers and a non‐conjugated diene. A rather complex kinetic scheme involving crosslinking and long‐chain branching is considered. It is shown that even in these conditions it is possible to carry out the prediction of molecular size and mass distributions, sequence size distributions, and z‐average mean‐square radius of gyration of the polymers. The influence of some kinetic parameters on the properties of the products is studied, considering a homogeneous operation in a semi‐batch reactor. The used simulation method is able to predict these properties before and after gelation whenever it occurs.

     

测度熵计算中映射不变分布的应用

构造计算测度熵(MetricEntropy)的马尔可夫划分(MarkovPartition)时,对于非线性映射采取等似然假设,影响精度。提出用计算映射的不变分布来进行改进;对逻辑映射导出映射不变分布的算式及迭代格式,进行了测度熵的计算;计算表明,迭代次数不多时即能得出较好结果。     

Additive and hereditary properties of graphs are uniquely factorizable into irreducible factors

A hereditary property of graphs is any class of graphs closed under isomorphism and subgraphs. Let 𝒫₁, 𝒫₂,…, 𝒫_n be hereditary properties of graphs. We say that a graph G has property 𝒫_1°𝒫_2°···_°𝒫_n if the vertex set of G can be partitioned into n sets V₁, V₂,…, V_n such that the subgraph of G induced by V_i belongs to 𝒫_i; i = 1, 2,…, n. A hereditary property is said to be reducible if there exist hereditary properties 𝒫₁ and 𝒫₂ such that ℛ = 𝒫_1°𝒫₂; otherwise it is irreducible. We prove that the factorization of a reducible hereditary property into irreducible factors is unique whenever the property is additive, i.e., it is closed under the disjoint union of graphs. © 2000 John Wiley & Sons, Inc. J Graph Theory 33: 44–53, 2000     

Kinetic model of diepoxides with reactive diluents cured with amines

The systems of diepoxides cured with primary amine in presence of an monoepoxide, monofunctional reactive, under equal stoichiometric ratio has been analyzed by a generating function method. The average degree of polymerization, which changed with time or conversion, and gel point were calculated. The profiles of the degree of polymerization and critical conversion are dependent on the content of and relative reactivities of epoxy groups. For a system with the same ratio, the critical epoxy conversion increases with increasing reactivity. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. B Polym. Phys. 36: 2339–2348, 1998     

The distribution of nodes of given degree in random trees

Let 𝒯_n denote the set of unrooted unlabeled trees of size n and let k ≥ 1 be given. By assuming that every tree of 𝒯_n is equally likely, it is shown that the limiting distribution of the number of nodes of degree k is normal with mean value ∼ μ_kn and variance ∼ σn with positive constants μ_k and σ_k. Besides, the asymptotic behavior of μ_k and σ_k for k → ∞ as well as the corresponding multivariate distributions are derived. Furthermore, similar results can be proved for plane trees, for labeled trees, and for forests. © 1999 John Wiley & Sons, Inc. J Graph Theory 31: 227–253, 1999     

Adaptation of one‐electron basis sets to spatial confinements

A method that generates out of a given orbital basis set its analog appropriate for describing the effects of a spatial confinement is presented. The method is based on the requirement that the one‐particle model spaces for the confined and for the unconfined systems are equivalent in the sense of a criterion derived from the basis‐set‐generating eigenvalue equations. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 73: 341–347, 1999     

具有不耐烦顾客且修理工多重延误休假的两部件并联的可修排队系统

从具有不耐烦顾客和修理工多重延误休假的角度,利用马尔可夫过程理论、稳态平衡方程、母函数方程的方法,研究两部件（服务台）并联的可修排队系统,并求出稳态平均队长,从而检测该模型的可行性.     

一种自适应交叉率和变异率的薄膜遗传算法

在并行移民操作的基础上,根据多层膜系迭代群体中各膜系的适应值信息,对每个膜系采取恰当的、自动适应搜索进程的交叉率和变异率。这样既保护了优良薄膜的设计方案,又能够在适应值整体水平不断提高的设计组群中,持续地产生更优良的薄膜设计结构。对增透膜的设计结果表明,采用提出的自适应遗传算法减小了早熟,提高了算法快速搜索合格膜系结构的能力。     

Dynamical algebras for Pöschl-Teller Hamiltonian hierarchies

The dynamical algebras of the trigonometric and hyperbolic symmetric Pöschl-Teller Hamiltonian hierarchies are obtained. A kind of discrete-differential realizations of these algebras are found which are isomorphic to so(3, 2) Lie algebras. In order to get them, first the relation between ladder and factor operators is investigated. In particular, the action of the ladder operators on normalized eigenfunctions is found explicitly. Then, the whole dynamical algebras are generated in a straightforward way.     

L p -Version of the Dubins–Savage Inequality and Some Exponential Inequalities

The Dubins–Savage inequality is generalized by using the pth (1<p≤2) conditional moment of the martingale differences. This inequality is further extended under suitable conditions when p>2. Another martingale inequality due to Freedman is also generalized when 0<p≤2. Implications of these inequalities for strong convergence are discussed. Some general exponential inequalities are also given for martingales (supermartingales) under suitable conditions.