原子激光传输的有效ABCD形式研究

利用含适量子系统传播子的ABCD形式的理论，将品质因子守恒系统中的ABCD定律，推广到有效品质因子守恒的系统——原子激光的传输中，通过引入有效品质因子和有效参数q_eff，利用Heisenberg图像得到传播子的有效ABCD形式.由于原子激光内部原子间相互作用的存在，原有的品质因子不再守恒，有效品质因子是描述原有品质因子和原子间相互作用综合作用效果的物理量. 关键词： 原子激光 传输 有效ABCD参数 传播子     

Anharmonic oxygen vibration and mode softening in Tl2Ba2Ca2Cu3O10 superconductor

The softening of the IR active 300 cm⁻¹ phonon mode in Tl-2223 superconductor, aroundT _c has been explained by considering a sixth order polarization potential at the off-center oxygen ion site in the Tl-O plane, and by using a nonlinear lattice dynamical theory. The present theory explains, more or less satisfactorily, the unusual temperature dependence of oxygen ion vibration and frequency shifts at higher temperature. The existence of strong nonlinear electron-phonon interaction atT _c has been emphasized.     

新疆××金矿主要矿物的标型特征及其意义

摘要黄铁矿的反射率均低于标准黄铁矿。含金黄铁矿的晶胞参数a_0为5.4170A—5.4175A、热电系数为正值。在600—200(cm~(-1))波数内,红外光谱曲线的吸收谷较为开阔,且随含金量的增加有向长波方向产生系统位移的趋势。在其求I矿,氧、氢和碳的同位素丰度是:δO_(SiO_2)~(18)11.93—16.3‰、δO_(H_2)~(12)O-1.06—4.34‰、δD—84.4—-128.8‰、δC~(13)-12.92—-17.22‰。在石英的包裹体气相中,CH_4/CO_2值为0.009—0.056,在液相中,l_7矿脉富K~+,l_(17)矿脉的K~+、Na~+相等,其它均为富Na~+型。离子组合及矿化度与岩体一致,矿化度属淡水型。文中还提出了说明矿床成因的地质年龄、化探成果、稳定同位素和流体包裹体成分的依据,补充了找矿评价的硫化物存在、黄铁矿的热电系数和红外谱标志。     

有机磷化合物的NMR研究——Ⅱ0,0-二烷基膦酸酯的1H、13C和31PNMR谱

本文报道了21个0,0一二烷基膦酸酯类化合物的¹H、¹³C和³¹P NMR参数。研究和讨论了不等价的二烷基¹H、¹³C化学位移和磷碳偶合常数与立体化学的关系。测定了(CH₃CH₂O)₂P(O)CH(CH₂NO₂)(p-OCH₃C₆H₄)的¹³C自旋一晶格弛豫时间T₁,二乙基¹³C T₁间的差别,说明在类似化合物中,含有化学位移各向异性对弛豫的贡献。     

New polyphenylene‐g‐polystyrene and polyphenylene‐g‐polystyrene/poly(ε‐caprolactone) copolymers by combined controlled polymerization and cross‐coupling processes

1,4‐Dibromo‐2‐(bromomethyl)benzene and 1,3‐dibromo‐5‐(bromomethyl)benzene were used as initiators in the atom transfer radical polymerization of styrene in conjunction with CuBr/2,2′‐bipyridine as a catalyst. The resulting polystyrene (PSt)‐based macromonomers, possessing at one end a 2,5‐dibromophenylene or 3,5‐dibromophenylene moiety, were used in combination with 2,5‐dihexylbenzene‐1,4‐diboronic acid for Suzuki coupling in the presence of Pd(PPh₃)₄ as a catalyst or with the system NiCl₂/2,2′‐bipyridine/triphenylphosphine/Zn for Yamamoto polymerization. Polyphenylenes (PPs) with PSt chains as substitution groups were obtained. The same macromonomers were used in Yamamoto copolycondensation reactions, in combination with a poly(ε‐caprolactone) (PCL) macromonomer, and this resulted in PPs with PSt/PCL side chains. The obtained PPs had good solubility properties in common organic solvents at room temperature similar to those of the starting macromonomers. The new polymers were characterized with ¹H (¹³C) NMR, IR, and gel permeation chromatography. The optical properties of the polymers were monitored with UV and fluorescence spectroscopy. The thermal behaviors of the macromonomers and final PPs were investigated with differential scanning calorimetry and compared. The morphology of PPs containing PSt and PCL blocks was characterized with atomic force microscopy, and a microphase‐separated layered morphology was observed. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 879–896, 2005     

Preparation of side‐on bisazobenzene‐containing homopolymers and block copolymers via ATRP and studies on their photoisomerization and photoalignment behaviors

The preparation of a series of novel homopolymers and copolymers containing bisazobenzene chromophores with side‐on structure in the side chains via atom transfer radical polymerization (ATRP) were presented. UV–vis spectra of the thin films of these polymers under irradiation of 488 nm Ar⁺ laser suggested that the photoisomerization of the bisazobenzene chromophores happened mainly on one of the two azo groups in the bisazobenzene chromophores with similar probability due to their side‐on structure. Good photoalignment behaviors of these polymers were proved by photoinduced birefringence measurements because side‐on structure permitted the two azo groups in the bisazobenzene chromophores both participated in the trans–cis–trans photoisomerization cycles equally to induce the whole chromophore reorientation. Furthermore, the reorientation axis located at the middle of chromophore decreased the sweep volume during photoalignment. The impetus for this study was to evaluate the photoisomerization and photoalignment process of side‐on bisazobenzene‐containing polymers and to find possible applications in the photosensitive devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3460–3472, 2007     

Effect of phenol and derivatives on atom transfer radical polymerization in the presence of air

The various phenolic compounds in conjunction with Cu(II) or Cu(I)‐N,N,N′,N″,N″‐pentamethyl diethylenetriamine (PMDETA) complexes are used to initiate atom transfer radical polymerization (ATRP) of methyl methacrylate, styrene, and methyl acrylate in the presence of a limited amount of air at temperatures in the range of 80–110 °C. Meanwhile, an effort is directed toward the elucidation of the role of phenol and derivatives in ATRP catalyzed by Cu(II)/PMDETA. The catalytic sequence involves the formation of Cu(I) by electron transfer from phenol to Cu(II); Cu(I) so formed can then react in two distinctly different ways: with organic halide to form a propagating radical or with oxygen to form copper salt in its higher oxidation state; and regeneration of Cu(I) by excess phenol. Such regeneration of Cu(I) would be expected to lead to polymerization as a result of the consumption of oxygen and phenol as well. The phenols with electron releasing groups tended to increase the conversion of the polymerization. In this respect, sodium phenoxide, a more effective additive was found, whereas p‐nitro phenol was the least effective. The obtained polymers displayed the common features of a controlled polymerization such as molecular weight control and low polydispersity index value (M_w/M_n < 1.5). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 351–359, 2004     

双模SU（1,1）相干态场与级联三能级原子相互作用的动力学

讨论了关联双模ＳＵ（１，１）相干态场与级联三能级原子的相互作用对原子动力学行为的影响，也研究了双模场的量广场的量子统计性质随时间的演化。通过数值计算，发现了一些新的演化规律。     

Hyperidentities of some generalizations of lattices

In the paper we present bases and hyperbases of hyperidentities of some generalizations of the variety L of all lattices and the variety D of distributive lattices. We describe the form of hyperidentities of some varieties with two binary operations. Received January 22, 1997; accepted in final form January 7, 1998.     

Phase transitions and reflection positivity for a class of quantum lattice systems

We prove a form of reflection positivity in planes containing sites for a class of quantum lattice systems. As an application, a proof is given of a phase transition for the Fisher-stabilized Ising antiferromagnet in an external magnetic field with parallel and transverse components, both by the method of infrared bounds and by a suitable version of the Peierls argument. We also discuss the spherical model in an appendix.