线性随机桁架结构的平稳随机响应分析

研究了随机桁架结构的平稳随机响应问题。同时考虑结构的物理参数、几何尺寸的随机性，从结构平稳随机响应在频域上的表达式出发，利用求解随机变量函数矩的方法，导出了随机桁架结构在平稳随机激励下位移响应均方值的均值、均方差和变异系数的计算表达式。通过算例考察了随机荷载激励下结构物理参数、几何尺寸的随机性对结构随机响应的影响。     

初始点任意的一个非线性优化的广义梯度投影法

广义投影算法的优点是避免转轴运算。它成功地给出了线性约束问题、初始点任意的只带非线性不等式约束问题，以及利用辅助规划来处理带等式与不等式约束问题的算法．后者完满地解决了投影算法对于非线性等式约束问题的处理，但要求满足不等式约束的初始点．本文据此利用广义投影与罚函数技巧给出了一个初始点任意的等式与不等式约束问题的算法，省去了求初始解的计算，并保持了上述方法的优点，证明了算法的全局收敛性     

蒙特卡罗模拟四极阱中原子的参变激发

在中性原子的磁囚禁实验中,磁阱线圈的电流噪声会激发磁阱中的原子运动,势必对原子团的温度和寿命产生不可忽视的影响。对于非简谐阱,这种激发具有能量选择特性,它又取决于电流噪声的频谱分布。选择了实验中常用的四极阱为研究对象,用直接模拟蒙特卡罗方法来模拟四极阱中原子运动的参变激发现象,得到了原子温度与原子数损失随激发频率的变化关系,并进一步计算了两个共振峰处原子温度随调制时间和调制深度的变化曲线。此外,还研究了弹性碰撞速率对参变激发过程中原子温度上升的影响。这些结果对四极阱参变激发的实验有较好的参考价值。     

介孔分子筛Al-MCM-41的合成与催化异构化性能

采用正硅酸乙酯(TEOS)为硅源,九水硝酸铝为铝源,十六烷基三甲基溴化胺(CTMABr)为模板剂,在室温条件下合成了介孔Al-MCM-41分子筛.通过XRD、N2等温吸附、SEM、FTIR等分析测试手段表征了分子筛的介孔结构和表面性质.结果表明所合成的分子筛有良好的介孔结构和较高的有序度,并且有较高的比表面积(达到816 m2·g-1)和窄的孔径分布.采用程序升温的焙烧方式、凝胶Al/Si比最大范围控制在0.06～0.13有利于合成高度有序的介孔Al-MCM-41分子筛.评价结果表明,所合成的Al-MCM-41分子筛对桥式四氢双环戊二烯(endo-TCD)异构化反应合成挂式异构体exo-TCD及金刚烷具有较高的催化活性和极高的选择性.     

任意维欧氏空间的长程势多极展开

给出了在任意维欧氏空间中一个一般的长程相互作用势的多极展开结果,并推导得到了单极子和偶极子两两之间的相互作用力公式.     

Asynchronous sampling for ultrafast experiments with low momentum compaction at the ANKA ring

A high‐repetition‐rate pump–probe experiment is presented, based on the asynchronous sampling approach. The low‐α mode at the synchrotron ANKA can be used for a time resolution down to the picosecond limit for the time‐domain sampling of the coherent THz emission as well as for hard X‐ray pump–probe experiments, which probe structural dynamics in the condensed phase. It is shown that a synchronization of better than 1 ps is achieved, and examples of phonon dynamics of semiconductors are presented.     

Crystal Structure and Mass-, Electronic-, Infrared Spectral Studies on Hexaaqua Ni(II) Bis(O-Tolylazo-Citrazinate) Hexahydrate Complex

A new crystalline octahedral hexaaqua Ni(II) bis(o-tolylazo-citrazinate)hexahydrate complex was synthesized. The analytical data proved the formation of 1:2 stoichiometry. An X-ray structure investigation has been carried out. The triclinic space group is p and the unit cell parameters are a = 585.5 pm, b = 993 pm, c = 1139.4 pm, α = 101.6°, β = 97.4°, γ = 102.4°. Evaluation of intensity data revealed the structure with an R-value of 0.03 (2316 observed independent reflections). The compound consists of hexaaqua nickel(2+) ions, univalent anions of the carboxylic acid and six additional water molecules per     

Analysis of the composition and structure of aqueous media under excitation by lasers and light emitting diodes

We developed a method for detecting traces of foreign components in water and analyzing the microstructure of water. The method is based on studies of the characteristics of secondary emission arising in aqueous media under excitation by radiation of ultraviolet lasers and light emitting diodes. A new type of cuvette (capillary cuvettes) for studying the secondary emission in molecular media was elaborated. The cuvettes enable the study of aqueous solutions at small concentrations of the components; they enable one to recognize the type of molecular compound present in aqueous media, in view of the photoluminescence spectra.     

X-ray diffraction in AT-cut quartz single crystal at acoustic excitation at the fundamental frequency

X-ray diffraction on different atomic planes of an AT-cut quartz crystal is studied experimentally in the Laue geometry in case of excitation by acoustic waves at the first resonant (fundamental) frequency. Acoustic waves lead to an increase in the integral intensity of the reflection-diffracted beam. The amplification coefficients in reflection are measured in dependence on the amplitude of a.c. voltage applied to the crystal at the resonant frequency. The frontal distributions of the intensity of the beam diffracted in the reflection direction are obtained for different atomic planes.