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21.
    
We study a stochastic particle system which is motivated from grain boundary coarsening in two-dimensional networks. Each particles lives on the positive real line and is labeled as belonging to either Species 1 or Species 2. Species 1 particles drift at unit speed toward the origin, while Species 2 particles do not move. When a particle in Species 1 hits the origin, it is removed, and a randomly selected particle mutates from Species 2 to Species 1. The process described is an example of a high-dimensional piecewise deterministic Markov process (PDMP), in which deterministic flow is punctuated with stochastic jumps. Our main result is a proof of exponential concentration inequalities of the Kolmogorov-Smirnoff distance between empirical measures of the particle system and solutions of limiting nonlinear kinetic equations. Our method of proof involves a time and space discretization of the kinetic equations, which we compare with the particle system to derive recurrence inequalities for comparing total numbers in small intervals. To show these recurrences occur with high probability, we appeal to a state dependent Hoeffding type inequality at each time increment.  相似文献   
22.
In this paper we derive a model for the evolution of the particle radius density for a system of many particles that evolve according to the Mullins–Sekerka problem. The derived model is a correction of the classical LSW theory that takes the effect of the fluctuations of the particle density into account. The main difference between the model derived in this paper and the classical LSW theory is the presence of a second order term which yields a boundary layer effect for large particles. In particular this model provides a possible solution for the so-called “selection problem” in the LSW theory.  相似文献   
23.
When precipitates grow with a lattice misfit inside a matrix having cubic crystal symmetry, a transition may occur from an isotropic arrangement of the precipitates to an alignment along the cubic directions of the crystal. Furthermore, if a uniaxial external strain is applied, an additional transition towards tetragonal symmetry can occur by fusion of the precipitates into large plates perpendicular (or long rods parallel) to the direction of applied strain (“rafting”). Recent experiments on Ni-Al-Mo alloys as well as computer simulations relating to these two transitions are reviewed.  相似文献   
24.
    
Based on first-principles calculations, we identify a two-stage process for the rotation of Sb ad-dimer on Si(001). The bond between Sb and Si, which is broken over transition states in the rotation pathway, undergoes changes from bonding to bonding near the transition states. Being close to the Fermi level, these states are sensitive to an external electric field, and thus may play a role in understanding the reversible rotation of the Sb ad-dimer between two orthogonal orientated states on Si(001) observed by scanning tunneling microscopy. https://doi.org/10.1209/0295-5075/86/36003  相似文献   
25.
    
We use the first-principles total-energy method within density functional theory (DFT) to study the energetic and kinetic properties of the initial stages of growth of Ti on a diamond(100) 2×1 surface. For a Ti adatom, the pedestal site at the center of two consecutive C dimers is the most stable adsorption site. As the coverage increases, the most stable adsorption sites change from pedestal to hollow sites. We predict the existence of two well-defined diffusion pathways of Ti atoms at half monolayer coverage, and identify the kinetic pathways through which the metastale site converts into the stable configuration.https://doi.org/10.1209/0295-5075/92/46005  相似文献   
26.
We study the convergence rate of multilevel algorithms from an algebraic point of view. This requires a detailed analysis of the constant in the strengthened Cauchy–Schwarz inequality between the coarse‐grid space and a so‐called complementary space. This complementary space may be spanned by standard hierarchical basis functions, prewavelets or generalized prewavelets. Using generalized prewavelets, we are able to derive a constant in the strengthened Cauchy–Schwarz inequality which is less than 0.31 for the L2 and H1 bilinear form. This implies a convergence rate less than 0.15. So, we are able to prove fast multilevel convergence. Furthermore, we obtain robust estimations of the convergence rate for a large class of anisotropic ellipic equations, even for some that are not H1‐elliptic. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
27.
Predominantly two kinds of antiphase boundaries (APBs) form in Al5Ti3, which is an Al-rich ordered derivative of the γ-TiAl (L10) phase. This phase can be viewed as a periodic arrangement of lean rhombs and squares on the Ti-rich (002) planes of the tetragonal L10. Energies of the two types of APBs were varied in a Monte Carlo simulation by suitably changing the pair interaction parameters. APBs of both types form boundaries of Al5Ti3 antiphase domains (APDs), which coarsen with time. An important observation in this regard is that mostly facetted APBs form at lower ageing temperatures, whereas curved APBs appear to form at relatively higher ageing temperatures. The findings of this work suggest that there exists a critical temperature, akin to the roughening transition temperature for crystals, that marks the transition from facetted to curved APBs.  相似文献   
28.
29.
    
This combined study using small‐angle neutron scattering (SANS), X‐ray powder diffraction (XRPD), transmission electron microscopy (TEM) and adsorption isotherm techniques demonstrates radical changes in the microstructure of porous hematite (α‐Fe2O3) nanoparticles upon calcination in air. TEM images of the as‐synthesized hematite sample show that it consists of subrounded nanoparticles [50 (8)–61 (11) nm in average minimum and maximum diameters] with an apparent porous structure of nanosized pores/channels or cracks. SANS data confirm the presence of two characteristic sizes, one originating from the particle size and the other from the pore/void structure. Furthermore, the TEM images show that the particle sizes are nearly unaffected by calcination at 623 K, whereas their pore/void structure changes radically to an apparently pitted or spongy microstructure with cavities or/and voids. The change in microstructure also causes a reduction in the surface area as calculated by gaseous adsorption. The XRPD and SANS data show that the crystallite and SANS particle sizes are virtually unchanged by calcination at 623 K. Calcination at 973 K induces a significant alteration of the sample. The XRPD data reveal that the crystallite size increases significantly, and the SANS and adsorption isotherm studies suggest that the specific surface area decreases by a factor of ∼5–6. The TEM images show that the particles are sintered into larger agglomerates, but they also show that parts of the porous microstructure observed in the sample calcined at 623 K are retained in the sample calcined at 973 K.  相似文献   
30.
    
This article studies the quiescent annealing of three different cocontinuous polystyrene/high‐density polyethylene blends modified with two types of interfacial agents of widely different efficacies. Quantitative analysis of phase growth was obtained using mercury porosimetry. In a previous work, it was shown that one of these modifiers, a symmetrical diblock copolymer, has a high affinity for the interface and demonstrates virtually no micelle formation prior to saturation of the blend interface. The other modifier, a hydrogenated SEBS of 70/30 composition, forms micelles at elevated concentrations of modifier. In this study, it is shown that the cocontinuous phase size grows linearly without modifier, whereas the addition of both interfacial modifiers significantly suppresses the PE/PS phase coarsening and results in nonlinear phase growth behavior. The effect of the diblock copolymer on suppressing coarsening, however, is much more effective than that for the triblock case clearly supporting the tendency toward micelle formation for that latter modifier. In the case of unmodified PE/PS, the driving force for capillary pressure effects is so high that it is the capillary instability phenomena that dominate the coarsening and hence result in a linear growth of pore size with annealing time. When interfacial modifiers are added, the influence of reduced interfacial tension and lower pore size polydispersity significantly diminishes both capillary pressure effects and capillary instability phenomena. In that case, capillary pressure becomes the main rate determining step resulting in a nonlinear dependence of pore size with annealing time. It is shown that both the viscosity of the phases and the temperature of annealing can strongly influence coarsening behavior at low levels of interfacial modifier. Under all those conditions, however, nonlinear phase growth for the partially compatibilized system was maintained. These results clearly show that careful quantitative coarsening experiments using mercury porosimetry can be used as a tool to analyze the efficacy of interfacial modifiers for highly continuous or cocontinuous systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 711–721, 2006  相似文献   
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