Thallium(III) coordination compounds: chemical information from 205Tl NMR longitudinal relaxation times

²⁰⁵Tl longitudinal relaxation rate measurements were performed on several thallium(III) complexes with the composition Tl(OH)_n(H₂O)_6?n^(3?n)+ (n = 1,2), Tl(Cl)_n(H₂O)_m?n^(3?n)+, Tl(Br)_n(H₂O)_m?n^(3?n)+ (m = 6 for n = 1–2, m = 5 for n = 3, m = 4 for n = 4), Tl(CN)_n(H₂O)_m?n^(3?n)+ (m = 6 for n = 1–2, m = 4 for n = 3–4) in aqueous solution, at different magnetic fields and temperatures. ¹³C and ²D isotopic labelling and ¹H decoupling experiments showed that the contribution of the dipolar relaxation path is negligible. The less symmetric lower complexes (n < 4) had faster relaxation rate dominantly via chemical shift anisotropy contribution which depended on the applied magnetic field: T₁ values are between 20 and 100 ms at 9.4 T and the shift anisotropy is Δσ = 1000–2000 ppm. The tetrahedral complexes, n = 4, relax slower; their T₁ is longer than 1 s and the spin–rotation mechanism is probably the dominant relaxation path as showed by a temperature dependence study. In the case of the TlCl₄^? complex, presumably a trace amount of TlCl₅^2? causes a large CSA contribution, 300 ppm. Since the geometry and the bond length for the complexes in solution are known from EXAFS data, it was possible to establish a correlation between the CSA parameter and the symmetry of the complexes. The relaxation behaviour of the Tl–bromo complexes is not in accordance with any known relaxation mechanism. Copyright © 2002 John Wiley & Sons, Ltd.     

Metric generalized inverse for linear manifolds and extremal solutions of linear inclusion in Banach spaces

Let X,Y be Banach spaces and M a linear manifold in X×Y={{x,y}∣x∈X,y∈Y}. The central problem which motivates many of the concepts and results of this paper is the problem of characterization and construction of all extremal solutions of a linear inclusion y∈M(x). First of all, concept of metric operator parts and metric generalized inverses for linear manifolds are introduced and investigated, and then, characterizations of the set of all extremal or least extremal solutions in terms of metric operator parts and metric generalized inverses of linear manifolds are given by the methods of geometry of Banach spaces. The principal tool in this paper is the generalized orthogonal decomposition theorem in Banach spaces.     

The analytical solution and the complete electronic structure of quantum well

With a detailed analysis of the Bloch wave properties of one-dimensional infinite crystal, we find the exact analytical solution of the quantum confinement states in quantum well with infinite barrier. Based on the analytical solution, we calculate the complete electronic structure of quantum well with arbitrary geometries. The calculation results demonstrate that the transitions only occur between specific pairs of sub-bands. It also shows that the band edge state plays an insignificant role in the optical properties, although it is the most distinguishing feature of the quantum well.     

一类二阶三点非齐次边值问题正解的存在性

本文讨论了一类二阶三点非齐次边值问题正解的存在性。利用Schander不动点定理，得到了正解的一个存在性结果     

Phase behavior study of poly(N‐tertbutylacrylamide‐co‐acrylamide) in the mixture of water–methanol: The role of polymer–nonsolvent second‐order interactions

The phase behavior of poly(N‐tertbutylacrylamide‐co‐acrylamide) (PNTBAM) in pure water and mixture of water–methanol is studied at different temperatures. The different compositions of PNTBAM are prepared by free‐radical polymerization technique and their phase behavior is studied by turbidimetry. The effects of copolymer and solvent composition on the phase behavior of the copolymers are discussed. It has been suggested that the inhomogenities in polymer chains are responsible for lowering the rate of phase transition by increasing the N‐tertbutylacrylamide (NTBAM) and methanol contents in copolymer and mixture, respectively. For the first time we have revealed that there are second‐order binary interactions in the water–methanol which are dominant in the special range of copolymer composition. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 455–462, 2009     

Enthalpies of solution oft-butyl chloride and bromide and carbon tetrachloride and tetrabromide in alcohols

Standard enthalpies of solution of t-BuX and CX₄ (X=Cl and Br) in several alcohols are reported as measured by a calorimetric method. The corresponding transfer functions from the gas phase were calculated.     

New Exact Solutions of the N-Coupled Nonlinear Schroedinger System

In this letter, abundant families of Jacobi elliptic function envelope solutions of the N-coupled nonlinear Schroedinger （NLS） system are obtained directly. When the modulus m → 1, those periodic solutions degenerate as the corresponding envelope soliton solutions, envelope shock wave solutions. Especially, for the 3-coupled NLS system, five types of Jacobi elliptic function envelope solutions are illustrated both analytically and graphically. Two types of those degenerate as envelope soliton solutions.     

梁受正弦分布压力作用的解析解

对梁受正弦分布压力作用的情况，本文以矩形截面简支梁为例，通过构造满足所有边界条件和双调和方程的应力函数给出了相应的解析解，这为求解梁受任意分布压力作用的解的问题打下了基础。     

关于不定方程组x-1=3py^2，x^2＋x＋1=3z^2

设P为素数，利用同余及高次丢番图方程的一些结果证明了不定方程组x-1=3py^2，x^2＋x＋1=3z^2仅有正整数解（p，x，y，z）=（7，22，1，13）。