全文获取类型
收费全文 | 6640篇 |
免费 | 1142篇 |
国内免费 | 400篇 |
专业分类
化学 | 2019篇 |
晶体学 | 36篇 |
力学 | 492篇 |
综合类 | 236篇 |
数学 | 2231篇 |
物理学 | 3168篇 |
出版年
2024年 | 21篇 |
2023年 | 115篇 |
2022年 | 382篇 |
2021年 | 347篇 |
2020年 | 224篇 |
2019年 | 175篇 |
2018年 | 139篇 |
2017年 | 280篇 |
2016年 | 333篇 |
2015年 | 263篇 |
2014年 | 448篇 |
2013年 | 538篇 |
2012年 | 432篇 |
2011年 | 423篇 |
2010年 | 377篇 |
2009年 | 434篇 |
2008年 | 397篇 |
2007年 | 417篇 |
2006年 | 350篇 |
2005年 | 253篇 |
2004年 | 211篇 |
2003年 | 221篇 |
2002年 | 214篇 |
2001年 | 167篇 |
2000年 | 175篇 |
1999年 | 139篇 |
1998年 | 120篇 |
1997年 | 104篇 |
1996年 | 100篇 |
1995年 | 53篇 |
1994年 | 65篇 |
1993年 | 63篇 |
1992年 | 30篇 |
1991年 | 27篇 |
1990年 | 28篇 |
1989年 | 15篇 |
1988年 | 14篇 |
1987年 | 9篇 |
1986年 | 19篇 |
1985年 | 16篇 |
1984年 | 13篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1977年 | 5篇 |
1975年 | 1篇 |
1972年 | 1篇 |
1967年 | 1篇 |
1959年 | 4篇 |
排序方式: 共有8182条查询结果,搜索用时 46 毫秒
241.
242.
针对认知无线电网络(CRN)中空闲频谱感知困难的问题,本文提出了基于前向纠错和差分进化算法的多节点频谱感知算法。首先,利用基于差分进化算法的协同检测完成信号感知;然后,研究了信道噪声对频谱感知性能的影响;最后,分析了前向纠错技术在信道存在噪声时对频谱感知性能的影响。仿真实验将纠错和无纠错控制信道的不同信噪比作为依据,采用三种不同的检测方法评估了本文算法。仿真实验结果表明,在存在噪声的认知无线电网络中,本文算法提高了系统的性能和检测概率,且协同感知算法的性能随着节点数目的增加而提高,该算法适合应用于实时性要求较高的应用程序。 相似文献
243.
为了实现包括服务端和客户端的一套简单、稳定、可靠的新型视频监控系统。首先分析了视频监控系统的发展历史和趋势,提出基于移动互联网的视频监控系统方案,并选定Android作为系统实现的平台;明确了需求和目标,设计出系统的整体方案,并搭建了系统的程序框架;再根据系统程序框架的设计,详细地设计并实现了各个子功能模块,其中主要的功能模块有视频采集与视频回显模块,视频预处理模块,视频编解码模块和视频存储模块等;最后,对整个系统进行了综合测试,验证了其功能的完整性,得出系统的性能表现数据。经实验证明,所设计系统使用便利,需求中指定的功能也基本实现,程序的运行稳定高效可靠,能达到预期效果,具有一定的实用性和研究意义。 相似文献
244.
旨在研究无线传感器与执行器网络(WSANs)中节点失效情况下恢复执行器(actor)节点服务的算法. 首先说明了WSANs中的实时覆盖模型, 证明WSANs覆盖恢复问题是NP难问题, 给出了近似求解方案. 在此基础上, 提出了一种基于六边形蜂巢结构的移动容错算法HMFR用于恢复失效actor节点, HMFR 算法在限制网络初始部署的条件下拥有很好的性能. 通过实验与现有的恢复算法进行比较, 发现HMFR算法在actor覆盖sensor节点数和移动距离方面有更好的性能. 相似文献
245.
以电耦合的Terman-Wang小世界神经元网络系统为研究对象, 研究了空间关联白噪声影响下神经元网络系统的同步动力学. 首先将动力学平均场近似理论扩展到受空间关联白噪声影响下的小世界网络系统中, 将描述网络系统动力学演化的2N维随机微分方程简化为11个确定性的矩微分方程. 其次, 基于动力学平均场近似理论所推导的矩方程, 讨论了空间关联噪声、网络结构参数对神经元网络系统同步动力学的关键影响, 发现较大的噪声空间关联系数、耦合强度及节点平均度均对神经元网络系统同步放电具有积极作用. 进一步地, 利用计算机仿真数值模拟原神经元网络系统的同步动力学, 并与基于动力学平均场近似理论所得到的结果进行比较, 发现二者具有较好的一致性. 相似文献
246.
To realize practical wide-area quantum communication,a satellite-to-ground network with partially entangled states is developed in this paper.For efficiency and security reasons,the existing method of quantum communication in distributed wireless quantum networks with partially entangled states cannot be applied directly to the proposed quantum network.Based on this point,an efficient and secure quantum communication scheme with partially entangled states is presented.In our scheme,the source node performs teleportation only after an end-to-end entangled state has been established by entanglement swapping with partially entangled states.Thus,the security of quantum communication is guaranteed.The destination node recovers the transmitted quantum bit with the help of an auxiliary quantum bit and specially defined unitary matrices.Detailed calculations and simulation analyses show that the probability of successfully transferring a quantum bit in the presented scheme is high.In addition,the auxiliary quantum bit provides a heralded mechanism for successful communication.Based on the critical components that are presented in this article an efficient,secure,and practical wide-area quantum communication can be achieved. 相似文献
247.
The nonlinear properties of lattice network-based(LNB) composite right-/left-handed transmission lines(CRLH TLs)with nonlinear capacitors are experimentally investigated.Harmonic generation,subharmonic generation,and parametric excitation are clearly observed in an unbalanced LNB CRLH TL separately.While the balanced design of the novel nonlinear TL shows that the subharmonic generation and parametric processes can be suppressed,and almost the same power level of the higher harmonics can be achieved over a wide bandwidth range,which are difficult to find in conventional CRLH TLs. 相似文献
248.
Shady Farah Oren Aviv Natalia Laout Stanislav Ratner Nurit Beyth Abraham J. Domb 《先进技术聚合物》2014,25(6):689-692
Silica particles functionalized with quaternary ammonium groups were prepared by interpenetrating polyethylenimine (PEI) into silica particles and crosslinking with diiodopentane, followed by octyliodide alkylation and methyliodide quaternarization (S‐QA‐PEI). The synthesized S‐QA‐PEI particles were identified with a slight particle size increase of 2–3 µm. Different ratios of PEI:silica particles were prepared and analyzed. While silica particles are negatively charged, ?16.7 ± 5.11 mV, the prepared S‐QA‐PEI particles are positively charged, +50–60 mV. These particles were embedded in poly(ethylene vinyl acetate) and poly(ethylene methacrylic acid) coatings which exhibited strong antibacterial activity. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
249.
Effect of Protic Ionic Liquid and Surfactant Structure on Partitioning of Polyoxyethylene Non‐ionic Surfactants
下载免费PDF全文
![点击此处可从《Chemphyschem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Inga L. Topolnicki Dr. Paul A. FitzGerald Prof. Rob Atkin Prof. Gregory G. Warr 《Chemphyschem》2014,15(12):2485-2489
The partitioning constants and Gibbs free energies of transfer of poly(oxyethylene) n‐alkyl ethers between dodecane and the protic ionic liquids (ILs) ethylammonium nitrate (EAN) and propylammonium nitrate (PAN) are determined. EAN and PAN have a sponge‐like nanostructure that consists of interpenetrating charged and apolar domains. This study reveals that the ILs solvate the hydrophobic and hydrophilic parts of the amphiphiles differently. The ethoxy groups are dissolved in the polar region of both ILs by means of hydrogen bonds. The environment is remarkably water‐like and, as in water, the solubility of the ethoxy groups in EAN decreases on warming, which underscores the critical role of the IL hydrogen‐bond network for solubility. In contrast, amphiphile alkyl chains are not preferentially solvated by the charged or uncharged regions of the ILs. Rather, they experience an average IL composition and, as a result, partitioning from dodecane into the IL increases as the cation alkyl chain is lengthened from ethyl to propyl, because the IL apolar volume fraction increases. Together, these results show that surfactant dissolution in ILs is related to structural compatibility between the head or tail group and the IL nanostructure. Thus, these partitioning studies reveal parameters for the effective molecular design of surfactants in ILs. 相似文献
250.
A new Gd coordination polymer based on 2-(pyridin-4-yl)-I H-imidazole-4,5-dicarboxylate (H3PIDC) has been synthesized under hydrothermal conditions, formulated as {[Gd3(HPIDC)3(PIDC)(H2O)4].3H2O}n (1). The compound crystallizes in the monoclinic system, space group C2/c with a=20.951(7), b = 9.515(3), c = 27.483(10) A,β= 106.176(6)°, Z = 4, V= 5262(3) A3, C40 H45 Gd3 N12 O30, Dc = 2.071 g/cm3, Mr=1645.63, λ (MoKa)=0.71073A, μ=3.846mm-1, F(000)=3204, the final R=0.0390 and wR= 0.1332. Complex 1 is a two-dimensional MOF built up from T-shaped 3-connected HPIDC2 , PIDC3 and 4-connected metal nodes. Dielectric constant of complex 1 was measured at different frequencies with temperature variation. 相似文献