Effect of Deuteration on Quasiline Electronic‐Vibrational Spectra of Phthalocyanine

Quasiline electronicvibrational spectra of fluorescence and absorption (excitation of fluorescence in selective recording) of the molecules of phthalocyanine deuterated around the periphery of benzene rings (H₂Phcd ₁₆) and the center of the macrocycle (D₂Phc) are obtained. The vibrational frequencies of the ground state are almost insensitive to this deuteration (except for vibrations with the participation of angular deformations). In excitation spectra, changes in deuteration are more pronounced due to the effects of nonadiabatic vibronic interaction of the vibrational sublevels of the S ₁ state and of the purely electronic level S ₂.     

Convexity of Nonlinear Image of a Small Ball with Applications to Optimization

Let f: XY be a nonlinear differentiable map, X,Y are Hilbert spaces, B(a,r) is a ball in X with a center a and radius r. Suppose f (x) is Lipschitz in B(a,r) with Lipschitz constant L and f (a) is a surjection: f (a)X=Y; this implies the existence of >0 such that f (a)^* yy, yY. Then, if r,/(2L), the image F=f(B(a,)) of the ball B(a,) is convex. This result has numerous applications in optimization and control. First, duality theory holds for nonconvex mathematical programming problems with extra constraint x–a. Special effective algorithms for such optimization problems can be constructed as well. Second, the reachability set for small power control is convex. This leads to various results in optimal control.     

Applications of SMP Bounds to Multi-class Traffic in High-speed Networks

In this paper, we consider the stochastic fluid-flow model of a single node in a high-speed telecommunication network handling multi-class traffic. The node has multiple buffers, one for each class of traffic. The contents of these buffers are multiplexed onto a single output channel using one of the service scheduling policies: the Timed Round Robin Policy or the Static Priority Service Policy. The Quality of Service requirements for each class are based on cell loss probabilities. Using effective bandwidth methodologies and the recently developed bounds for semi-Markov modulated traffic, we solve call admission control problems for the two service scheduling policies at this node. We compare the performance of the effective bandwidth methodologies and the SMP bounds technique. We also numerically compare the performance of the two service scheduling policies.     

A unified framework for pull control mechanisms in multi‐stage manufacturing systems

This paper presents a unified framework for pull production control mechanisms in multistage manufacturing systems. A pull production control mechanism in a multistage manufacturing system is a mechanism that coordinates the release of parts into each stage of the system with the arrival of customer demands for final products. Four basic pull production control mechanisms are presented: Base Stock, Kanban, Generalized Kanban, and Extended Kanban. It is argued that on top of any of these basic coordination mechanisms, a local mechanism to control the workinprocess in each stage may be superimposed. Several cases of basic stage coordination mechanisms with stage workinprocess control are presented, and several production control systems that have appeared in the literature are shown to be equivalent to some of these cases.     

Time-optimal control of a parabolic system with time lags given in the integral form

In this paper the time-optimal control problem for a distributedparabolic system in which time lags appear in the integral formboth in the state equation and in the boundary condition ispresented. The particular properties of the optimal controlare discussed.     

用等效网络方法求均匀弹簧纵振动的本征频率

利用机电类比方法导出了均匀质量弹簧在几种特定边界条件下的本征频率方程,并给出了相应的本征频率公式。体现了等效网络理论分析机械振动问题的优越性。     

Langford系统Hopf分叉的线性反馈控制

分析Langford系统的Hopf分叉现象，并研究采用线性反馈控制方法控制该系统的Hopf分叉.从理论上推导出受控系统产生Hopf分叉的条件，给出了某些极限环的解析表达式，对该系统进行了分叉点的转移与极限环的稳定性控制.数值模拟说明本文采用的方法对Langford系统的Hopf分叉控制是有效的. 关键词： Langford系统 反馈控制 Hopf分叉 极限环     

飞秒激光控制的量子分子动力学研究——多维三能级系统

结合MCTDH方法和优化控制理论，以具有三个电子能级，三个振动自由度的吡嗪分子为例，模拟了优化飞秒激光作用下的量子分子动力学过程. 在对多维两能级系统的优化控制模拟的基础上，以三能级中的两个激发态为目标态，考虑了不同的目标态对多维系统量子动力学过程的影响. 关键词： 飞秒激光控制 MCTDH 方法 量子分子动力学     

一类参数不确定统一混沌系统的脉冲滞后同步

针对一类具有传输信道时间延迟且参数不确定的统一混沌系统，提出了一种脉冲控制同步方法.该方法将两个非自治混沌系统之间脉冲同步的实用稳定性问题转化为同步误差系统在原点的实用稳定性问题，基于脉冲微分方程的相关理论，给出了同步误差系统在原点的实用稳定判据，仿真结果验证了方法的有效性. 关键词： 统一混沌系统 混沌同步 脉冲控制 实用稳定性     

随机Bonhoeffer-Van der Pol系统的随机混沌控制

讨论了具有有界随机参数的随机Bonhoeffer-Van der Pol系统的随机混沌现象，并利用噪声对其进行控制.首先运用Chebyshev多项式逼近的方法，将随机Bonhoeffer-Van der Pol系统转化为等价的确定性系统，使原系统的随机混沌控制问题转换为等价的确定性系统的确定性混沌控制问题，继而可用Lyapunov指数指标来研究等价确定性系统的确定性混沌现象和控制问题.数值结果表明，随机Bonhoeffer-Van der Pol系统的随机混沌现象与相应的确定性Bonhoeffer-Van der Pol系统极为相似.利用噪声控制法可将混沌控制到周期轨道，但是在随机参数及其强度的影响下也呈现出一些特点.