分光光度法研究在氯化钠-四丁基溴化铵体系中Au(Ⅲ)与U(Ⅵ)、Ce(Ⅲ)、Mg(Ⅱ)和Cu(Ⅱ)的浮选分离

用分光光度法研究了氯化钠和四丁基溴化铵浮选分离金的行为及与一些金属离子分离的条件。结果表明,当溶液中氯化钠和四丁基溴化铵的浓度分别为2.5×10-3mol/L和4.0×10-4mol/L,pH3.0时,Au(Ⅲ)可与U(Ⅵ)、Ce(Ⅲ)、Mg(Ⅱ)和Cu(Ⅱ)离子定量分离,对合成水样中Au(Ⅲ)的分离和测定,结果满意。     

以(NH_4)_2Ce(NO_3)_6氧化体系合成己二酰-1′,6′-双(4-卤偶氮苯)

以自制的己二酰-1′,6′-双(4-卤苯肼)化合物为原料,在室温条件下用(NH4)2Ce(NO3)6氧化体系氧化脱氢得3种己二酰-1′,6′-双(4-卤偶氮苯)化合物。产品的结构经元素分析、IR、1H NMR确证。产率在89%—93%之间。     

浙产山胡椒根挥发油化学成分的研究

采用水蒸汽蒸馏法提取挥发油,气相色谱-质谱联用法结合计算机检索对浙产山胡椒根挥发油的化学成分进行分析和鉴定,用气相色谱面积归一法计算各组分的相对百分含量。从山胡椒根的挥发油中,分析并鉴定出17种化合物。主要含1,2,3,3a,4,5,6,7-八氢-1,4-二甲基-7-(1-甲基乙烯基)-奥艹、4,6,6-三甲基-2-(3-甲基-1,3-丁二烯基)-3-氧杂环-辛烷、愈创木醇、1,2,3,5,6,7,8,8a-八氢-1,4-二甲基-7-(1-甲基乙烯基)-奥艹,它们占挥发油总量的84.75%。     

高效液相色谱-串联质谱法测定动物血浆中罗匹尼罗的浓度

建立高效液相色谱-串联质谱(LC-MS/MS)测定动物血浆中罗匹尼罗浓度的方法。血浆经乙酸乙酯萃取后,以HPLC分离,电喷雾离子化(ESI~+)串联质谱检测。以甲醇-乙腈-0.1‰冰醋酸(36:9:55)为流动相,流速为0.2mL·min~(-1),采用Ultimate XB-C 18柱(150mm×2.1mm,3μm)分离,在三级四极杆串联质谱中经电喷雾电离源(ESI)离子化,以多反应监测(MRM)方式进行检测。盐酸罗匹尼罗、盐酸苯海拉明(内标)的扫描离子对m/Z分别为261→114和m/Z 256→167。LC-MS/MS测定血浆中罗匹尼罗线性范围为0.02—400ng·mL~(-1),范围内线性关系良好(r=0.9998);以3个浓度水平的质量控制样品求得各浓度水平日内、日间精密度(RSD)均小于15.2%。在非临床药代动力学研究中,应用此法测定了受试兔子血浆中罗匹尼罗的浓度。该法灵敏、快速、准确,操作简便,样品处理方便,线性范围宽,该方法检测快速、专一、灵敏,可满足罗匹尼罗临床前药代动力学研究和临床药动学研究的要求。     

Quantum Secure Direct Communication and Quantum Sealed-Bid Auction with EPR Pairs

I present a new protocol for three-party quantum secure direct communication （QSDC） with a set of ordered M Einstein-Podolsky-Rosen （EPR） pairs. In the scheme, by performing two unitary operations and Bell state measurements, it is shown that the three legitimate parties can exchange their respective secret message simultaneously. Then I modify it for an experimentally feasible and secure quantum sealed-bid auction （QSBD） protocol. Furthermore, I also analyze th~ecurity of the protocol, and the scheme is proven to be secure against the intercept-and-resend attack, the disturbancb attack and the entangled-and-measure attack.     

Exact Solutions of （2＋1）-Dimensional HNLS Equation

In this paper, we use the classical Lie group symmetry method to get the Lie point symmetries of the （2＋1）-dimensional hyperbolic nonlinear Schr6dinger （HNLS） equation and reduce the （2＋1）-dimensional HNLS equation to some （1 ＋ 1 ）-dimensional partial differential systems. Finally, many exact travelling solutions of the （2＋1）-dimensional HNLS equation are obtained by the classical Lie symmetry reduced method.     

Experimental investigation of the relativistic backward wave oscillator with a periodic guiding magnetic field

Experiment is carried out on the accelerator Sinus-700 to investigate the Relativistic Backward Wave Oscillator （RBWO） with a periodic guiding magnetic field. When the strength of the guiding magnetic field, whose period is 4.6 cm, is 0.54 T, a microwave output power of 0.95 GW at 9.1 GHz microwave frequency is achieved. It is shown that the RBWO with a periodic guiding magnetic field is feasible.     

Lepton-number-violating decays of singly-charged Higgs bosons in the type-（Ⅰ＋Ⅱ ） seesaw model

The lepton-number-violating decays of singly-charged Higgs bosons H^± are investigated in the minimal type-（ Ⅰ＋Ⅱ ） seesaw model with one SU（2）L Higgs triplet △ and one heavy Majorana neutrino N1 at the TeV scale. We find that the branching ratios B（H^＋ → 1α^＋υ^-） （for α = e,μ,τ） depend not only on the mass and mixing parameters of three light neutrinos υi （for i = 1, 2, 3） but also on those of N1. Assuming that the mass of N1 lies in the range of 200 GeV to 1 TeV, we figure out the generous interference bands for the contributions of υi and N1 to B（H^＋→ 1α^＋υ^-）. We illustrate some salient features of such interference effects by considering three typical mass patterns of υi, and show that the relevant Majorana CP-violating phases can affect the magnitudes of B（H^＋→ 1α^＋υ^-）） in this parameter region.     

Systematic studies on α-decay half-lives for super heavy nuclei

Radioactive decay of super heavy nuclei via the emission of α-particles has been studied theoretically in the preformed cluster model （PCM）. The nucleus-nucleus （NN） potential is obtained by double folding the density distributions of the α-particle and the daughter nucleus with a realistic effective interaction. The M3Y effective interaction, supplemented by a zero-range pseudo-potential for exchange term, is used to calculate the NN potential. The α decay half-lives for 317 nuclei at Z=102 120 are performed in the PCM framework with the theoretical Q values extracted from the MSller-Nix-Kratz and Liran-Marinov-Zeldes mass tables and are compared with the experimental data. The calculated results are also compared with those obtained by using Q values from the Muntian-Hofmann-Patyk-Sobiczewski and Myers-Swiatecki mass estimates.     

Analysis of the coupling constants ga0ηπ0 and ga0η＇ π0 with light-cone QCD sum rules

In this article, we take the point of view that the light scalar meson a0（980） is a conventional qqstate, and calculate the coupling constants ga0ηπ0 and ga0ηπ0 with the light-cone QCD sum rules. The central value of the coupling constant ga0ηπ0 is consistent with that extracted from the radiative decay φ（1020） → a0（980）γ→ηπ0γ. The central value and lower bound of the decay width Γa0→ηπ0 =127＋8448 MeV are compatible with the experimental data of the total decay width Γa0（980） = （50-100） MeV from the Particle Data Group with a very model dependent estimation （the decay width can be much larger）, while the upper bound is too large. We give a possible explanation for the discrepancy between the theoretical calculation and experimental data.