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排序方式: 共有363条查询结果,搜索用时 15 毫秒
271.
一个新的Hardy-Hilbert类不等式及其应用 总被引:11,自引:2,他引:9
本文求出一个具有相同最佳常数因子的类似于Hardy-Hilbert不等式的新不 等式.作为应用,给出它的等价形式及一些特殊结果. 相似文献
272.
The determination of the weight distribution of linear codes has been a fascinating problem since the very beginning of coding theory. There has been a lot of research on weight enumerators of special cases, such as self-dual codes and codes with small Singleton's defect. We propose a new set of linear relations that must be satisfied by the coefficients of the weight distribution. From these relations we are able to derive known identities (in an easier way) for interesting cases, such as extremal codes, Hermitian codes, MDS and NMDS codes. Moreover, we are able to present for the first time the weight distribution of AMDS codes. We also discuss the link between our results and the Pless equations. 相似文献
273.
274.
本文建立了两个相关的∑Aa_i-B_2型凝胶化反应方程,含试样官能团数和重均官能度两个未知数.解联立方程,得到一元二次方程.通过测定该方程的系数,间接测得试样官能团数和重均官能度.该方法用于H_2O_2引发的羟基聚丁二烯羟值测定。其结果比目前国内外通用的经典酰化法高一倍以上.证明新的羟值数据是正确的. 相似文献
275.
Nurudeen A. Odewunmi Mohammad A. Jafar Mazumder Shaikh A. Ali Bader G. Alharbi 《化学:亚洲杂志》2021,16(7):801-821
1-(6-Bromohexyloxy)-4-propargyloxybenzene upon quaternization with 3-dimethylamino-1-propanol and N,N-dimethyldodecylamine produced two new inhibitor molecules: N-[6-(4-Propargyloxyphenoxy)hexyl]-N,N-dimethyl-N-(3-hydroxypropyl)ammonium bromide (PHAB) and N-[6-(4-Propargyloxyphenoxy)hexyl]-N,N-dimethyl-N-dodecylammonium bromide (PDAB), respectively, in excellent yields. The inhibitor molecules were characterized by elemental analysis, Fourier transform infrared spectroscopy, 1H NMR, and 13C NMR spectroscopy. The inhibitors were evaluated for X-60 mild steel corrosion in 15 wt.% HCl using different electrochemical and gravimetric techniques. The potentiodynamic polarization confirms both the inhibitors as mixed-type corrosion inhibitors. A low concentration (15 ppm) of PDAB has demonstrated excellent corrosion inhibition efficiencies of 97%, 98%, and 86% at 25 °C, 50 °C, and 70 °C, respectively, for 24 h exposure time. SEM and EDX spectra reveal that the adsorptions of corrosion inhibitors on X-60 mild steel create a protective film that serves as a barrier to mitigate the corrosion process. The X-ray photoelectron spectroscopy confirmed the chemical interaction between the corrosion inhibitors and mild steel, which was predicted by the Langmuir adsorption model. Assembly of inhibitive motifs of the alkyne, π-electron-rich aromatic, quaternary ammonium and C12 alkyl chain hydrophobe in PDAB has augmented its inhibiting action. 相似文献
276.
The paper shows a simple method that provides us the induction period, rate of weight increase at an earlier stage of thermal oxidation of elastomer and the rate of weight loss by oxidative degradation from a certain period of aging time. Ethylene-propylene elastomer (EPR) was aged in air at various constant temperatures ranged from 90 °C to 130 °C. The weight of samples was measured periodically at room temperature. The weight increased after a certain period of induction period at the early stage of aging. The activation energy obtained from the reciprocal of the induction period and that of the rate of weight increase was the same. The values were 113 kJ/mol. The weight started to decrease from the maximum point. The activation energy for the tangent of decrease curve was 60.3 kJ/mol. This method was applied to study the effect of pre-irradiation of EPR in air on the heat resistant property of the sample. The relatively low dose of 40 kGy decreased the induction period. 相似文献
277.
Yu-Jiao Chen Liang-Tao Wu Tai-An Li Meng-Qin Pu Prof. Xiao-Li Sun Prof. Hongli Bao Prof. Wen-Ming Wan 《Angewandte Chemie (International ed. in English)》2023,62(31):e202304033
The development of novel polymerization capable of yielding polymers with low molecular weight distribution (Đ) is essential and significant in polymer chemistry, where monofunctional initiator contains only one initiation site in these polymerizations generally. Here, ketyl radical anion species is introduced to develop a novel Ketyl Mediated Polymerization (KMP), which enables radical polymerization at carbon radical site and anionic ring-opening polymerization at oxygen anion site, respectively. Meanwhile, polymerization and corresponding organic synthesis generally couldn't be performed simultaneously in one pot. Through KMP, organic synthesis and polymerization are achieved in one pot, where small molecules (cyclopentane derivates) and polymers with low Đ are successfully prepared under mild condition simultaneously. At the initiation step, both organic synthesis and polymerization are initiated by single electron transfer reaction with ketyl radical anion formation. Cyclopentane derivates are synthesized through 3–3 coupling reaction and cyclization. Polystyrene and polycaprolactone with low Đ and a full monomer conversion are prepared by KMP via radical polymerization and anionic ring-opening polymerization, respectively. This work therefore enables both organic synthesis and two different polymerizations from same initiation system, which saves time, labour, resource and energy and expands the reaction mode and method libraries of organic chemistry and polymer chemistry. 相似文献
278.
Ts.Ch-D. Batueva O.V. Borodin M.A. Bykov A.O. Ivanova O.N. Kazak D.V. Nikiforov 《Discrete Mathematics》2017,340(11):2659-2664
The weight of an edge in a normal plane map (NPM) is the degree-sum of its end-vertices. An edge is of type if and . In 1940, Lebesgue proved that every NPM has an edge of one of the types , , or , where 7 and 6 are best possible. In 1955, Kotzig proved that every 3-connected planar graph has an edge with , which bound is sharp. Borodin (1989), answering Erd?s’ question, proved that every NPM has either a -edge, or -edge, or -edge.A vertex is simplicial if it is completely surrounded by 3-faces. In 2010, Ferencová and Madaras conjectured (in different terms) that every 3-polytope without simplicial 3-vertices has an edge with . Recently, we confirmed this conjecture by proving that every NPM has either a simplicial 3-vertex adjacent to a vertex of degree at most 10, or an edge of types , , or .By a -vertex we mean a -vertex incident with precisely triangular faces. The purpose of our paper is to prove that every NPM has an edge of one of the following types: , , , , , , or , where all bounds are best possible. In particular, this implies that the bounds in , , and can be attained only at NPMs having a simplicial 3-, 4-, or 5-vertex, respectively. 相似文献
279.
Michal Kotoul Tomas Vyslouzil Aldo R. Boccaccini Ivo Dlouhy 《Theoretical and Applied Fracture Mechanics》2008,49(2):158-170
Theoretical and experimental work are made for bridged cracks in chevron-notched three point bend specimens made of glass matrix composite reinforced by long SiC fibres. The fracture toughness (KIC) values are determined using the chevron-notch technique and compared with the theoretical predictions based on micromechanical analysis exploiting weight functions. The weight functions for orthotropic material are obtained numerically by means of detailed FEM analysis using the ANSYS package and they are further used together with appropriate bridging models for the theoretical prediction of the R-curve behaviours typical of the investigated composites. 相似文献
280.
几种含芯电子相关能修正的G2和G2(ACI)方法 总被引:1,自引:1,他引:0
针对冻结芯电子近似,在MP2/6-311G(d,p)级别上对G2、MP2/6-311G(d)和MP2/6-311G(d,p)级别上对G2(QCI)方法进一步考虑了芯电子相关能修正,尝试建立了G2(fu2)、G2(QCI/ful)和G2(QCI/fu2)方法。G2-l test set 的反应能量计算结果表明,这些方法进一步减小了经验修正量;G2(QCI/ful)和G2(QCI/fu2)也比G2(QCI)的总体精度有所提高;但G2(fu2)在G2基础上,总体精度没有改善。G2(fu2)、G2(QCI/ful)和G2(QCI/fu2)计算G2-l test set反应能量的平均绝对偏差分别为5.11、4.74和4.81kJ mol-1,G2和G2(QCI)分别为5.09和4.97kJ mol-1. 相似文献