Structural study on a sulfido-bridged dinuclear organotin(IV) complex with weak Sn ··· Sn bonding

A dinuclear anionic complex, Bu₄N[Me₂SnCl(S)ClSnMe₂Br], has been synthesized in chloroform solution by reacting (Me₂SnS)₃, Me₂SnCl₂, and Bu₄NBr. Attempts to isolate the anionic complex using tetramethylammonium cation were unsuccessful. The anion possesses two five-coordinate tin(IV) units bridged by sulfide and bromide. X-ray diffraction study revealed the possibility of a weak Sn–Sn bond in the complex. Theoretical (DFT) studies have been carried out to analyze the nature of metal–metal interaction in the complex.     

Weak local residuals as smoothness indicators for the shallow water equations

The system of shallow water equations admits infinitely many conservation laws. This paper investigates weak local residuals as smoothness indicators of numerical solutions to the shallow water equations. To get a weak formulation, a test function and integration are introduced into the shallow water equations. We use a finite volume method to solve the shallow water equations numerically. Based on our numerical simulations, the weak local residual of a simple conservation law with a simple test function is identified to be the best as a smoothness indicator.     

Weak values of a quantum observable and the cross-Wigner distribution

We study the weak values of a quantum observable from the point of view of the Wigner formalism. The main actor here is the cross-Wigner transform of two functions, which is in disguise the cross-ambiguity function familiar from radar theory and time-frequency analysis. It allows us to express weak values using a complex probability distribution. We suggest that our approach seems to confirm that the weak value of an observable is, as conjectured by several authors, due to the interference of two wavefunctions, one coming from the past, and the other from the future.     

Variational approach to impulsive evolution equations

This article uses variational method for studying existence and uniqueness of solutions for impulsive evolution equations. The main techniques include Hilbert triple, Sobolev embedding theorem, Galerkin approximation and weak convergence for passing to the limit.     

Non-linear longitudinal vibrations of non-slender piezoceramic rods

Characteristic non-linear effects can be observed, when piezoceramics are excited using weak electric fields. In experiments with longitudinal vibrations of piezoceramic rods, the behavior of a softening Duffing-oscillator including jump phenomena and multiple stable amplitude responses at the same excitation frequency and voltage is observed. Another phenomenon is the decrease of normalized amplitude responses with increasing excitation voltages. For such small stresses and weak electric fields as applied in the experiments, piezoceramics are usually described by linear constitutive equations around an operating point in the butterfly hysteresis curve. The non-linear effects under consideration were, e.g. observed and described by Beige and Schmidt [1,2], who investigated longitudinal plate vibrations using the piezoelectric 31-effect. They modeled these non-linearities using higher order quadratic and cubic elastic and electric terms. Typical non-linear effects, e.g. dependence of the resonance frequency on the amplitude, superharmonics in spectra and a non-linear relation between excitation voltage and vibration amplitude were also observed e.g. by von Wagner et al. [3] in piezo-beam systems. In the present paper, the work is extended to longitudinal vibrations of non-slender piezoceramic rods using the piezoelectric 33-effect. The non-linearities are modeled using an extended electric enthalpy density including non-linear quadratic and cubic elastic terms, coupling terms and electric terms. The equations of motion for the system under consideration are derived via the Ritz method using Hamilton's principle. An extended kinetic energy taking into consideration the transverse velocity is used to model the non-slender rods. The equations of motion are solved using perturbation techniques. In a second step, additional dissipative linear and non-linear terms are used in the model. The non-linear effects described in this paper may have strong influence on the relation between excitation voltage and response amplitude whenever piezoceramic actuators and structures are excited at resonance.     

ON REICH''''S OPEN QUESTION

1　IntroductionandPreliminariesThroughoutthispaperweassumethatEisarealBanachspace ,E isthedualspaceofE ,DisanonemptysubsetofEandJ:E → 2 E isthenormalizeddualitymappingdefinedbyJ(x) =f∈E ,　〈x ,f〉 =‖x‖‖f‖ ,　‖x‖ =‖f‖ 　 (x∈E) . (1 )　　Definition 1　LetT :D →Dbeamapping .1 .Tissaidtobeasymptoticallynonexpansive[1],ifthereexistsasequence kn [1 ,∞ )withlimn→∞kn =1suchthat‖Tnx-Tny‖ ≤kn‖x-y‖　forall　x ,y∈D ,n≥ 1 ;　　 2 .Tissaidtobenonexpansive,ifthesequence kn app…     

Modified fixed point algorithm in fluid–structure interactionAccélération avec des conditions de transpiration d'un algorithme de point fixe en interaction fluide–structure

In this work, we address the numerical solution of some non-linear problems arising in the time discretization of fluid–structure interaction problems with fully implicit schemes. At each time step, we have to solve a highly non-linear coupled system, since the fluid domain depends on the unknown displacement of the structure. We propose a modified fixed-point algorithm which combines the Block-Gauss–Seidel iterations with a transpiration formulation. Numerical experiments show the great improvement in computing time with respect to the standard method. To cite this article: S. Deparis et al., C. R. Mecanique 331 (2003).     

Unsteady rheometry: can we characterize weak gels with a controlled stress rheometer?

This paper is concerned with the influence of apparatus inertia effects in controlled stress rheometry. As evidenced on creep experiments, the coexistence of apparatus inertia and viscoelasticity leads to a coupling frequency. For weak gels, this coupling frequency is typically between 1 and 100 Hz. Therefore, frequency sweeps around and above this coupling frequency also corresponds to an effective shear stress sweep evolution due to a non-trivial resonant effect. In other words, frequency sweep experiments are not made at constant shear stress. The detailed modelling and analysis of this inertia effect on a typical weak gel shows a clear and fundamental limitation for its characterization using a controlled stress rheometer. Also, alternative approaches to standard rheometer software analysis are proposed to take this coupling effect into account. This paper was presented at the 3rd Annual Rheology Conference, AERC 2006, April 27-29, 2006, Crete, Greece.     

Relatively Compact Orbits and Compact Attractors for a Class of Nonlinear Evolution Equations

In the present paper we consider the nonlinear evolution equation u+AuG(u), where A:D(A)XX is m-accretive with (I+A)^–1 compact for some >0, and is continuous, and we prove that the orbit is relatively compact if and only if u is uniformly continuous, and both u and G^u are bounded on . In the same spirit, we derive conditions for orbits of bounded sets to have compact attractors. Some consequences and an example from age-structured population dynamics illustrate the effectiveness of the abstract result.