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91.
In this paper we report the results of a morphological and structural investigation on film properties of a soluble polydiacetylene, the poly[1,6-bis(3,6-dihexadecyl-N-carbazolyl)-2,4-hexadiyne] (polyDCHD-HS). The red films of this polymer, prepared by standard spin-coating techniques, revealed absence of linear dichroism and birefringence in contrast with the ordered mesophases detected by powder X-ray studies. In order to interpret the optical behavior of this polymer, we performed AFM and SEM studies of polyDCHD-HS films spun on hydrophylic and hydrophobic glass substrates. We found the presence of surfaces organized in rod-like particles, more regularly oriented on the hydrophylic substrate. GIXRD studies, carried out on films sufficiently thick to allow the observation of the diffraction pattern, reveled the presence of a lamellar structure with a spacing of 3.22 nm. The low intensity of the diffraction peaks and the isotropic linear optical properties of the films show that the lamellar mesophases are not extended over large areas. These findings were compared with the data obtained from AFM and SEM studies on films of two other polydiacetylenes, the poly[1-(3,6-dihexadexyl-N-carbazolyl)-6-(N-carbazolyl)-2,4-hexadyine] (polya-DCHD) and the poly[1,6-bis(3,6-dipalmitoyl-N-carbazolyl)-2,4-hexadyine] (polyDPCHD), spun on hydrophylic glass substrate. The results confirmed the presence of nodular morphologies which seem to be a general characteristic of this class of materials. The particles organization appears instead related to the chemical nature of the substituents on the carbazolyl rings. 相似文献
92.
Abakumov G. A. Druzhkov N. O. Kurskii Yu. A. Shavyrin A. S. 《Russian Chemical Bulletin》2003,52(3):712-717
Products of thermal transformation of substituted N-aryl-o-quinoneimines were studied using NMR spectroscopy. The formation of 4aH-phenoxazine, which was further dimerized by the Diels—Alder reaction, was established. 相似文献
93.
Transfer matrix approach of vibration isolation analysis of periodic composite structure 总被引:1,自引:0,他引:1
Wang Yong Huang Qibai Zhou Minggang Xu Zhisheng 《Archive of Applied Mechanics (Ingenieur Archiv)》2007,77(7):461-471
The transmission properties of elastic waves propagating in a three-dimensional composite structure embedded periodically
with spherical inclusions are analyzed by the transfer matrix method in this paper. Firstly, the periodic composite structures
are divided into many layers, the transfer matrix of monolayer structure is deduced by the wave equations, and the transfer
matrix of the entire structure is obtained in the case of boundary conditions of displacement and stress continuity between
layers. Then, the effective impedance of the structure is analyzed to calculate its reflectivity and transmissivity of vibration
isolation. Finally, numerical simulation is carried out; the experiment results validate the accuracy and feasibility of the
method adopted in the paper and some useful conclusions are obtained.
Project (No. 50075029) supported by the National Natural Science Foundation of China. 相似文献
94.
Schôichi Ôta Franciszek Hugon Szafraniec 《Journal of Mathematical Analysis and Applications》2007,329(2):987-997
We are in progress of extending the family of ‘q-deformed operators’ considered in the previous papers by joining to them q-subnormal as well as q-formally subnormal ones. It turns out that q-positive definiteness, a notion generalizing Halmos' standard positive definiteness of bounded subnormal operators, is likewise central for our new scheme. 相似文献
95.
Attapol Kaewkhao 《Journal of Mathematical Analysis and Applications》2007,333(2):950-958
We give some sufficient conditions for the Domínguez-Lorenzo condition in terms of the James constant, the Jordan-von Neumann constant, and the coefficient of weak orthogonality. As a consequence, we obtain fixed point theorems for multivalued nonexpansive mappings. 相似文献
96.
全纯函数族的正规定则 总被引:2,自引:0,他引:2
Let f be a holomorphic function on a domain D Lontaiu in C, and let a be a finite complex number. We denote by -↑Ef/(a) = {z ∈ D : f(z) = a, ignoring multiplicity} the set of all distinct α-points of f. Let F be a family of holomorphic functions on D. If there exist three finite values a, b(≠ O,α) and c(≠ O) such that for every f ∈F, -↑Ef′/(0) Lontain in -↑Ef(α) and -↑Ef′ (b) Lontain in -↑Ef(c), then F is a normal family on D. 相似文献
97.
物理实验课程考核、评估体系初探 总被引:4,自引:0,他引:4
对物理实验课程考核、评估方法进行了探讨,提出了物理实验课程考核、评估体系及实施细则.重点介绍了体系中的核心部分——正规的物理实验课程考试. 相似文献
98.
Ding-kang WANG~ Yan ZHANG Key Laboratory of Mathematics Mechanization Academy of Mathematics Systems Science Chinese Academy of Sciences Beijing China 《中国科学A辑(英文版)》2007,50(10):1441-1450
We present an algorithm to decompose a polynomial system into a finite set of normal ascending sets such that the set of the zeros of the polynomial system is the union of the sets of the regular zeros of the normal ascending sets.If the polynomial system is zero dimensional,the set of the zeros of the polynomials is the union of the sets of the zeros of the normal ascending sets. 相似文献
99.
The dendrite growth process of transparent NaBi(WO4)2 with small prandtl and high melting point was studied by using the in-situ observation system. According to the dynamic images and detailed information, there are two kinds of restriction effect on
the dendrite growth, the competition between arms and branches and the convection in the melt. The dendrite growth rate was
time dependent, and the rate of arm growth reached the maximum 5.8 mm/s in the diffusive-advective region and rapidly decreased
in the diffusive-convective region. The growth rate of branch had the same change trends as the arm’s. Based on the EPMA-EDS
data of solidification structure of quenched NaBi(WO4)2 melt, it was found that there were component differences from stoichiometric concentration in the melt near the interface
during the growth process.
Supported by the National Natural Science Foundation of China (Grant No. 50331040) and the Innovation Funds from Shanghai
Institute of Ceramics, Chinese Academy of Sciences (Grant No. SCX0623) 相似文献
100.
The present paper covers a salt of 2:18 heteropoly complex of tungstotitanophosphate prepared with the method of improved sequence preparation. The title compound was characterized by elemental analysis, 31P NMR spectra, polarography, cyclic voltammetry, IR, UV, X-ray powder diffraction , X-ray photoelectron spectra and TG-DTA analysis. The results show that the complex with the formula K8[TiP2W17O62]·12H2O has Dawson structure. Its properties such as spectra, redox behavior and thermal stability are discussed. 相似文献