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61.
LetR be a ring with unit and invariant basis property. In [1], the authors define a functorK(_;R):TOP/LIP
c-LPEP by combining the open cone construction of [7] with a geometric module construction and show this functor is a homology theory. This paper shows that if attention is restricted to objects TOP/LIP
c with a homotopy colimit structure, then the functorK(_;R) is a Quinn homology theory, In particular, for each having a homotopy colimit structure,K(;R) is a homotopy colimit in the category of -spectra. Furthermore, the constituent spectra of this homotopy colimit are obtained naturally from the fibres of .Partially supported by the National Science Foundation under grant number DMS88-03148.Partially supported by the SNF (Denmark) under grant number 11-7792. 相似文献
62.
Shouhong Xu Yuan Song Shizuko Sato Isamu Miyata Junpei Yamanaka Masakatsu Yonese 《Colloid and polymer science》2005,283(4):383-392
Two-dimensional structures and characteristics of the complexes between sodium hyaluronate (NaHA) and bovine serum albumin (BSA) were studied by using a quartz crystal microbalance method and an atomic force microscope (AFM). NaHA did not adsorb on poly(-methyl-l-glutamate) (PMLG) film. On the other hand, the complexes adsorbed on it and the adsorption behaviors were found to be Langmuir types. With increasing weight ratio of BSA to NaHA, W
BSA, the adsorption constants K decreased and the saturated adsorption masses increased. The adsorbed complexes were spherical particles and at saturated adsorption states they covered compactly on the PMLG film. The mean diameters d
AFM estimated from the topographic images decreased from 70 to 54 nm with increasing W
BSA. The adhesion force F
ad and the frictional force F
f between the complex layers and the AFM tip were obtained by using the contact mode of the AFM. With increasing W
BSA, the values of F
ad decreased and the values of F
f increased. Compared with the frictional coefficient of the NaHA adsorption layer on the BSA monolayer, the values for the NaHA–BSA complex layer were found to be much higher. 相似文献
63.
聚丙烯酰胺双向凝胶电泳法分析变色人发角蛋白组成 总被引:1,自引:0,他引:1
报道了一种用双向聚丙烯酰胺凝胶电泳分析经S-羧甲基化修饰的变色人发角蛋白样品的方法,以含8mo1/L脲变性凝胶电泳做第一向,SDS-PAGE做第二向。不同处理的变色人发得到有差别的双向电泳图谱,即不同处理方法得到的人发蛋白质组成有差异。以此可做为人发变色处理的一个定性方法。 相似文献
64.
Acetonitrile and [D3]acetonitrile in the vicinal region of a planar AgX fiber contain linear dipole–dipole linked oligomers as shown by 1) comparison of infrared band intensity ratios in the gaseous and condensed phases and 2) remarkable plots of absorbance (C? N stretch) versus time during evaporation from an AgX planar fiber element. The plots (CH3CN 2252 cm?1, CD3CN 2262 cm?1) reveal the presence of octamers, hexamers, tetramers, and dimers along with some heptamer, trimer, and monomer structures. A novel isotope effect arises from the somewhat smaller size of the CD3CN resulting in an increase in the CN band intensity. The organized oligomers may be termed pseudocrystals and are the main components responsible for absorption intensity in the infrared spectrum of acetonitrile, on the AgX planar fiber or in an IR cell. 相似文献
65.
From measurements performed on different polymeric glass-forming liquids using differential scanning calorimetry (DSC), we determined the values of the fragility index m according to the concept proposed by Angell. We calculated the average size of a cooperative rearranging region (CRR) at the glass transition i.e. z(Tg), according to the definition proposed by Solunov. This quantity is linked to the Kauzmann temperature which was determined from dielectric spectroscopy or viscosimetry measurements performed on different samples including three-dimensional polymeric networks and linear polymer families with variable lateral chain lengths. By using our experimental data and others collected in the literature in order to scan a large domain of fragility values, we show that the fragility index m, characterising the glass-forming liquid, can be correlated to z(Tg) which characterises the glass formed. 相似文献
66.
I. L. Baranov L. V. Tabulina L. S. Stanovaya T. G. Rusal’skaya 《Russian Journal of Electrochemistry》2006,42(4):320-325
Variations in electrophysical properties of anodic silicon oxide at the surface of semiconductor silicon are studied as a function of the composition of electrolytic solutions containing orthophosphoric acid and the conditions of reaching the final formation potential. The optimum conditions for the formation of anodic SiO2 coatings that include phosphorus-containing admixtures are determined, the coatings being intended for application as diffusates in nanoelectronics. 相似文献
67.
Yulu Yang Mingguang Wu Xingwang Zhu Hui Xu Si Ma Yongfeng Zhi Hong Xia Xiaoming Liu Jun Pan Jie-Yinn Tang Siang-Piao Chai Leonardo Palmisano Francesco Parrino Junli Liu Jianzhong Ma Ze-Lin Wang Ling Tan Yu-Fei Zhao Yu-Fei Song Pardeep Singh Pankaj Raizada Deli Jiang Di Li R. A. Geioushy Jizhen Ma Jintao Zhang Song Hu Rongjuan Feng Gang Liu Minghua Liu Zhenhua Li Mingfei Shao Neng Li Jiahe Peng Wee-Jun Ong Nikolay Kornienko Zhenyu Xing Xiujun Fan Jianmin Ma 《中国化学快报》1990,30(12):2065-2088
This roadmap demonstrates a series of two-dimensional nanomaterials, such as graphene, black phosphorus, oxides, layered double hydroxides, chalcogenides, bismuth-based layered compounds, MXenes, metal organic frameworks, covalent organic frameworks, and others, for environmental catalysis. 相似文献
68.
P. Valtazanos S. T. Elbert S. Xantheas K. Ruedenberg 《Theoretical chemistry accounts》1991,78(5-6):287-326
Summary The global features of the groundstate ring opening of cyclopropylidene to allene are studied by means ofab-initio FORS MCSCF calculations based on a minimal AO basis set. The energy surface is completely mapped out in terms of three reaction coordinates, namely the CCC ring-opening angle and two angles describing the rotations of the CH2 groups. For each choice of these three variables, the twelve remaining internal coordinates are optimized by energy minimization. In the initial phase of the reaction, as the CCC angle opens, the CH2 groups rotate in a disrotatory manner, maintainingC
s symmetry. This uphill reaction path leads to a transition region which occurs early, for a CCC angle of about 84°. In this transition region the reaction path branches into two pathways which are each others' mirror images. The system exhibits thus abifurcating transition region. Passed this region, the two pathways are overall conrotatory in character. However, these downhill reaction paths to the products are poorly defined because, from a CCC opening angle of about 90° on,the CH
2
groups can rotate freely and isoenergetically in a synchronized, cogwheel-like manner and this disrotatory motion can mix unpredictably with the conrotatory downhill motion. There is no preference for any one of the two reaction pathways yielding the two stereoisomers of allene and the reaction is thereforenonstereospecific with respect to the numbered hydrogen atoms. The global surface is documented by means of contour maps representing slices corresponding to constant CCC angles. The bifurcating transition region is mapped in detail.Operated for the U.S. Department of Energy by Iowa State University under Contract No. 7405-ENG-82. This work was supported by the office of Basic Energy Sciences 相似文献
69.
N. C. van de Merbel M. Stenberg R. Öste G. Marko-Varga L. Gorton H. Lingeman U. A. Th. Brinkman 《Chromatographia》1995,41(1-2):6-14
Summary A two-dimensional, column liquid chromatographic system is used for the determination of the D- and L-enantiomers of amino acids in biological samples. Separation of the amino acids is first on ion-exchange column by gradient elution with a sodium citratesodium chloride buffer. Enantioseparation is by subsequent injection of 3 l heart-cuts of the individual amino acids onto a second column with a chiral crown ether stationary phase. Finally, fluorescence detection is after post-column labelling of the amino acids using ano-phthalaldehyde-2-mercaptoethanol reagent solution. The high separation power and selectivity of the system allow processing of complex samples with hardly any additional treatment and the determination of small quantities of D-amino acids in the presence of excess L-form. Applicability of the system is illustrated by the determination of D- and L-aspartate, serine, glutamate and alanine in various complex biological samples, such as protein hydrolysates, urine and biotechnological and food samples. Data are given on detectability, repeatability and linearity. 相似文献
70.
Two-dimensional capillary electrophoresis was used for the separation of proteins and biogenic amines from the mouse AtT-20 cell line. The first-dimension capillary contained a TRIS–CHES–SDS–dextran buffer to perform capillary sieving electrophoresis, which is based on molecular weight of proteins. The second-dimension capillary contained a TRIS–CHES–SDS buffer for micellar electrokinetic capillary chromatography. After a 61-s preliminary separation, fractions from the first-dimension capillary were successively transferred to the second-dimension capillary, where they further separated by MECC. The two-dimensional separation required 60 min. 相似文献