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51.
分子筛膜具有规整的微孔结构(<1 nm), 耐高温高压、 抗有机溶剂, 在液相和气相小分子分离中受到广泛关注. 分子筛膜可以与催化反应耦合于一体构成膜反应器, 使反应过程与组分分离同时进行, 促进反应平衡移动, 达到反应强化的效果. 本文概述了近十年不同类型分子筛膜反应器在催化反应中的应用研究进展, 并对分子筛膜反应器未来的发展趋势进行了展望. 相似文献
52.
Why would natural selection favor the prevalence of cooperation within the groups of selfish individuals? A fruitful framework to address this question is evolutionary game theory, the essence of which is captured in the so-called social dilemmas. Such dilemmas have sparked the development of a variety of mathematical approaches to assess the conditions under which cooperation evolves. Furthermore, borrowing from statistical physics and network science, the research of the evolutionary game dynamics has been enriched with phenomena such as pattern formation, equilibrium selection, and self-organization. Numerous advances in understanding the evolution of cooperative behavior over the last few decades have recently been distilled into five reciprocity mechanisms: direct reciprocity, indirect reciprocity, kin selection, group selection, and network reciprocity. However, when social viscosity is introduced into a population via any of the reciprocity mechanisms, the existing scaling parameters for the dilemma strength do not yield a unique answer as to how the evolutionary dynamics should unfold. Motivated by this problem, we review the developments that led to the present state of affairs, highlight the accompanying pitfalls, and propose new universal scaling parameters for the dilemma strength. We prove universality by showing that the conditions for an ESS and the expressions for the internal equilibriums in an infinite, well-mixed population subjected to any of the five reciprocity mechanisms depend only on the new scaling parameters. A similar result is shown to hold for the fixation probability of the different strategies in a finite, well-mixed population. Furthermore, by means of numerical simulations, the same scaling parameters are shown to be effective even if the evolution of cooperation is considered on the spatial networks (with the exception of highly heterogeneous setups). We close the discussion by suggesting promising directions for future research including (i) how to handle the dilemma strength in the context of co-evolution and (ii) where to seek opportunities for applying the game theoretical approach with meaningful impact. 相似文献
53.
以聚乙烯醇(PVA)-戊二醛(GA)体系作为研究对象, 系统地研究了分子内环化对凝胶体系的影响, 为水凝胶体系的网络结构评价奠定了一定的实验基础. 相似文献
54.
55.
Thi Thu Van Nguyen Jean-Jacques Strodiot Van Hien Nguyen 《Journal of Global Optimization》2009,44(2):175-192
In this article we present a new and efficient method for solving equilibrium problems on polyhedra. The method is based on
an interior-quadratic proximal term which replaces the usual quadratic proximal term. This leads to an interior proximal type
algorithm. Each iteration consists in a prediction step followed by a correction step as in the extragradient method. In a
first algorithm each of these steps is obtained by solving an unconstrained minimization problem, while in a second algorithm
the correction step is replaced by an Armijo-backtracking linesearch followed by an hyperplane projection step. We prove that
our algorithms are convergent under mild assumptions: pseudomonotonicity for the two algorithms and a Lipschitz property for
the first one. Finally we present some numerical experiments to illustrate the behavior of the proposed algorithms. 相似文献
56.
The original BML model is extended by introducing extended sites, which can hold several vehicles at each time-step. Unexpectedly, the flow in the extended model sharply transits from free-flow to global jams, but the transition is not one-order in original BML model. And congestion in the extended model appears more easily. This can ascribe to the mixture of vehicles from different directions in one site, leading to the drop-off of the capacity of the site. Furthermore, the typical configuration of free flowing and global jams in the extended models is disorder, different from the regular structure in the original model. 相似文献
57.
《Journal of Coordination Chemistry》2012,65(13):1537-1539
The results of a spectrophotometric investigation of the reaction of the biologically active salt 1-benzoylethylpyridinium-4-aldoxime chloride with aquapentacyanoferrate(II) ion are presented. In spite of the presence of two donor sites, only the carbonyl group of the ligand coordinates to the iron centre. Reaction kinetics are consistent with a dissociative mechanism. 相似文献
58.
In this Letter, a car-following model with consideration of roadside memorial is proposed. The numerical results show that the proposed model can qualitatively describe the impacts of roadside memorial on traffic flow and the traffic risk coefficient. It is also shown that roadside memorial can enhance the traffic safety. 相似文献
59.
N. G. Fytas A. Malakis 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(1):111-120
The one-parametric Wang-Landau (WL) method is
implemented together with an extrapolation scheme to yield
approximations of the two-dimensional (exchange-energy,
field-energy) density of states (DOS) of the 3D bimodal
random-field Ising model (RFIM). The present approach generalizes
our earlier WL implementations, by handling the final stage of the
WL process as an entropic sampling scheme, appropriate for the
recording of the required two-parametric histograms. We test the
accuracy of the proposed extrapolation scheme and then apply it to
study the size-shift behavior of the phase diagram of the 3D
bimodal RFIM. We present a finite-size converging approach and a
well-behaved sequence of estimates for the critical disorder
strength. Their asymptotic shift-behavior yields the critical
disorder strength and the associated correlation length's
exponent, in agreement with previous estimates from ground-state
studies of the model. 相似文献
60.
带铁芯托卡马克装置的等离子体平衡数值解法 总被引:1,自引:0,他引:1
本文提出一种计算铁芯变压器托卡马克装置中等离子体平衡的数值方法。将铁芯对等离子体平衡的影响等效地看作外部线圈电流的作用,这样问题就转化为求解空芯变压器装置的等离子体平衡问题。这一方法的另一特点是计算区域减至最小。 相似文献