全文获取类型
收费全文 | 4109篇 |
免费 | 276篇 |
国内免费 | 400篇 |
专业分类
化学 | 561篇 |
晶体学 | 19篇 |
力学 | 331篇 |
综合类 | 77篇 |
数学 | 2827篇 |
物理学 | 970篇 |
出版年
2024年 | 8篇 |
2023年 | 52篇 |
2022年 | 57篇 |
2021年 | 66篇 |
2020年 | 72篇 |
2019年 | 113篇 |
2018年 | 114篇 |
2017年 | 130篇 |
2016年 | 129篇 |
2015年 | 102篇 |
2014年 | 207篇 |
2013年 | 337篇 |
2012年 | 159篇 |
2011年 | 224篇 |
2010年 | 237篇 |
2009年 | 257篇 |
2008年 | 260篇 |
2007年 | 243篇 |
2006年 | 235篇 |
2005年 | 213篇 |
2004年 | 193篇 |
2003年 | 139篇 |
2002年 | 174篇 |
2001年 | 124篇 |
2000年 | 110篇 |
1999年 | 105篇 |
1998年 | 86篇 |
1997年 | 86篇 |
1996年 | 61篇 |
1995年 | 66篇 |
1994年 | 45篇 |
1993年 | 29篇 |
1992年 | 41篇 |
1991年 | 19篇 |
1990年 | 25篇 |
1989年 | 22篇 |
1988年 | 18篇 |
1987年 | 8篇 |
1986年 | 8篇 |
1985年 | 20篇 |
1984年 | 13篇 |
1983年 | 11篇 |
1982年 | 20篇 |
1981年 | 33篇 |
1980年 | 28篇 |
1979年 | 17篇 |
1978年 | 11篇 |
1977年 | 17篇 |
1976年 | 17篇 |
1973年 | 8篇 |
排序方式: 共有4785条查询结果,搜索用时 78 毫秒
131.
Lung-Hui Chen 《复变函数与椭圆型方程》2015,60(5):707-731
We study the inverse spectral problem in an interior transmission eigenvalue problem. The Cartwright’s theory in value distribution theory gives a connection between the distributional structure of the eigenvalues and the asymptotic behaviours of its defining functional determinants. Given a sufficient quantity of transmission eigenvalues, we prove a uniqueness of the refraction index in inhomogeneous medium as an uniqueness problem in entire function theory. The asymptotically periodical structure of the zero set of the solutions helps to locate infinitely many eigenvalues of infinite degree of freedom. 相似文献
132.
The paper presents a new method based on simultaneous derivatization and air-assisted liquid–liquid microextraction (AALLME) for the extraction and preconcentration of some aliphatic amines prior to gas chromatography-flame ionization detection (GC-FID). Primary aliphatic amines are derivatized and extracted simultaneously by a fast reaction with butylchloroformate (derivatization agent/extraction solvent) under mild conditions. The mixture of butylchloroformate and aqueous sample solution is rapidly sucked into a 10-mL glass syringe and then is injected into a test tube with conical bottom and the procedure is repeated seven times. After centrifuging the resulted cloudy solution, the derivatized analytes in the sedimented phase are determined by GC-FID. The influence of main factors on the efficiency of derivatization/extraction procedure is studied. Under the optimal conditions, the enrichment factors (EFs) for aliphatic amines are obtained in the range of 248–360 and limits of detection (LODs) are between 0.30 and 2.6 μg L−1. The obtained extraction recoveries ranged from 50 to 72% and the relative standard deviation (RSD) was less than 4.8% for intra-day (n = 6) and inter-days (n = 4) precision. The method is successfully applied to determine some aliphatic amines in environmental water samples. 相似文献
133.
Kalipada Adhikari Sudip Chattopadhyay Barin Kumar De Amitava Sharma Ranendu Kumar Nath Dhiman Sinha 《Journal of computational chemistry》2013,34(15):1291-1310
A valence‐universal multireference coupled cluster (VUMRCC) theory, realized via the eigenvalue independent partitioning (EIP) route, has been implemented with full inclusion of triples excitations for computing and analyzing the entire main and several satellite peaks in the ionization potential spectra of several molecules. The EIP‐VUMRCC method, unlike the traditional VUMRCC theory, allows divergence‐free homing‐in to satellite roots which would otherwise have been plagued by intruders, and is thus numerically more robust to obtain more efficient and dependable computational schemes allowing more extensive use of the approach. The computed ionization potentials (IPs) as a result of truncation of the (N−1) electron basis manifold involving virtual functions such as 2h‐p and 3h‐2p by different energy thresholds varying from 5 to 15 a.u. with 1 a.u. intervals as well as thresholds such as 20, 25, and 30 a.u. have been carefully looked into. Cutoff at around 25 a.u. turns out to be an optimal threshold. Molecules such as C2H4 and C2H2 (X = D,T), and N2 and CO (X = D,T,Q) with Dunning's cc‐pVXZ bases have been investigated to determine all main and 2h‐p shake‐up and 3h‐2p double shake‐up satellite IPs. We believe that the present work will pave the way to a wider application of the method by providing main and satellite IPs for some problematic N‐electron closed shell systems. © 2013 Wiley Periodicals, Inc. 相似文献
134.
CHENG SIQING MENG XIANGGUANG CHEN YONG WANG QIAN ZENG XIANCHENG 《Journal of Dispersion Science and Technology》2013,34(2):199-207
The effect of Fe (II) metallomicelle as a model of catalase, which was formed by adding surfactants (CTAB, SDS, LSS, Brij35) in Fe (II) -trien complex of molar ratios 1: 500 on the decomposition of hydrogen peroxide was investigated at 20°C and 30°C in pH 10 using KI-color and UV Spectrophotometry. A kinetic model for metallomicellar catalysis was proposed. The association constant of the ternary complex K and the rate constant of the decomposition of hydrogen peroxide k3 were obtained. The results indicate that the metallomicelles making up of Fe (II) metal complex and cationic or nonionic surfactants have obvious catalysis on the decomposition of hydrogen peroxide, but the metallomicelles making up of Fe (II) metal complex and anionic or zwitterionic surfactants have inhibition on this reaction. 相似文献
135.
航空通信环境中存在复杂的干扰信号,对正常的通信信号造成强烈的干扰。利用传统算法进行干扰信号过滤,无法避免由于干扰信号过于复杂导致过滤不充分的缺陷。提出一种基于加权残差优化算法的航空通信网络中复杂干扰过滤方法。对原始信号进行降频处理,能够消除峰值干扰信号,提高了信号的准确性。根据加权残差修正优化算法的相关原理,对通信信号进行残差优化处理,经过处理后的通信信号在受到干扰时会形成零陷,实现了对复杂干扰信号的过滤。实验结果表明,利用该算法进行航空通信网络中复杂干扰信号过滤,能够有效提高过滤的准确性,效果令人满意。 相似文献
136.
夜视战场环境视觉传感信息的实时获取是跟踪夜视战场图像处理分析的前提,针对夜视战场环境的复杂特征,设计了夜视战场环境视觉传感信息采集系统,分析了系统的总体结构,系统硬件主要包括视觉传感器、传感器控制卡和扩展卡、图像采集与存储以及信号调理电路,给出了系统采集节点的程序设计流程以及传感信息采集的具体程序代码实现过程。实验结果说明,所设计系统可有效采集到夜间军事战场中的传感信息,并且具有较高的采集精度。 相似文献
137.
138.
This paper introduces a new framework for implicit restarting of the Krylov–Schur algorithm. It is shown that restarting with arbitrary polynomial filter is possible by reassigning some of the eigenvalues of the Rayleigh quotient through a rank‐one correction, implemented using only the elementary transformations (translation and similarity) of the Krylov decomposition. This framework includes the implicitly restarted Arnoldi (IRA) algorithm and the Krylov–Schur algorithm with implicit harmonic restart as special cases. Further, it reveals that the IRA algorithm can be turned into an eigenvalue assignment method. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
139.
发动机是军舰上的重要部件之一,其稳定性对军舰的正常航行具有重要影响。以舰用发动机关键部件(主泵轴承)为具体研究对象,提出了基于功率谱包络能量和支持向量机相结合的故障诊断方法。首先获取了大量可表征舰用发动机主泵轴承健康状态的振动加速度信息,对其进行功率谱分析,获得其功率谱的包络能量;以获取的舰用发动机主泵轴承功率谱的包络能量构建特征向量,并设计基于SVM的舰用发动机主泵轴承故障诊断模型,对主泵轴承的故障进行诊断研究。研究结果表明,采用基于功率谱包络能量和SVM相结合的舰用发动机关键部件故障诊断方法,可以很好实现主泵轴承的故障诊断效能,为舰用发动机主泵轴承故障诊断的工程应用奠定了基础。 相似文献
140.