Synthesis,spatial structure and spectral properties of pyrylo‐4 (thio) squaraines variously substituted in cyclobutene moiety

Synthetic routes have been developed to a number of (thio) squaraine dyes containing the residues of CH‐acids at the central cyclobutene ring. The electronic and spatial structure as well as the chemical conversions and optical behaviour of the compounds obtained have been studied both theoretically and by X‐ray diffraction analysis, ¹H NMR and electronic spectroscopy. As shown, the electronic nature and sterical characteristics of the central ring substituents give rise to some general conformational features and crystal packing regularities and also govern the spectral position of the first π–π^* absorption band. The structure–property relationships established in the study provide guidance for the purposeful design of deeply coloured (thio) squaraines. Copyright © 2015 John Wiley & Sons, Ltd.     

Synthesis,Characterization, and Antiproliferative Activity of Novel Chiral [QuinoxP*AuCl2]+ Complexes

Herein is reported the synthesis of two Au(III) complexes bearing the (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (R,R-QuinoxP*) or (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (S,S-QuinoxP*) ligands. By reacting two stoichiometric equivalents of HAuCl₄.3H₂O to one equivalent of the corresponding QuinoxP* ligand, (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (1) and (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (2) were formed, respectively, in moderate yields. The structure of (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (2) was further confirmed by X-ray crystallography. The antiproliferative activities of the two compounds were evaluated in a panel of cell lines and exhibited promising results comparable to auranofin and cisplatin with IC₅₀ values between 1.08 and 4.83 µM. It is noteworthy that in comparison to other platinum and ruthenium enantiomeric complexes, the two enantiomers (1 and 2) do not exhibit different cytotoxic effects. The compounds exhibited stability in biologically relevant media over 48 h as well as inert reactivity to excess glutathione at 37 °C. These results demonstrate that the Au(III) atom, stabilized by the QuinoxP* ligand, can provide exciting compounds for novel anticancer drugs. These complexes provide a new scaffold to further develop a robust and diverse library of chiral phosphorus Au(III) complexes.     

Cooperation of σ–π and σ*–π* Conjugation in the UV/Vis and Fluorescence Spectra of 9,10-Disilylanthracene

In 1996, we reported that silyl groups of 9,10-disilylanthracenes significantly affect the UV/Vis and fluorescence spectra. Although the results indicate that the silyl groups have strong electronic effects on anthracene, the details of the mechanisms responsible for this have not yet been clarified. This article describes the analysis of the UV/Vis and fluorescence spectra of 9,10-bis(diisopropylsilyl)anthracene by theoretical calculations. This study reveals that π conjugation of anthracene is extended by cooperation of σ–π and σ*–π* conjugation between the silyl groups and anthracene. This effect increases the transition moment of the π–π* transition of anthracene. As a result, the molecular extinction coefficient of the ¹L_a band and the fluorescence quantum yield are increased.     

具有卷积的中心自反环

本文研究了具有卷积的中心自反环的性质,定义并引入了中心-自反环,显然,中心-自反环是自反环、中心自反环和-自反环的推广.给出了这类环的一些特征,研究了相关的环扩张,包括平凡扩张,Dorroh扩张和多项式扩张.     

A note on idempotents in finite AW*-factors

We prove that the value of the quasi-trace on an idempotent element in an AW*-factor of type is the same as the dimension of its left (or right) support.

     

A description of Hilbert -modules in which all closed submodules are orthogonally closed

Let , be -algebras and a full Hilbert --bimodule such that every closed right submodule is orthogonally closed, i.e., . Then there are families of Hilbert spaces , such that and are isomorphic to -direct sums , resp. , and is isomorphic to the outer direct sum .

     

欧拉游历间K1—变换下的算法复杂性

本文主要讨论了欧拉图方面的国际权威ＨｅｒｂｅｒｔＦｌｅｉｃｈｎｅｒ教授所著书［１］中的一个问题；对欧拉图Ｇ的任意两个欧拉游历要经过多少Ｋ－变换或Ｋ＾＊－变换才能从一个游历得到另一个游历？我们得到的结论是：对欧拉图Ｇ中的任两个欧拉游历Ｔ、Ｔ＇最多经过‖Ｅ（Ｇ）‖－‖Ｖ（Ｇ）‖－变换可以使Ｔ变换成Ｔ＇。且此结果不能再改进。进一步我们分别对Ｋ－变换和Ｋ＆－变换的算法复杂性进行了讨论。     

P－正则半群的双序集

本文刻划了双序集Ｅ为某Ｐ－正则半群的幂等元双序集的充要条件．所得定理不仅推广了Ｄ．Ｅａｓｄｏｗｎ关于带的双序集的结论，而且导出了正则＊－半群的幂等元双序集的一个刻划．进而还对Ｐ－正则半群的若干特殊情形及向非正则半群的推广进行了讨论．     

TEM01模式激光对两能级原子的作用力研究

推导了两能级原子在稳态和小速度一阶微扰近似下的受力矢量方程，并分析表明ＴＥＭ０１模光场以原子的作用力中存在旋涡力，对在大正失谐δ〉〉Ω０〉〉Г和ｚ〈〈ｚ０＝ｋｗ＾２／λ条件下的ＴＥＭ０１模行波和驻波场中原子的受力进行了分析，对行波场，自发辐射对原子运动的影响很大，但在ｒ〈〈λ区域内原子受到横向囚禁力；对驻波场，自发辐射的影响可以忽略，考虑在ｚ方向波长范围内原子的平均受力得到的结论为：在横向，除了有