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191.
The kinetics of phase separation subsequent to a finite temperature quench is assumed to be driven by diffusion on the altered free energy surface and is generally assumed to be slow. The situation can be different in phase separating liquid binary mixtures, especially for systems characterized by the large difference in mutual interactions between solute and solvent molecules. In such cases, the phase separation kinetics could be fast and may get completed within a short time (ns) scale. As a result, in these systems, one may observe diverse dynamical features arising out of local heterogeneity leading to the onset of phase separation through pattern formation, spinodal decomposition, nucleation, and growth. By using a coarse-grained analysis, we examine phase separation kinetics in each spatial grid and indeed observe important effects of initial heterogeneity on the subsequent evolution. Interestingly, we observe slower separation kinetics for those regions that correspond to the composition at the minimum of the high-temperature surface. The heterogeneous dynamics has been captured here through the non-linear susceptibility function, which shows a pattern similar to what is observed in the supercooled liquid. Each grid shows somewhat different dynamics in the three-stage (exponential, power-law, and logarithmic regime) phase separation dynamics. The late stage of phase separation kinetics is usually attributed to the coarsening of the phase-separated domains. However, in a liquid binary mixture, the late-stage power-law decay undergoes a further change. A new dynamical regime arises characterized by a logarithmic time dependence, which is due to the “smoothening” of the rough interface of already well-separated phases. This can also be described as opposite to the roughening transition described by Chui and Weeks [Phys. Rev. Lett. 40, 733 (1978)]. This reverse roughening transition can explain the logarithmic time dependence observed in the simulation. 相似文献
192.
Juan CASADO-DIAZ 《数学年刊B辑(英文版)》2015,36(5):703-714
The author considers two classical problems in optimal design
consisting in maximizing or minimizing the energy corresponding to
the mixture of two isotropic materials or two-composite material.
These results refer to the smoothness of the optimal solutions. They
also apply to the minimization of the first eigenvalue. 相似文献
193.
R. Quintanilla 《Applicable analysis》2013,92(2):135-155
This article investigates the structural stability in several thermomechanics and heat conduction theories as well as the convergence of these theories to the classical versions of the thermoelasticity and heat conduction. We consider first the Lord–Shulman theory of thermoelasticity. We study the structural stability with respect to the relaxation parameter and the convergence of the solutions when the relaxation parameter tends to zero. Second we study the dual-phase-lag theory. Assuming that the relaxation parameters are small we consider the Taylor series in which only the first powers of the phase-lag parameters are retained. In this situation we consider the heat equation and study the structural stability and the convergence with respect to the phase-lag of the gradient of temperature. In the last part of the article, we consider the thermoelastic theory proposed by Chandrasekharaiah and Tzou. We study the structural stability and the convergence with respect to both relaxation parameters that describe this theory 相似文献
194.
Srdjan Stojanovic 《Numerical Functional Analysis & Optimization》2013,34(5-6):573-591
An optimal control problem for a parabolic equation when the control parameter is the zero order coefficient of the differential operator is considered. An optimality system is derived. Under a certain sign condition, the problem is solved completely, by proving uniqueness and providing a constructive existence proof for the nonlinear parabolic optimality system. 相似文献
195.
An exact reduced density operator of a quantum system interacting with a bosonic thermal reservoir is derived by means of the simple algebraic method. The necessary and sufficient condition is found that the time-convolutionless master equation becomes exact up to the second order with respect to the system-reservoir interaction. The result is examined by means of the boson-detector model. The reduced dynamics of a quantum system interacting with a classical reservoir is also discussed. 相似文献
196.
Adriana Garroni Marcello Ponsiglione Francesca Prinari 《Calculus of Variations and Partial Differential Equations》2006,27(4):397-420
In this paper we consider positively 1-homogeneous supremal functionals of the type . We prove that the relaxation $\bar{F}$ is a difference quotient, that is
where is a geodesic distance associated to F. Moreover we prove that the closure of the class of 1-homogeneous supremal functionals with respect to Γ-convergence is given exactly by the class of difference quotients associated to geodesic distances. This class strictly contains supremal functionals, as the class of geodesic distances strictly contains intrinsic distances.
Mathematics Subject Classification (2000) 47J20, 58B20, 49J45 相似文献
197.
Ziener CH Bauer WR Melkus G Weber T Herold V Jakob PM 《Magnetic resonance imaging》2006,24(10):1341-1347
We describe the relationship between the correlation time and microscopic spatial inhomogeneities in the static magnetic field. The theory takes into account diffusion of nuclear spins in the inhomogeneous field created by magnetized objects. A simple general expression for the correlation time is obtained. It is shown that the correlation time is dependent on a characteristic length, the diffusion coefficient of surrounding medium, the permeability of the surface and the volume fraction of the magnetized objects. For specific geometries (spheres and cylinders), exact analytical expressions for the correlation time are given. The theory can be applied to contrast agents (magnetically labeled cells), capillary network, BOLD effect and so forth. 相似文献
198.
We investigate the value function of the infinite horizon problem in optimal control for a general—not necessarily discounted—running cost and provide sufficient conditions for its lower semicontinuity, continuity, and local Lipschitz regularity. Then we use the continuity of to prove a relaxation theorem and to write the first order necessary optimality conditions in the form of a, possibly abnormal, maximum principle whose transversality condition uses limiting/horizontal supergradients of at the initial point. When is merely lower semicontinuous, then for a dense subset of initial conditions we obtain a normal maximum principle augmented by sensitivity relations involving the Fréchet subdifferentials of . Finally, when V is locally Lipschitz, we prove a normal maximum principle together with sensitivity relations involving generalized gradients of V for arbitrary initial conditions. Such relations simplify drastically the investigation of the limiting behavior at infinity of the adjoint state. 相似文献
199.
The set covering problem (SCP) is central in a wide variety of practical applications for which finding good feasible solutions quickly (often in real-time) is crucial. Surrogate constraint normalization is a classical technique used to derive appropriate weights for surrogate constraint relaxations in mathematical programming. This framework remains the core of the most effective constructive heuristics for the solution of the SCP chiefly represented by the widely-used Chvátal method. This paper introduces a number of normalization rules and demonstrates their superiority to the classical Chvátal rule, especially when solving large scale and real-world instances. Directions for new advances on the creation of more elaborate normalization rules for surrogate heuristics are also provided. 相似文献
200.
TRANSFORM-ANN for online optimization of complex industrial processes: Casting process as case study
Srinivas Soumitri Miriyala Venkat R. Subramanian Kishalay Mitra 《European Journal of Operational Research》2018,264(1):294-309
Artificial Neural Networks (ANNs) are well known for their credible ability to capture non-linear trends in scientific data. However, the heuristic nature of estimation of parameters associated with ANNs has prevented their evolution into efficient surrogate models. Further, the dearth of optimal training size estimation algorithms for the data greedy ANNs resulted in their overfitting. Therefore, through this work, we aim to contribute a novel ANN building algorithm called TRANSFORM aimed at simultaneous and optimal estimation of ANN architecture, training size and transfer function. TRANSFORM is integrated with three standalone Sobol sampling based training size determination algorithms which incorporate the concepts of hypercube sampling and optimal space filling. TRANSFORM was used to construct ANN surrogates for a highly non-linear industrially validated continuous casting model from steel plant. Multiobjective optimization of casting model to ensure maximum productivity, maximum energy saving and minimum operational cost was performed by ANN assisted Non-dominated Sorting Genetic Algorithms (NSGA-II). The surrogate assisted optimization was found to be 13 times faster than conventional optimization, leading to its online implementation. Simple operator's rules were deciphered from the optimal solutions using Pareto front characterization and K-means clustering for optimal functioning of casting plant. Comprehensive studies on (a) computational time comparisons between proposed training size estimation algorithms and (b) predictability comparisons between constructed ANNs and state of art statistical models, Kriging Interpolators adds to the other highlights of this work. TRANSFORM takes physics based model as the only input and provides parsimonious ANNs as outputs, making it generic across all scientific domains. 相似文献