半正二阶三点边值问题的解和正解

考察了非线性二阶三点边值问题的n个解和正解的存在性,其中允许非线性项有一个负的下界并且n是一个任意的自然数．主要结论表明该问题可以具有n个解或者正解,只要非线性项在某些有界集上的“高度”是适当的．     

双频超声交替强化超临界流体萃取装置的设计与应用

本文针对超临界流体萃取（SFE）系统设备的特点，设计丁可用于强化SFE过程的双频超声波交替强化装置。以香椿叶中黄酮类化合物为提取对象，对超声强化USFE过程的影响因素及强化效果进行了实验研究，结果表明；低频超声利于提取，频率为20kHz的超声强化的萃取率最大，38kHz的超声最小，两者交替的居于中间。     

Theoretical Analysis of the Motional Model of Nonlinear Heterogeneous Catalysis

In this paper, a model of the motional nonlinear heterogeneous catalysis process is discussed using the characteristic line method, the analytical results of elution profile are obtained and the formula which determines the parameters of reaction rate and adsorption isotherm through the motional measurement data under the nonlinear condition is given.     

后处理温度对ZrO2气凝胶超细粉织构和结构的影响

运用神效儿宝治疗小儿厌食症２１０例，总有效率为９５．２％，显效率为６２．４％。该药使用、携带方便、见效快，疗效短，无毒副作用。实验证明，该药能显著提高胃蛋白酶含量，减慢肠管推进性运动，提高动物耐疲劳、耐缺氧能力，提高巨噬细胞吞噬率及血清补Ｃ３含量，且无毒副。作用     

The contribution of the pressure drop to analyte retention in coupled column supercritical fluid chromatography of lipids

Summary This paper reports the qualitative and quantitative effects of the column pressure drop on the retention of lipid components in a serially coupled capillary column SFC system. The contribution of the pressure drop consists of two components, the density effect and the flow effect. The magnitude of the flow effect,i. e. the change in retention which results from changes in the flow-rate when column pressures are changed, is determined by the difference in single column analyte k values. The effect will be positive compared with the uncorrected retention values when the column with largest k value is closest to the injector. With the columns in reversed order, the effect will be negative. The contribution from the density effect always resulted in larger coupled column k values and was in most instances of more significance than the flow effect component. Values calculated with and without pressure drop correction have been compared and it has been shown that for most of the eighteen model lipid compounds investigated, the deviations from the experimental retention factors were smaller when pressure drop corrections were made.     

Supercritical fluid chromatography of industrial paraffins and waxes

Summary The application of capillary SFC for SIMDIST investigations of paraffins and waxes is reported. Pressure, density and temperature of the mobile phase are optimized to obtain high chromatographic resolution of complex mixtures of industrial products. Isothermal linear pressure programming and asymptotic pressure and density programming are used in the range from 15 to 35 MPa in the isothermic mode above 100°C. SFC chromatograms of natural and synthetic paraffins, microcrystalline wax and candle wax are compared. The retention behaviour of paraffin mixtures and waxes has been investigated on methyl/phenyl and biphenyl capillary columns. The polarity of the stationary phases influences the absolute retention time more than it influences the chromatographic resolution.     

Headspace single-drop microextration for the detection of organotin compounds

The performance of single-drop microextraction (SDME), coupled with gas chromatography/mass spectrometry, was assessed for the determination of tributyltin compounds in water and solid samples. Experimental parameters impacting the performance of SDME, such as microextraction solvent and sampling and stirring time, were investigated. Analytical results obtained by SDME were compared with those generated by conventional solid phase microextraction (SPME) and liquid-liquid extraction (LLE) for the determination of TBT in PACS-2 sediment certified reference material (CRM).     

CuO/ZnO/Al2O3合成甲醇催化剂制备方法

ＣｕＯ／ＺｎＯ／Ａｌ２Ｏ３合成甲醇催化剂的制备方法吴晓晖刘金尧刘崇微朱起明（清华大学化学系一碳化工国家重点实验室，北京１０００８４）何菲（天津大学化工系一碳化工国家重点实验室，天津３０００７２）关键词氧化铜，氧化锌，氧化铝，超细粒子，草酸盐胶体...     

Optical Nonlinearity of Hybrid and Nanocomposite Materials Prepared by the Sol-Gel Method

In this paper the nonlinear refractive index, optical limiting effect, photoinduced and electroinduced second harmonic generation of dye-doped hybrid and nanoparticle-doped composite materials prepared by the sol-gel process have been reported. The origin of these nonlinear optical effects has been discussed.