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991.
992.
R. Stan Brown Zhong‐Lin Lu C. Tony Liu Wing Yin Tsang David R. Edwards Alexei A. Neverov 《Journal of Physical Organic Chemistry》2010,23(1):1-15
Phosphodiesters are notoriously hydrolytically inert compounds that are demonstrated to have large accelerations of P‐OR cleavage promoted by transition and lanthanide metal ions in methanol and ethanol media. This review commentary describes recent findings of how a simple mononuclear and a dinuclear Zn(II) complex promote the cleavage of a series of RNA models and DNA models in alcohol media. The discussion centers on the analysis of the mechanisms of cleavage, energetics of the catalytic process, on recent findings of electrophilic assistance of leaving group departure, and the observation of a rapid hydrolytic reaction of a DNA model promoted by the dinuclear Zn(II) complex in ethanol containing less than 2% water. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
993.
Jie Li DING Xi Ru CHEN 《数学学报(英文版)》2006,22(6):1679-1686
For generalized linear models (GLM), in case the regressors are stochastic and have different distributions, the asymptotic properties of the maximum likelihood estimate (MLE) β^n of the parameters are studied. Under reasonable conditions, we prove the weak, strong consistency and asymptotic normality of β^n 相似文献
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The decay properties of the D and D s mesons are computed in a nonrelativistic phenomenological quark-antiquark potential of the type V (r) =-4 /3 α s /r+ Ar ν with different choices of ν.Numerical method to solve the Schrdinger equation has been used to obtain the spectroscopy of qQ mesons.The numerically obtained radial solutions are employed to obtain the decay constant and leptonic decay widths.It has been observed that predictions of the ground state masses and the decay widths are consistent with other model predictions as well as with the known experimental values. 相似文献
998.
Synthesis and characterization of Ni-Zn ferrite nanoparticles 总被引:1,自引:0,他引:1
G.S. Shahane Ashok Kumar R.P. Pant 《Journal of magnetism and magnetic materials》2010,322(8):1015-168
Nickel zinc ferrite nanoparticles NixZn1−xFe2O4 (x=0.1, 0.3, 0.5) have been synthesized by a chemical co-precipitation method. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, electron paramagnetic resonance, dc magnetization and ac susceptibility measurements. The X-ray diffraction patterns confirm the synthesis of single crystalline NixZn1−xFe2O4 nanoparticles. The lattice parameter decreases with increase in Ni content resulting in a reduction in lattice strain. Similarly crystallite size increases with the concentration of Ni. The magnetic measurements show the superparamagnetic nature of the samples for x=0.1 and 0.3 whereas for x=0.5 the material is ferromagnetic. The saturation magnetization is 23.95 emu/g and increases with increase in Ni content. The superparamagnetic nature of the samples is supported by the EPR and ac susceptibility measurement studies. The blocking temperature increases with Ni concentration. The increase in blocking temperature is explained by the redistribution of the cations on tetrahedral (A) and octahedral (B) sites. 相似文献
999.
J.K. Tripathi B. Satpati A. Gupta 《Journal of magnetism and magnetic materials》2010,322(21):3464-3469
Thermal stability of thin Pt/Cr/Co multilayers and the subsequent changes in their structural, magnetic, and magneto-optical properties are reported. We observe CoCrPt ternary alloy phase formation due to annealing at temperatures about 773 K, which is accompanied by enhancement in the coercivity value. In addition, 360° domain wall superimposed on a monodomain like background has been observed in the pristine multilayer, which changes into a multidomain upon annealing at 873 K. 相似文献
1000.
Jozef Stre?ka 《Physics letters. A》2010,374(36):3718-202
The rigorous approach aimed at providing exact analytical results for hybrid classical-quantum models is elaborated on the grounds of generalized algebraic mapping transformations. This conceptually simple method allows one to obtain novel interesting exact results for the hybrid classical-quantum models, which may for instance describe interacting many-particle systems composed of the classical Ising spins and quantum Heisenberg spins, the localized Ising spins and delocalized electrons, or many other hybrid systems of a mixed classical-quantum nature. 相似文献