WO3/ZrO2固体强酸催化剂上异丁烷-丁烯烷基化反应研究(Ⅰ)--钨负载量和焙烧温度的影响

制备了系列 WO3/ Zr O2 固体强酸催化剂 ,用 XRD,DTA-TG,H2 -TPR,Raman光谱和酸性测定等方法测定其晶型结构、表面状态和酸性 .结果表明 ,WO3/ Zr O2 中的 Zr O2 基本以 T晶相存在 ,WO3对稳定 T晶相有重要作用 ,样品具有较大的表面积 .分散于 Zr O2 表面上的 WO3主要以单层分散和析出的 WO3晶粒形式存在 ,部分可能与 Zr O2 作用形成 Zr— O—W键并起强酸作用 .研究了各种实验条件下的异丁烷 -丁烯烷基化反应 .与其它固体酸相比 ,具有较高的起始活性和 i-C08选择性 ,且与酸强度和酸量有较好的对应关系     

用带误差项的Ishikawa迭代过程逼近φ-强增生算子的零点

本文使用新的分析技巧研究了一致光滑Ｂａｎａｃｈ空间中φ 强增生算子的零点逼近问题，所得结果改进和扩展了近期许多相应的结果     

解强刚性块线代数方程组的两类L-收敛迭代法

对解强刚性块线代数方程组X=(A(?)J)X φ,本文提出了L-收敛的最佳单参数迭代法(L-OOPI)和L-收敛的多参数迭代直接法(L-MPID),并给出了数值例子．数例表明,对于强刚性块线代数方程组,该二迭代法是有效的．     

Strong coupling constants of light pseudoscalar mesons with heavy baryons in QCD

We calculate the strong coupling constants of light pseudoscalar mesons with heavy baryons within the light cone QCD sum rules method. It is shown that sextet–sextet, sextet–antitriplet and antitriplet–antitriplet transitions are described by one universal invariant function for each class. A comparison of our results on the coupling constants with the predictions existing in literature is also presented.     

A Strong Limit Theorem on Random Selection

In this paper, the idea of random selection in the theorem on gambling system is extended to Markov chains, by using the notion likelihood ratio and an analytic technique. A strong limit theorem on the relative frequency of ordered couple under random selection is established.AMS Subject Classification (2001) primary 60F15 Secondary 60J10     

A Strong Law for Mixing Random Variables

A sharp almost sure bound is derived for limit points of average sum of weakly dependent random variables, which ensures strong laws of large numbers for and -mixing random variables, without assumptions on rate of tending to zero of and -mixing parameters _n and _n.     

异方差回归模型近邻型估计的相合性

本文研究异方差回归模型Ｙｉ＾（ｎ）＝ｇ（ｘｉ＾（ｎ））＋εｉ＾（ｎ）,ｉ＝１,…,ｎ,其中ｇ是右实函数,ｘｉ＾（ｎ）是非随机设计点列,εｉ＾（ｎ）是随机误差,文中定义了一类ｇ（ｘ）的近邻型估计ｇｎ（ｘ）＝（ｎ）∑（ｉ＝１）Ｗｍ（ｘ）Ｙｉ＾（ｎ）,得到了ｒ阶平均相全和渐近正态性,特别,在（∞）∑（ｎ＝１）（ｎ）∑（ｉ＝１）Ｅ／εｉ＾（ｎ）／＾ｓ／（ｎｉ）＾ｓ／ｒ〈∞,ｍａｘＥ（１≤ｉ≤ｎ）／εｉ（＾     

On the Integrability of Strong Maximal Functions Corresponding to Different Frames

For the frame in ⁿ, let B₂()()( ⁿ) be a family of all n-dimensional rectangles containing x and having edges parallel to the straight lines of , and let M_{B 2()} be a maximal operator corresponding to B ₂(). The main result of the paper is the following Theorem. For any function fL(1+1n⁺ L)( ⁿ ) (n2) there exists a measure preserving and invertible mapping ^{n n} such that

Strongly confined semiconductor quantum dots: Pair excitations and optical properties

This paper reviews a microscopic model of basic electron-hole pair excitation processes in strongly confined semiconductor quantum dots (QD) and their influence on the optical QD properties. The effects of valence band mixing, Coulomb interaction, and surface polarization are taken into account. The exciton and biexciton wave functions and energies are obtained using a numerical diagonalization method. The computed optical spectra, such as absorption, gain, pump-probe, and two-photon absorption, agree well with experiments.     

Analysis of longitudinal multispin orders in strongly coupled spin systems

Longitudinal multispin orders provide an effective way for measurement of scalar couplings and also to probe molecular interactions and dynamics. Analysis of longitudinal orders has been made in strongly coupled AB and ABX spin systems to determine the dependence of strong coupling parameter on these orders. Experimental and simulated spectra of various longitudinal orders are illustrated for these spin systems. This general procedure can be extended to broad range of spin systems to understand the influence of strong coupling on longitudinal orders.