全文获取类型
收费全文 | 1106篇 |
免费 | 135篇 |
国内免费 | 106篇 |
专业分类
化学 | 427篇 |
晶体学 | 14篇 |
力学 | 276篇 |
综合类 | 27篇 |
数学 | 227篇 |
物理学 | 376篇 |
出版年
2024年 | 2篇 |
2023年 | 5篇 |
2022年 | 14篇 |
2021年 | 18篇 |
2020年 | 24篇 |
2019年 | 41篇 |
2018年 | 34篇 |
2017年 | 58篇 |
2016年 | 52篇 |
2015年 | 56篇 |
2014年 | 68篇 |
2013年 | 91篇 |
2012年 | 43篇 |
2011年 | 72篇 |
2010年 | 66篇 |
2009年 | 64篇 |
2008年 | 50篇 |
2007年 | 50篇 |
2006年 | 53篇 |
2005年 | 36篇 |
2004年 | 46篇 |
2003年 | 53篇 |
2002年 | 51篇 |
2001年 | 45篇 |
2000年 | 48篇 |
1999年 | 28篇 |
1998年 | 36篇 |
1997年 | 27篇 |
1996年 | 23篇 |
1995年 | 23篇 |
1994年 | 18篇 |
1993年 | 9篇 |
1992年 | 3篇 |
1991年 | 11篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1347条查询结果,搜索用时 31 毫秒
121.
W. Ding L. Calabri K. M. Kohlhaas X. Chen D. A. Dikin R. S. Ruoff 《Experimental Mechanics》2007,47(1):25-36
The fracture strengths and elastic moduli of arc-grown multi-walled carbon nanotubes (MWCNTs) were measured by tensile loading
inside of a scanning electron microscope (SEM). Eighteen tensile tests were performed on 14 MWCNTs with three of them being
tested multiple times (3×, 2×, and 2×, respectively). All the MWCNTs fractured in the “sword-in-sheath” mode. The diameters
of the MWCNTs were measured in a transmission electron microscope (TEM), and the outer diameter with an assumed 0.34 nm shell
thickness was used to convert measured load-displacement data to stress and strain values. An unusual yielding before fracture
was observed in two tensile loading experiments. The 18 outer shell fracture strength values ranged from 10 to 66 GPa, and
the 18 Young's modulus values, obtained from a linear fit of the stress–strain data, ranged from 620 to 1,200 GPa, with a
mean of 940 GPa. The possible influence of stress concentration at the clamps is discussed. 相似文献
122.
纺织结构复合材料力学性能的实验研究 总被引:13,自引:1,他引:13
本文通过实验测定了三维编织结构复合材料侧边未切割、受切割和中央钻孔试件的拉伸性能,对比了受切割和未切割纤维对于试件侧边拉伸应变的影响,并且讨论了拉伸失效的机理和原因.发现受切割和钻孔试件的拉伸性能低于未加工试件的性能,受切割侧边的拉伸应变高于未切割侧边的拉伸应变,三维编织结构复合材料的拉伸失效主要由纤维断裂引起的.文中还对三维编织结构复合材料的孔边应力集中现象进行了研究,并进行了深入分析,得到一个重要结论,即四步法复合材料的孔边应力集中系数比传统层板复合材料和金属材料的低.从这个意义上说,三维编织结构复合材料适合于作为含孔结构的连接件. 相似文献
123.
124.
Numerical integration formulas in n-dimensional Euclidean space of degree three are discussed. In this paper, for the product regions a method is presented to construct numerical integration formulas of degree three with 2n real points and positive weights. The presented problem is a little different from those dealt with by other authors. All the corresponding one-dimensional integrals can be different from each other and they are also nonsymmetrical. In this paper an n-dimensional numerical integration problem is turned into n one-dimensional moment problems, which simplifies the construction process. Some explicit numerical formulas are given. Furthermore, a more generalized numerical integration problem is considered, which will shed light on the final solution to the third degree numerical integration problem. 相似文献
125.
Wei LiuQimin Zhang 《Applied mathematics and computation》2011,218(8):3973-3980
In general, most of stochastic age-structured system of three species do not have explicit solutions, thus numerical approximation schemes are invaluable tools for exploring their properties. The aim of this paper is to investigate the convergence of numerical approximation solution to the true solution for stochastic age-structured system of three species. 相似文献
126.
We consider mixed integer linear sets defined by two equations involving two integer variables and any number of non-negative continuous variables. We analyze the benefit from adding a non-split inequality on top of the split closure. Applying a probabilistic model, we show that the importance of a type 2 triangle inequality decreases with decreasing lattice width, on average. Our results suggest that this is also true for type 3 triangle and quadrilateral inequalities. 相似文献
127.
结合实测数据,以三个对数正态分布函数的和函数为拟合函数,以梯度下降法为主要方法,对沉积物粒度分布进行了数据拟合,通过数值实验我们发现:利用梯度下降法可以有效地优化分布函数的各参数,实现拟合残差的稳步持续减小,具有良好的可操作性,拟合效果是令人满意的,它为我们进行数据拟合提供了一条新的思路,同时此方法也可以推广到解决其他极值问题. 相似文献
128.
L. U. Ancarani K. V. Rodriguez G. Gasaneo 《International journal of quantum chemistry》2011,111(15):4255-4265
n1,3S (n = 1 ? 4) states for atomic three‐body systems are studied with the Angular Correlated Configuration Interaction method. A recently proposed angularly correlated basis set is used to construct, simultaneously and with a single diagonalization, ground and excited states wave functions which: (i) satisfy exactly Kato cusp conditions at the two‐body coalescence points; (ii) involve only linear parameters; (iii) show a fast convergency rate for the energy; and (iv) form an orthogonal set. The efficiency of the method is illustrated by the study a variety of three‐body atomic systems [m m m] with two negatively charged light particles, with diverse masses m and m, and a heavy positively charged nucleus m. The calculated ground 11S and excited n1,3S (n = 2 ? 4) state energies are compared with those given in the literature, when available. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
129.
Hong‐Jian Wang Paul v. R. Schleyer Judy I. Wu Yan Wang Hai‐Jun Wang 《International journal of quantum chemistry》2011,111(5):1031-1038
The resonance energies (REs) of neutral three membered ring analogs of the cyclopropenyl cation, computed using block localized wave function (BLW) methods, reveal considerable variations. The RE's of cyclopropenes substituted with exocyclic double bonded groups C?X, (X = O, NH, CH2, S, PH, SiH2) increase with the electronegativity of X in the same row (SiH2 < PH < S and CH2 < NH < O). The extra cyclic resonance energies (ECREs) (an energetic measure of aromaticity based on comparisons with the RE's of acyclic models) of these derivatives range from +10.5 kcal/mol for cyclopropenone (X = O) (somewhat aromatic; the benzene ECRE is 29.3 kcal/mol) to ?2.4 kcal/mol (slightly antiaromatic) for X = SiH2. Additional disubstitution of the C?C double bond by X′ groups (X′ = CH3, NH2, OH, SiH3, PH2, SH) increases the REs considerably, but has only small effects on the ECREs. Even the ECRE of deltic acid (X = O, X′ = OH) is only increased to +13.3 kcal/mol. The conclusion based on ECRE's, that all 12 of the three membered rings are only marginally aromatic/antiaromatic, is supported by the satisfactorily plot (R2 = 0.92) of ECRE against values of NICS(0)πzz (a superior nucleus chemical independent shift magnetic index of aromaticity), which range only from ?6.1 ppm (diatropic) for deltic acid (cf., ?35.5 ppm for benzene and ?14.2 ppm for the parent cyclopropenium ion) to +8.9 ppm (paratropic) for the silicon derivative, X = SiH2, X′ = SiH3. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
130.
Scale effects on strength of geomaterials, case study: Coal 总被引:1,自引:0,他引:1
Scale effects on the strength of coal are studied using a discrete element model. The key point of the model is its capability to discriminate between the “strictly sample size” effect and the “Discrete Fracture Network (DFN) density” effect on the mechanical response. Simulations of true triaxial compression tests are carried out to identify their respective roles. The possible bias due to the discretization size distribution of the discrete element model is investigated in detail by considering low-resolution configurations. The model is shown to be capable of quantitatively reproducing the dependency of the maximum strength on the size of the sample. This relationship mainly relies on the DFN density. For all given sizes, as long as the DFN density remains constant with a uniform distribution or if discontinuities are absent in the considered medium, the maximum strength of the material remains constant. 相似文献