首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   835篇
  免费   122篇
  国内免费   41篇
化学   349篇
晶体学   3篇
力学   90篇
综合类   7篇
数学   48篇
物理学   501篇
  2023年   7篇
  2022年   10篇
  2021年   11篇
  2020年   15篇
  2019年   8篇
  2018年   11篇
  2017年   20篇
  2016年   18篇
  2015年   15篇
  2014年   26篇
  2013年   55篇
  2012年   21篇
  2011年   63篇
  2010年   47篇
  2009年   47篇
  2008年   67篇
  2007年   60篇
  2006年   66篇
  2005年   43篇
  2004年   32篇
  2003年   38篇
  2002年   29篇
  2001年   39篇
  2000年   23篇
  1999年   32篇
  1998年   27篇
  1997年   30篇
  1996年   22篇
  1995年   16篇
  1994年   21篇
  1993年   18篇
  1992年   10篇
  1991年   4篇
  1990年   13篇
  1989年   10篇
  1988年   1篇
  1987年   5篇
  1986年   5篇
  1985年   4篇
  1984年   1篇
  1983年   2篇
  1982年   5篇
  1980年   1篇
排序方式: 共有998条查询结果,搜索用时 15 毫秒
941.
A new class of non-isolated singularities called hyperplane singularities is introduced. Special deformations with simplest critical points are constructed and an algebraic expression for the number of Morse points is given. The topology of the Milnor fibre is completely studied.  相似文献   
942.
The application of the recently developed method of geometro-stochastic quantization to spin-1/2 fields in curved spacetime does not give rise to any of the conceptual and technical difficulties encountered by more conventional methods of quantization. Field propagation is based on the concept of stochastic parallel transport governed by quantum connections that incorporate Poincaré gauge invariance and obey the equivalence principle. Consequently, under free-fall conditions, such geometro-stochastic Dirac field propagation does not give rise to Bogolubov transformations resulting in spontaneous fermion creation.1. Supported in part by the NSERC Research Grant No. A5206.2. Supported by an NSERC postgraduate fellowship.  相似文献   
943.
ICP-AES法测定耐磨合金钢中Ni、Cr、Mo、V和W等十二种元素   总被引:6,自引:1,他引:5  
本文采用王水、硫磷混酸溶解试样,研究了应用ICP-AES技术测定耐磨合金钢中Ni、Cr、Mo、V、W、Zn、Co、La、Ce、Ti、Mn、Cu12种元素的方法。试验了硫酸、磷酸用量对测定的影响和共存离子干扰,方法相对标准偏差为1.40%—3.22%,回收率为96.0%—108.1%。对试样进行分析,结果满意。  相似文献   
944.
用WX—5型看谱仪进行高碳铬轴承钢定量分析的方法   总被引:1,自引:0,他引:1  
本文介绍看变定量分析方法,采用高场光栅同步看谱分析图和细化定量分析标志表,对高碳铬轴承钢中,Cr,Mn,Si元素进行了一系列定量分析试验。其定量结果符合国内化学标准GB222-84要求。具有操作简便灵活,成本低,不取样,损伤小,快速准确等特点。  相似文献   
945.
 报道了外径为0.8 mm的多级气隙-光纤探针技术。探针接收的弱光信号用变象管相机记录、贮存及数字化处理。该探针嵌入固体炸药TNT/RDX=40/60(ρ0=1.70 g/cm3)和液体炸药硝基甲烷内部,测得爆速分别为8.02和6.27 km/s。对光信号的可靠性进行了实验验证。  相似文献   
946.
真空Einstein方程所容许的群及方程的局部不变解   总被引:2,自引:0,他引:2  
该文提出李变换群延拓群的概念,并运用纤维丛方法解决了延拓群算子中的系数问题.在此基础上,作者着重求出了真空Einstein方程所容许的群,同时还提出求方程局部不变解的一种可能方案.  相似文献   
947.
Although branched chain fatty acids perform many functions in biological systems, the importance of the anteiso 18 methyleicosanoic acid (MEA) has only recently been recognized. In this first review on MEA its role and distribtuion is explored MEA has been found in minor amounts in the fatty acid components of a wide range of biological materials, but the current interest results from it being the major covalently bound fatty acid in mammalian hair fibres, a finding which is unusual because protein-bound fatty acids are typically straight-chain, even-numbered acids (C14–C18). MEA is released by surface restricted reagents indicating that it is located exclusively in or on the surface of the cuticle cells, a conclusion that has been verified by analysis of isolated cuticle cells. X-ray photoelectron spectroscopy (XPS) and secondary-ion mass spectroscopy (SIMS) studies support these results in that they show the surface of the cuticle to be predominantly hydrocarbon. When either neutral hydroxylamine or acidic chlorine solutions are applied to hair and wool fibres fatty acids are liberated, indicating the presence of thioester bonds. Calculations, based on fatty acid and amino acid analysis, indicate that approximately one residue in 10 of the cuticular membrane protein is a fatty acid thioester of cysteine. Removal of this covalently linked fatty acid renders the fibre hydrophilic, thus offering a chemical explanation for many technological and cosmetic treatments of mammalian fibres. Examination of the fibre surface and that of isolated cuticle cells by transmission electron microscopy (TEM) confirms the presence of a thin non-staining continuous layer surrounding the cuticle cells. Alkaline treatments which remove the bound fatty acids were found to disrupt this layer. TEM examination of developing hair fibres has indicated that the fatty acid layer on the upper surface and scale edges of the cuticle cell differs from that of the underside of the cell. Similar structural studies of hair from patients with maple syrup urine disease (MSUD) support the findings that thioester-bound MEA is limited to the upper surface of fibre cuticle cells. The current model proposed for the boundary layer consists of crosslinked protein with surface thioester-linked fatty acids. forming a continuous hydrophobic layer on the upper surface and scale edges of the cells.  相似文献   
948.
本文所叙述的方法是将固体钢铁样品在车床、铣床上打平,或在磨片机上磨成平面。然后用选好的最佳仪器测量条件,用铁元素做内标,按照自编的分析程序在MBS火花发射台的氩气气氛中激发,进行火花原子发射光谱法测定。此法简单、快速,所得分析结果与推荐的标准值基本一致,其相对标准偏差RSD≤10%,测试结果令人满意。  相似文献   
949.
The effect of immobilization on the oxidation-reduction equilibria of some quinonoid indicators adsorbed on Amberlite XAD-2 was studied. The reduction potentials of the immobilized indicators were determined at pH 0 by a reflectometric technique involving the use of optical fibres. The standard potentials of the immobilized indicators were evaluated graphically by means of the Nernst equation for poten-tiometric measurements, and the Kubelka-Munk equation for diffuse reflectance measurements. The reduction potential was lowered by adsorption of the indicator on a non-polar surface and evidence for formation of a semiquinone was noted in the case of immobilized cacotheline. The solid-solvent model for adsorption on polystyrene-divinylbenzene copolymers was used to explain the observations.  相似文献   
950.
文中用合成的偶氮氯磷-mA螯合形成纤维(以下称CPA-mA纤维)对地质样品中的稀土元素进行分离富集,并制成薄试样进行荧光X-射线光谱法测定[1,2]。CPA-mA纤维合成简单,交换速度快,在抗坏血酸和混合掩蔽剂(EDTA+CYDT+EGTA)存在下使痕量稀土元素及基体分离并得以富集。分析结果表明该方法的RSD小于15.68%,标准加入回收率在84.0~107.5%之间,能较好地满足地质工作的需要。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号