Determination of the gas chromatographic elution sequences of the (+)- and (−)-enantiomers of stable atropisomeric PCBs on Chirasil-dex

Pure enantiomers of chiral (atropisomeric) polychlorinated biphenyls (PCBs) obtained by high-performance liquid chromatography were used to establish the gas chromatographic elution sequences of the (+)- and (−)-enantiomers of six PCB atropisomers on Chirasil-Dex. The elution order was found to be (−/+) for PCBs 84, 132, 136, and 176 and (+/−) for PCBs 135 and 174. The retention characteristics of all 19 tri- and tetra-ortho atropisomeric PCBs were also investigated. Nine of the atropisomers could be separated using this chiral selector. PCBs 95, 132, and 149 were completely resovled and PCBs 84, 91, 135, 136, 174, and 176 were partially separated (R = 0.7–0.9). All of the separated congeners are 2,3,6-substituted in at least one ring, and conversely – none of the congeners that lacks 2,3,6-substitution could be separated. Thus, chiral recognition and enantiomer separation seems to be strongly governed by 2,3,6-substitution.     

非等熵气体动力学方程组大初值问题的放缩框架

非等熵气体动力学系统Cauchy问题弱解全局存在性有两个公开问题:一个是包含真空的小初值问题,另一个是任意大初值问题.本文通过引入一个放缩框架证明了上述两个问题的等价性,即对于粘性消失解,其包含真空小初值问题的一致BV估计蕴含着任意大初值问题弱解的全局存在性.该放缩框架对大多数具有物理背景的双曲守恒律系统亦成立.     

Undercompressive shocks for nonstrictly hyperbolic conservation laws

We study 2×2 systems of hyperbolic conservation laws near an umbilic point. These systems have Undercompressive shock wave solutions, i.e., solutions whose viscous profiles are represented by saddle connections in an associated family of planar vector fields. Previous studies near umbilic points have assumed that the flux function is a quadratic polynomial, in which case saddle connections lie on invariant lines. We drop this assumption and study saddle connections using Golubitsky-Schaeffer equilibrium bifurcation theory and the Melnikov integral, which detects the breaking of heteroclinic orbits. The resulting information is used to construct solutions of Riemann problems.     

Exact solutions for network rewiring models

Evolving networks with a constant number of edges may be modelled using a rewiring process. These models are used to describe many real-world processes including the evolution of cultural artifacts such as family names, the evolution of gene variations, and the popularity of strategies in simple econophysics models such as the minority game. The model is closely related to Urn models used for glasses, quantum gravity and wealth distributions. The full mean field equation for the degree distribution is found and its exact solution and generating solution are given.     

1-Soliton solution and conservation laws for nonlinear wave equation in semiconductors

This paper obtains the 1-soliton solution of a nonlinear wave equation that arises in the study of semiconductors. The conserved quantities are also calculated from this equation. Furthermore, additional non-trivial conserved quantities are computed using the invariance and multiplier approach based on the well known result that the Euler-Lagrange operator annihilates the total divergence.     

Structural response of stiffened plates in similitude under a turbulent boundary layer excitation

In structural dynamics, similitude laws usually deal with simple configurations as thin flat plates with point forces. Only recently, few papers have analyzed stiffened shells or stochastic pressure loads.This research activity extends the applicability of some similitude laws, developed for thin flat plates under a turbulent boundary layer load, to ribbed plates forced by the same wall pressure fluctuations.The work addresses the problem of designing a scaled experimental test-article and, successively, of re-modulating the measured data in order to get the structural response of an original (unscaled) configuration.Due to the complexity of the structural domain, the design of a scaled configuration leads to a distorted similitude. Then, a simple approach, to circumvent the distortion effects, is proposed.     

On the Lower Tail Probabilities of Some Random Sequences in <Emphasis Type="Italic">l</Emphasis><Subscript><Emphasis Type="Italic">p</Emphasis></Subscript>

We investigate the behaviour of the logarithmic small deviation probability of a sequence (σ _n θ _n ) in l _p , 0<p≤∞, where (θ _n ) are i.i.d. random variables and (σ _n ) is a decreasing sequence of positive numbers. In particular, the example σ _n ∼n ^−μ (1+log n)^−ν is studied thoroughly. Contrary to the existing results in the literature, the rate function and the small deviation constant are expressed expli- citly in the present treatment. The restrictions on the distribution of θ ₁ are kept to an absolute minimum. In particular, the usual variance assumption is removed. As an example, the results are applied to stable and Gamma-distributed random variables.     

Invariance Analysis and Variational Conservation Laws for the Wave Equation on Some Manifolds

In this paper we discuss symmetries of a nonlinear wave equation that arises as a consequence of some Riemannian metrics of signature −2. The objective of this study is to show how geometry can be responsible in giving rise to a nonlinear inhomogeneous wave equation rather than assuming nonlinearities in the wave equation from physical considerations. We find Lie point symmetries of the corresponding wave equations and give their solutions in two cases. Some interesting physical conclusions relating to conservation laws such as energy, linear and angular momenta are also determined.     

Group Laws [x,y −1] ≡ u(x,y) and Varietal Properties

Let F = ?x, y? be a free group. It is known that the commutator [x, y ^?1] cannot be expressed in terms of basic commutators, in particular in terms of Engel commutators. We show that the laws imposing such an expression define specific varietal properties. For a property 𝒫 we consider a subset U(𝒫) ? F such that every law of the form [x, y ^?1] ≡ u, u ∈ U(𝒫) provides the varietal property 𝒫. For example, we show that each subnormal subgroup is normal in every group of a variety 𝔙 if and only if 𝔙 satisfies a law of the form [x, y ^?1] ≡ u, where u ∈ [F′, ?x?].     

Limit relations for three simple hyperbolic systems of conservation laws

This paper is concerned with the limit relations from the Euler equations of one‐dimensional compressible fluid flow and the magnetohydrodynamics equations to the simplified transport equations, where the δ‐shock waves occur in their Riemann solutions of the latter two equations. The objective is to prove that the Riemann solutions of the perturbed equations coming from the one‐dimensional simplified Euler equations and the magnetohydrodynamics equations converge to the corresponding Riemann solutions of the simplified transport equations as the perturbation parameterx ε tends to zero. Furthermore, the result can also be generalized to more general situations. Copyright © 2009 John Wiley & Sons, Ltd.