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61.
62.
选择绕圆柱预混燃烧算例,验证CH4/空气三种简化动力学机理(16s41r、15s19r和53s325r).考虑均匀来流,忽略湍流和湍流与燃烧相互作用以及燃料扩散效应,假设层流有限反应速率,采用保自由流5阶WENO格式求解多组分Euler方程组,得到CH4/空气预混燃烧流场温度等值线、沿驻点线压力和温度及其CH4、CO和CO2质量百分数分布.结果表明:三种简化动力学机理给出的流场均出现弓形激波和火焰面,弓形激波和火焰驻点距离及其形状、诱导区宽度和简化动力学机理相关.当圆柱直径增大,弓形激波和火焰向圆柱上游移动,对应的驻点距离均增大,诱导区宽度变短,点火延时变小,但火焰和弓形激波位置次序未变化.53s325r模型要比16s41r模型和15s19r模型精度要高,点火延时覆盖的压力和温度范围也较宽,所有简化机理均未完全反应,在较大圆柱直径下游达到化学平衡. 相似文献
63.
Shahram Mehdipour-Ataei Samal Babanzadeh 《International Journal of Polymer Analysis and Characterization》2020,25(3):147-157
AbstractA new monomeric building block was prepared via three consecutive reactions. 4-(4-Nitrobenzyl)pyridine was catalytically reduced to 4-(4-aminobenzyl)pyridine by converting the nitro to amino group. In second step, the later compound was reacted with 3,5-dinitrobenzoyl chloride to obtain a dinitro compound which finally was converted to a new diamine by reduction of nitro groups. Polycondensation reactions of the diamine with diacidchlorides led to preparation of novel cardo polyamides with high thermal stability and flame retardancy, as well as improved solubility. The structure-property relations were studied by varying the diacidchlorides to investigate the effect of symmetry and aromaticity on the polymers. 相似文献
64.
《Mendeleev Communications》2020,30(1):121-123
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65.
The stabilization of partially-premixed jet flames in the presence of high potential electric fields
Numerous research efforts have focused on flame stabilization and emissions. Based on initial experiments, specific mechanisms resulting from DC electric fields were chosen to be investigated, namely the chemical, thermal, and ionization mechanisms. Numerical simulations were performed on premixed propane-ozone-air flames to characterize ozone effects on flame speed resulting from the formation of ozone in high potential electric fields. These results were compared against partially premixed flame experiments to observe the dominant influences within leading edge stabilization within high potential electric fields. It was found that the electromagnetic or ionization influences, serve as the dominant effect on the combustion zone. 相似文献
66.
67.
Ioannis Dosis Maria Athanasiadou Ioannis Athanassiadis Xanthippos Karamanlis 《International journal of environmental analytical chemistry》2013,93(12):1151-1165
Polybrominated diphenyl ether (PBDE) concentrations were determined in marine sediment samples collected from 7 different locations around Thermaikos Gulf in north Greece. PBDEs were detected in all sampling sites and their average total concentration (ΣPBDEs) ranged from 0.26 to 4.92?ng?g?1?d.w. Concentrations were an order of magnitude higher in locations outlining the inner part of the Gulf, which were also closer to industrial areas, sewage treatment plant discharges, the city's harbour and landfill area. These findings suggest pollution in the aquatic ecosystem from industrial and urban activities in the area. Congener profiles exhibit predominance of BDE-209, while concentrations of other PBDE congeners were usually lower, when compared to similar studies from other countries globally, indicating that Thermaikos Gulf is among the low-polluted areas. Statistical analysis showed significant differences among the higher polluted sampling stations. Statistically significant differences also existed between sampling stations with high and low PBDE concentrations. Correlations between congeners suggested local contamination sources; however, specific point sources of pollution were not established. 相似文献
68.
Sedigheh Basiri Soleyman Moinfar 《International journal of environmental analytical chemistry》2013,93(15):1453-1465
The method relies on selective complexation of As(III) with a suitable chelating agent followed by dispersive liquid–liquid microextraction (DLLME) method. Flame atomic absorption spectrometry (FAAS) equipped with microsample introduction system was utilised for determination of As(III). 1-Undecanol and acetone were used as extraction solvent and disperser solvent respectively. Some effective parameters on complex formation and extraction have been optimised. Under the optimum conditions, the enrichment factor of 108 for As(III) was obtained from 9.8?mL of water samples. The calibration graph was linear in the range of 2–15?µg?L?1 with detection limits of 0.60?µg?L?1 for As(III). The relative standard deviation (R.S.D.) for ten replicate measurements of 5.00?µ?gL?1 of As(III) was 6.2%. Operation simplicity and high enrichment factors are the main advantages of DLLME for the determination of As(III) without necessity for hydride generation in water samples. 相似文献
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Three kinds of polyethylene glycol phosphates (PEGPs) toughening agents were synthesized by esterification of phosphorus pentoxide (P2O5) with polyethylene glycol and characterized by Fourier transform infrared spectra and 31P nuclear magnetic resonance. A series of lightweight phenolic foams toughened with different loadings of PEGPs were prepared. Optical microscopy results show that the addition of PEGPs with small molecular weight PEG improves the structural homogeneity of phenolic foams obviously. The flame retardancy of toughened phenolic foams was evaluated by using UL 94, limiting oxygen index, and cone calorimeter. The results indicate that the incorporation of PEGPs not only increases the toughness of phenolic foams but also improves their flame retardancy. Moreover, the thermal stability of PEGPs and the toughened foams was investigated by thermogravimetric analysis. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献